[Not Available].
Identifieur interne : 000055 ( PubMed/Curation ); précédent : 000054; suivant : 000056[Not Available].
Auteurs : Salah Kouass [Tunisie] ; Abderrahmen Guesmi ; Ahmed DrissSource :
- Acta crystallographica. Section C, Crystal structure communications [ 1600-5759 ] ; 2010.
Abstract
The title compound, namely lithium cobalt(II/III) bis(diphosphate), Li(4.03)Co(1.97)(P(2)O(7))(2), is a new mixed-valent lithium/cobalt(II/III) phosphate. Three metal sites out of seven are occupied simultaneously by Li(+) and Co(II/III) ions. This disorder was established both from an analysis of the atomic displacement ellipsoids and Li/Co-O bond distances, and by means of a charge-distribution (CHARDI) model, which provides satisfactory agreement on the computed charges (Q) for all the cations.
DOI: 10.1107/S0108270109052810
PubMed: 20048409
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Section C, Crystal structure communications</title><idno type="eISSN">1600-5759</idno><imprint><date when="2010" type="published">2010</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The title compound, namely lithium cobalt(II/III) bis(diphosphate), Li(4.03)Co(1.97)(P(2)O(7))(2), is a new mixed-valent lithium/cobalt(II/III) phosphate. Three metal sites out of seven are occupied simultaneously by Li(+) and Co(II/III) ions. This disorder was established both from an analysis of the atomic displacement ellipsoids and Li/Co-O bond distances, and by means of a charge-distribution (CHARDI) model, which provides satisfactory agreement on the computed charges (Q) for all the cations.</div></front></TEI><pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">20048409</PMID><DateCreated><Year>2010</Year><Month>1</Month><Day>5</Day></DateCreated><DateCompleted><Year>2010</Year><Month>02</Month><Day>19</Day></DateCompleted><DateRevised><Year>2015</Year><Month>8</Month><Day>14</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1600-5759</ISSN><JournalIssue CitedMedium="Internet"><Volume>66</Volume><Issue>Pt 1</Issue><PubDate><Year>2010</Year><Month>Jan</Month></PubDate></JournalIssue><Title>Acta crystallographica. Section C, Crystal structure communications</Title><ISOAbbreviation>Acta Crystallogr C</ISOAbbreviation></Journal><ArticleTitle>[Not Available].</ArticleTitle><Pagination><MedlinePgn>i4-6</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1107/S0108270109052810</ELocationID><Abstract><AbstractText>The title compound, namely lithium cobalt(II/III) bis(diphosphate), Li(4.03)Co(1.97)(P(2)O(7))(2), is a new mixed-valent lithium/cobalt(II/III) phosphate. Three metal sites out of seven are occupied simultaneously by Li(+) and Co(II/III) ions. This disorder was established both from an analysis of the atomic displacement ellipsoids and Li/Co-O bond distances, and by means of a charge-distribution (CHARDI) model, which provides satisfactory agreement on the computed charges (Q) for all the cations.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Kouass</LastName><ForeName>Salah</ForeName><Initials>S</Initials><AffiliationInfo><Affiliation>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences, Université de Tunis El Manar, 2092 Tunis, Tunisie.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Guesmi</LastName><ForeName>Abderrahmen</ForeName><Initials>A</Initials></Author><Author ValidYN="Y"><LastName>Driss</LastName><ForeName>Ahmed</ForeName><Initials>A</Initials></Author></AuthorList><Language>FRE</Language><PublicationTypeList><PublicationType UI="D004740">English Abstract</PublicationType><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><VernacularTitle>Le phosphate de cobalt et de lithium à valence mixte Li(4+x)Co(2-x)(P2O7)2 (x = 0,03): étude structurale et analyse de distribution de charge.</VernacularTitle><ArticleDate DateType="Electronic"><Year>2009</Year><Month>Dec</Month><Day>19</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>Acta Crystallogr C</MedlineTA><NlmUniqueID>8305826</NlmUniqueID><ISSNLinking>0108-2701</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2009</Year><Month>10</Month><Day>28</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2009</Year><Month>12</Month><Day>08</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2010</Year><Month>1</Month><Day>6</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2010</Year><Month>1</Month><Day>6</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2010</Year><Month>1</Month><Day>6</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">20048409</ArticleId><ArticleId IdType="pii">S0108270109052810</ArticleId><ArticleId IdType="doi">10.1107/S0108270109052810</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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