CobaltMaghrebV1, PascalFrancis, Corpus, bibRecord, 000202

Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH2BP2O9

Identifieur interne : 000202 ( PascalFrancis/Corpus ); précédent : 000201; suivant : 000203

Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH2BP2O9

Auteurs : Abderrahmen Guesmi ; Ahmed Driss

Source :

Advanced engineering materials : (Print) [ 1438-1656 ] ; 2004.

RBID : Pascal:05-0020473

Descripteurs français

Pascal (Inist)
- Structure cristalline, Méthode hydrothermale, Diffraction RX, Liaison hydrogène, Croissance cristalline, Distance interatomique, Angle liaison, Cristal centrosymétrique, Monocristal, Cobalt hydrogénoborophosphate, Sodium hydrogénoborophosphate, NaCoH2BP2O9, 6166F, B Co H Na O P.

English descriptors

KwdEn :
- Bond angle, Centrosymmetrical crystals, Crystal growth, Crystal structure, Hydrogen bonds, Hydrothermal growth, Interatomic distances, Monocrystals, XRD.

Abstract

A new sodium cobalt hydrogen borophosphate, NaCoH₂BP₂O₉, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single-crystal x-ray diffraction method]. The structure consists in anionic groups I(H₂BP₂O₉)^3-]₂ (centrosymmetric units [HP(2)O₃O_1/2-HBO₂O₂/₂-P(1)O₃O_1/2]₂) which are interconnected by sharing corners with the Co₂O₁₀ bioctahedral units. The framework connection is reinforced by hydrogen bonds.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 1438-1656`
A03		`1`		`@0 Adv. eng. mater. : (Print)`
A05				`@2 6`
A06				`@2 10`
A08	`01`	`1`	`ENG`	`@1 Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH₂BP₂O₉`
A11	`01`	`1`		`@1 GUESMI (Abderrahmen)`
A11	`02`	`1`		`@1 DRISS (Ahmed)`
A14	`01`			`@1 Institut préparatoire aux études d'ingénieur, Rue Ibnou Eljazzar @2 Monastir, 5090 @3 TUN @Z 1 aut.`
A14	`02`			`@1 Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences @2 El Manar, 2092, Tunis @3 TUN @Z 1 aut. @Z 2 aut.`
A20				`@2 796, 840-842 [4 p.]`
A21				`@1 2004`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 27060 @5 354000122700220110`
A44				`@0 0000 @1 © 2005 INIST-CNRS. All rights reserved.`
A45				`@0 23 ref.`
A47	`01`	`1`		`@0 05-0020473`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Advanced engineering materials : (Print)`
A66	`01`			`@0 DEU`
C01	`01`		`ENG`	`@0 A new sodium cobalt hydrogen borophosphate, NaCoH₂BP₂O₉, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single-crystal x-ray diffraction method]. The structure consists in anionic groups I(H₂BP₂O₉)^3-]₂ (centrosymmetric units [HP(2)O₃O_1/2-HBO₂O₂/₂-P(1)O₃O_1/2]₂) which are interconnected by sharing corners with the Co₂O₁₀ bioctahedral units. The framework connection is reinforced by hydrogen bonds.`
C02	`01`	`3`		`@0 001B60A66F`
C02	`02`	`3`		`@0 001B60A66`
C03	`01`	`3`	`FRE`	`@0 Structure cristalline @5 03`
C03	`01`	`3`	`ENG`	`@0 Crystal structure @5 03`
C03	`02`	`X`	`FRE`	`@0 Méthode hydrothermale @5 04`
C03	`02`	`X`	`ENG`	`@0 Hydrothermal growth @5 04`
C03	`02`	`X`	`SPA`	`@0 Método hidrotermal @5 04`
C03	`03`	`3`	`FRE`	`@0 Diffraction RX @5 05`
C03	`03`	`3`	`ENG`	`@0 XRD @5 05`
C03	`04`	`3`	`FRE`	`@0 Liaison hydrogène @5 06`
C03	`04`	`3`	`ENG`	`@0 Hydrogen bonds @5 06`
C03	`05`	`3`	`FRE`	`@0 Croissance cristalline @5 07`
C03	`05`	`3`	`ENG`	`@0 Crystal growth @5 07`
C03	`06`	`3`	`FRE`	`@0 Distance interatomique @5 08`
C03	`06`	`3`	`ENG`	`@0 Interatomic distances @5 08`
C03	`07`	`3`	`FRE`	`@0 Angle liaison @5 09`
C03	`07`	`3`	`ENG`	`@0 Bond angle @5 09`
C03	`08`	`X`	`FRE`	`@0 Cristal centrosymétrique @5 14`
C03	`08`	`X`	`ENG`	`@0 Centrosymmetrical crystals @5 14`
C03	`08`	`X`	`SPA`	`@0 Cristal centrosimétrico @5 14`
C03	`09`	`3`	`FRE`	`@0 Monocristal @5 17`
C03	`09`	`3`	`ENG`	`@0 Monocrystals @5 17`
C03	`10`	`3`	`FRE`	`@0 Cobalt hydrogénoborophosphate @4 INC @5 53`
C03	`11`	`3`	`FRE`	`@0 Sodium hydrogénoborophosphate @4 INC @5 54`
C03	`12`	`3`	`FRE`	`@0 NaCoH2BP2O9 @4 INC @5 55`
C03	`13`	`3`	`FRE`	`@0 6166F @2 PAC @4 INC @5 56`
C03	`14`	`3`	`FRE`	`@0 B Co H Na O P @4 INC @5 92`
C07	`01`	`3`	`FRE`	`@0 Composé minéral @5 48`
C07	`01`	`3`	`ENG`	`@0 Inorganic compounds @5 48`
N21				`@1 010`
N44	`01`			`@1 PSI`
N82				`@1 PSI`

Format Inist (serveur)

NO :	PASCAL 05-0020473 INIST
ET :	Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH₂BP₂O₉
AU :	GUESMI (Abderrahmen); DRISS (Ahmed)
AF :	Institut préparatoire aux études d'ingénieur, Rue Ibnou Eljazzar/Monastir, 5090/Tunisie (1 aut.); Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences/El Manar, 2092, Tunis/Tunisie (1 aut., 2 aut.)
DT :	Publication en série; Niveau analytique
SO :	Advanced engineering materials : (Print); ISSN 1438-1656; Allemagne; Da. 2004; Vol. 6; No. 10; 796, 840-842 [4 p.]; Bibl. 23 ref.
LA :	Anglais
EA :	A new sodium cobalt hydrogen borophosphate, NaCoH₂BP₂O₉, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single-crystal x-ray diffraction method]. The structure consists in anionic groups I(H₂BP₂O₉)^3-]₂ (centrosymmetric units [HP(2)O₃O_1/2-HBO₂O₂/₂-P(1)O₃O_1/2]₂) which are interconnected by sharing corners with the Co₂O₁₀ bioctahedral units. The framework connection is reinforced by hydrogen bonds.
CC :	001B60A66F; 001B60A66
FD :	Structure cristalline; Méthode hydrothermale; Diffraction RX; Liaison hydrogène; Croissance cristalline; Distance interatomique; Angle liaison; Cristal centrosymétrique; Monocristal; Cobalt hydrogénoborophosphate; Sodium hydrogénoborophosphate; NaCoH2BP2O9; 6166F; B Co H Na O P
FG :	Composé minéral
ED :	Crystal structure; Hydrothermal growth; XRD; Hydrogen bonds; Crystal growth; Interatomic distances; Bond angle; Centrosymmetrical crystals; Monocrystals
EG :	Inorganic compounds
SD :	Método hidrotermal; Cristal centrosimétrico
LO :	INIST-27060.354000122700220110
ID :	05-0020473

Links to Exploration step

Pascal:05-0020473

Le document en format XML

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BP<sub>2</sub>
O<sub>9</sub>
</title>
<author><name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
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<author><name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bond angle</term>
<term>Centrosymmetrical crystals</term>
<term>Crystal growth</term>
<term>Crystal structure</term>
<term>Hydrogen bonds</term>
<term>Hydrothermal growth</term>
<term>Interatomic distances</term>
<term>Monocrystals</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Structure cristalline</term>
<term>Méthode hydrothermale</term>
<term>Diffraction RX</term>
<term>Liaison hydrogène</term>
<term>Croissance cristalline</term>
<term>Distance interatomique</term>
<term>Angle liaison</term>
<term>Cristal centrosymétrique</term>
<term>Monocristal</term>
<term>Cobalt hydrogénoborophosphate</term>
<term>Sodium hydrogénoborophosphate</term>
<term>NaCoH2BP2O9</term>
<term>6166F</term>
<term>B Co H Na O P</term>
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<front><div type="abstract" xml:lang="en">A new sodium cobalt hydrogen borophosphate, NaCoH<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single-crystal x-ray diffraction method]. The structure consists in anionic groups I(H<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
)<sup>3-</sup>
]<sub>2</sub>
 (centrosymmetric units [HP(2)O<sub>3</sub>
O<sub>1/2</sub>
-HBO<sub>2</sub>
O<sub>2</sub>
/<sub>2</sub>
-P(1)O<sub>3</sub>
O<sub>1/2</sub>
]<sub>2</sub>
) which are interconnected by sharing corners with the Co<sub>2</sub>
O<sub>10</sub>
 bioctahedral units. The framework connection is reinforced by hydrogen bonds.</div>
</front>
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BP<sub>2</sub>
O<sub>9</sub>
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<fA11 i1="01" i2="1"><s1>GUESMI (Abderrahmen)</s1>
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<fA11 i1="02" i2="1"><s1>DRISS (Ahmed)</s1>
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<fA14 i1="01"><s1>Institut préparatoire aux études d'ingénieur, Rue Ibnou Eljazzar</s1>
<s2>Monastir, 5090</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences</s1>
<s2>El Manar, 2092, Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<fA20><s2>796, 840-842 [4 p.]</s2>
</fA20>
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<fC01 i1="01" l="ENG"><s0>A new sodium cobalt hydrogen borophosphate, NaCoH<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single-crystal x-ray diffraction method]. The structure consists in anionic groups I(H<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
)<sup>3-</sup>
]<sub>2</sub>
 (centrosymmetric units [HP(2)O<sub>3</sub>
O<sub>1/2</sub>
-HBO<sub>2</sub>
O<sub>2</sub>
/<sub>2</sub>
-P(1)O<sub>3</sub>
O<sub>1/2</sub>
]<sub>2</sub>
) which are interconnected by sharing corners with the Co<sub>2</sub>
O<sub>10</sub>
 bioctahedral units. The framework connection is reinforced by hydrogen bonds.</s0>
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<s5>03</s5>
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<fC03 i1="02" i2="X" l="FRE"><s0>Méthode hydrothermale</s0>
<s5>04</s5>
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<s5>04</s5>
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<s5>04</s5>
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<fC03 i1="03" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>05</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>XRD</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Liaison hydrogène</s0>
<s5>06</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Hydrogen bonds</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Croissance cristalline</s0>
<s5>07</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Crystal growth</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Distance interatomique</s0>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Interatomic distances</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Angle liaison</s0>
<s5>09</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Bond angle</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Cristal centrosymétrique</s0>
<s5>14</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Centrosymmetrical crystals</s0>
<s5>14</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Cristal centrosimétrico</s0>
<s5>14</s5>
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<fC03 i1="09" i2="3" l="FRE"><s0>Monocristal</s0>
<s5>17</s5>
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<fC03 i1="09" i2="3" l="ENG"><s0>Monocrystals</s0>
<s5>17</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Cobalt hydrogénoborophosphate</s0>
<s4>INC</s4>
<s5>53</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Sodium hydrogénoborophosphate</s0>
<s4>INC</s4>
<s5>54</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>NaCoH2BP2O9</s0>
<s4>INC</s4>
<s5>55</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>B Co H Na O P</s0>
<s4>INC</s4>
<s5>92</s5>
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<s5>48</s5>
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<server><NO>PASCAL 05-0020473 INIST</NO>
<ET>Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
</ET>
<AU>GUESMI (Abderrahmen); DRISS (Ahmed)</AU>
<AF>Institut préparatoire aux études d'ingénieur, Rue Ibnou Eljazzar/Monastir, 5090/Tunisie (1 aut.); Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences/El Manar, 2092, Tunis/Tunisie (1 aut., 2 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Advanced engineering materials : (Print); ISSN 1438-1656; Allemagne; Da. 2004; Vol. 6; No. 10; 796, 840-842 [4 p.]; Bibl. 23 ref.</SO>
<LA>Anglais</LA>
<EA>A new sodium cobalt hydrogen borophosphate, NaCoH<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single-crystal x-ray diffraction method]. The structure consists in anionic groups I(H<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
)<sup>3-</sup>
]<sub>2</sub>
 (centrosymmetric units [HP(2)O<sub>3</sub>
O<sub>1/2</sub>
-HBO<sub>2</sub>
O<sub>2</sub>
/<sub>2</sub>
-P(1)O<sub>3</sub>
O<sub>1/2</sub>
]<sub>2</sub>
) which are interconnected by sharing corners with the Co<sub>2</sub>
O<sub>10</sub>
 bioctahedral units. The framework connection is reinforced by hydrogen bonds.</EA>
<CC>001B60A66F; 001B60A66</CC>
<FD>Structure cristalline; Méthode hydrothermale; Diffraction RX; Liaison hydrogène; Croissance cristalline; Distance interatomique; Angle liaison; Cristal centrosymétrique; Monocristal; Cobalt hydrogénoborophosphate; Sodium hydrogénoborophosphate; NaCoH2BP2O9; 6166F; B Co H Na O P</FD>
<FG>Composé minéral</FG>
<ED>Crystal structure; Hydrothermal growth; XRD; Hydrogen bonds; Crystal growth; Interatomic distances; Bond angle; Centrosymmetrical crystals; Monocrystals</ED>
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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH2BP2O9

Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH2BP2O9

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