CobaltMaghrebV1, Main, Merge, bibRecord, 000A11

Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH2BP2O9

Identifieur interne : 000A11 ( Main/Merge ); précédent : 000A10; suivant : 000A12

Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH2BP2O9

Auteurs : Abderrahmen Guesmi [Tunisie] ; Ahmed Driss [Tunisie]

Source :

Advanced engineering materials : (Print) [ 1438-1656 ] ; 2004.

RBID : Pascal:05-0020473

Descripteurs français

Pascal (Inist)
- Structure cristalline, Méthode hydrothermale, Diffraction RX, Liaison hydrogène, Croissance cristalline, Distance interatomique, Angle liaison, Cristal centrosymétrique, Monocristal, Cobalt hydrogénoborophosphate, Sodium hydrogénoborophosphate, NaCoH2BP2O9, 6166F, B Co H Na O P.

English descriptors

KwdEn :
- Bond angle, Centrosymmetrical crystals, Crystal growth, Crystal structure, Hydrogen bonds, Hydrothermal growth, Interatomic distances, Monocrystals, XRD.

Abstract

A new sodium cobalt hydrogen borophosphate, NaCoH₂BP₂O₉, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single-crystal x-ray diffraction method]. The structure consists in anionic groups I(H₂BP₂O₉)^3-]₂ (centrosymmetric units [HP(2)O₃O_1/2-HBO₂O₂/₂-P(1)O₃O_1/2]₂) which are interconnected by sharing corners with the Co₂O₁₀ bioctahedral units. The framework connection is reinforced by hydrogen bonds.

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Pascal:05-0020473

Le document en format XML

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BP<sub>2</sub>
O<sub>9</sub>
</title>
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<author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
</title>
<author><name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
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<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences</s1>
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<placeName><settlement type="city">Tunis</settlement>
<region type="region" nuts="2">Gouvernorat de Tunis</region>
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<orgName type="university" n="3">Université de Tunis - El Manar</orgName>
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<author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bond angle</term>
<term>Centrosymmetrical crystals</term>
<term>Crystal growth</term>
<term>Crystal structure</term>
<term>Hydrogen bonds</term>
<term>Hydrothermal growth</term>
<term>Interatomic distances</term>
<term>Monocrystals</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Structure cristalline</term>
<term>Méthode hydrothermale</term>
<term>Diffraction RX</term>
<term>Liaison hydrogène</term>
<term>Croissance cristalline</term>
<term>Distance interatomique</term>
<term>Angle liaison</term>
<term>Cristal centrosymétrique</term>
<term>Monocristal</term>
<term>Cobalt hydrogénoborophosphate</term>
<term>Sodium hydrogénoborophosphate</term>
<term>NaCoH2BP2O9</term>
<term>6166F</term>
<term>B Co H Na O P</term>
</keywords>
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<front><div type="abstract" xml:lang="en">A new sodium cobalt hydrogen borophosphate, NaCoH<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single-crystal x-ray diffraction method]. The structure consists in anionic groups I(H<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
)<sup>3-</sup>
]<sub>2</sub>
 (centrosymmetric units [HP(2)O<sub>3</sub>
O<sub>1/2</sub>
-HBO<sub>2</sub>
O<sub>2</sub>
/<sub>2</sub>
-P(1)O<sub>3</sub>
O<sub>1/2</sub>
]<sub>2</sub>
) which are interconnected by sharing corners with the Co<sub>2</sub>
O<sub>10</sub>
 bioctahedral units. The framework connection is reinforced by hydrogen bonds.</div>
</front>
</TEI>
<affiliations><list><country><li>Tunisie</li>
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<tree><country name="Tunisie"><region name="Gouvernorat de Tunis"><name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
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<name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
<name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
</country>
</tree>
</affiliations>
</record>

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Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH2BP2O9

Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH2BP2O9

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri