[Not Available].
Identifieur interne : 000121 ( Ncbi/Merge ); précédent : 000120; suivant : 000122[Not Available].
Auteurs : Salah Kouass [Tunisie] ; Abderrahmen Guesmi [Tunisie] ; Ahmed DrissSource :
- Acta crystallographica. Section C, Crystal structure communications [ 1600-5759 ] ; 2010.
Abstract
The title compound, namely lithium cobalt(II/III) bis(diphosphate), Li(4.03)Co(1.97)(P(2)O(7))(2), is a new mixed-valent lithium/cobalt(II/III) phosphate. Three metal sites out of seven are occupied simultaneously by Li(+) and Co(II/III) ions. This disorder was established both from an analysis of the atomic displacement ellipsoids and Li/Co-O bond distances, and by means of a charge-distribution (CHARDI) model, which provides satisfactory agreement on the computed charges (Q) for all the cations.
DOI: 10.1107/S0108270109052810
PubMed: 20048409
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pubmed:20048409Le document en format XML
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<front><div type="abstract" xml:lang="en">The title compound, namely lithium cobalt(II/III) bis(diphosphate), Li(4.03)Co(1.97)(P(2)O(7))(2), is a new mixed-valent lithium/cobalt(II/III) phosphate. Three metal sites out of seven are occupied simultaneously by Li(+) and Co(II/III) ions. This disorder was established both from an analysis of the atomic displacement ellipsoids and Li/Co-O bond distances, and by means of a charge-distribution (CHARDI) model, which provides satisfactory agreement on the computed charges (Q) for all the cations.</div>
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