CobaltMaghrebV1, PascalFrancis, Curation, bibRecord, 000093

Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH2BP2O9

Identifieur interne : 000093 ( PascalFrancis/Curation ); précédent : 000092; suivant : 000094

Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH2BP2O9

Auteurs : Abderrahmen Guesmi [Tunisie] ; Ahmed Driss [Tunisie]

Source :

Advanced engineering materials : (Print) [ 1438-1656 ] ; 2004.

RBID : Pascal:05-0020473

Descripteurs français

Pascal (Inist)
- Structure cristalline, Méthode hydrothermale, Diffraction RX, Liaison hydrogène, Croissance cristalline, Distance interatomique, Angle liaison, Cristal centrosymétrique, Monocristal, Cobalt hydrogénoborophosphate, Sodium hydrogénoborophosphate, NaCoH2BP2O9, 6166F, B Co H Na O P.

English descriptors

KwdEn :
- Bond angle, Centrosymmetrical crystals, Crystal growth, Crystal structure, Hydrogen bonds, Hydrothermal growth, Interatomic distances, Monocrystals, XRD.

Abstract

A new sodium cobalt hydrogen borophosphate, NaCoH₂BP₂O₉, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single-crystal x-ray diffraction method]. The structure consists in anionic groups I(H₂BP₂O₉)^3-]₂ (centrosymmetric units [HP(2)O₃O_1/2-HBO₂O₂/₂-P(1)O₃O_1/2]₂) which are interconnected by sharing corners with the Co₂O₁₀ bioctahedral units. The framework connection is reinforced by hydrogen bonds.

A01	`01`	`1`		`@0 1438-1656`
A03		`1`		`@0 Adv. eng. mater. : (Print)`
A05				`@2 6`
A06				`@2 10`
A08	`01`	`1`	`ENG`	`@1 Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH₂BP₂O₉`
A11	`01`	`1`		`@1 GUESMI (Abderrahmen)`
A11	`02`	`1`		`@1 DRISS (Ahmed)`
A14	`01`			`@1 Institut préparatoire aux études d'ingénieur, Rue Ibnou Eljazzar @2 Monastir, 5090 @3 TUN @Z 1 aut.`
A14	`02`			`@1 Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences @2 El Manar, 2092, Tunis @3 TUN @Z 1 aut. @Z 2 aut.`
A20				`@2 796, 840-842 [4 p.]`
A21				`@1 2004`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 27060 @5 354000122700220110`
A44				`@0 0000 @1 © 2005 INIST-CNRS. All rights reserved.`
A45				`@0 23 ref.`
A47	`01`	`1`		`@0 05-0020473`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Advanced engineering materials : (Print)`
A66	`01`			`@0 DEU`
C01	`01`		`ENG`	`@0 A new sodium cobalt hydrogen borophosphate, NaCoH₂BP₂O₉, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single-crystal x-ray diffraction method]. The structure consists in anionic groups I(H₂BP₂O₉)^3-]₂ (centrosymmetric units [HP(2)O₃O_1/2-HBO₂O₂/₂-P(1)O₃O_1/2]₂) which are interconnected by sharing corners with the Co₂O₁₀ bioctahedral units. The framework connection is reinforced by hydrogen bonds.`
C02	`01`	`3`		`@0 001B60A66F`
C02	`02`	`3`		`@0 001B60A66`
C03	`01`	`3`	`FRE`	`@0 Structure cristalline @5 03`
C03	`01`	`3`	`ENG`	`@0 Crystal structure @5 03`
C03	`02`	`X`	`FRE`	`@0 Méthode hydrothermale @5 04`
C03	`02`	`X`	`ENG`	`@0 Hydrothermal growth @5 04`
C03	`02`	`X`	`SPA`	`@0 Método hidrotermal @5 04`
C03	`03`	`3`	`FRE`	`@0 Diffraction RX @5 05`
C03	`03`	`3`	`ENG`	`@0 XRD @5 05`
C03	`04`	`3`	`FRE`	`@0 Liaison hydrogène @5 06`
C03	`04`	`3`	`ENG`	`@0 Hydrogen bonds @5 06`
C03	`05`	`3`	`FRE`	`@0 Croissance cristalline @5 07`
C03	`05`	`3`	`ENG`	`@0 Crystal growth @5 07`
C03	`06`	`3`	`FRE`	`@0 Distance interatomique @5 08`
C03	`06`	`3`	`ENG`	`@0 Interatomic distances @5 08`
C03	`07`	`3`	`FRE`	`@0 Angle liaison @5 09`
C03	`07`	`3`	`ENG`	`@0 Bond angle @5 09`
C03	`08`	`X`	`FRE`	`@0 Cristal centrosymétrique @5 14`
C03	`08`	`X`	`ENG`	`@0 Centrosymmetrical crystals @5 14`
C03	`08`	`X`	`SPA`	`@0 Cristal centrosimétrico @5 14`
C03	`09`	`3`	`FRE`	`@0 Monocristal @5 17`
C03	`09`	`3`	`ENG`	`@0 Monocrystals @5 17`
C03	`10`	`3`	`FRE`	`@0 Cobalt hydrogénoborophosphate @4 INC @5 53`
C03	`11`	`3`	`FRE`	`@0 Sodium hydrogénoborophosphate @4 INC @5 54`
C03	`12`	`3`	`FRE`	`@0 NaCoH2BP2O9 @4 INC @5 55`
C03	`13`	`3`	`FRE`	`@0 6166F @2 PAC @4 INC @5 56`
C03	`14`	`3`	`FRE`	`@0 B Co H Na O P @4 INC @5 92`
C07	`01`	`3`	`FRE`	`@0 Composé minéral @5 48`
C07	`01`	`3`	`ENG`	`@0 Inorganic compounds @5 48`
N21				`@1 010`
N44	`01`			`@1 PSI`
N82				`@1 PSI`

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Pascal:05-0020473

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
</title>
<author><name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Institut préparatoire aux études d'ingénieur, Rue Ibnou Eljazzar</s1>
<s2>Monastir, 5090</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
</affiliation>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences</s1>
<s2>El Manar, 2092, Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
</affiliation>
</author>
<author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences</s1>
<s2>El Manar, 2092, Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">INIST</idno>
<idno type="inist">05-0020473</idno>
<date when="2004">2004</date>
<idno type="stanalyst">PASCAL 05-0020473 INIST</idno>
<idno type="RBID">Pascal:05-0020473</idno>
<idno type="wicri:Area/PascalFrancis/Corpus">000202</idno>
<idno type="wicri:Area/PascalFrancis/Curation">000093</idno>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
</title>
<author><name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Institut préparatoire aux études d'ingénieur, Rue Ibnou Eljazzar</s1>
<s2>Monastir, 5090</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
</affiliation>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences</s1>
<s2>El Manar, 2092, Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
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<author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences</s1>
<s2>El Manar, 2092, Tunis</s2>
<s3>TUN</s3>
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<country>Tunisie</country>
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<series><title level="j" type="main">Advanced engineering materials : (Print)</title>
<title level="j" type="abbreviated">Adv. eng. mater. : (Print)</title>
<idno type="ISSN">1438-1656</idno>
<imprint><date when="2004">2004</date>
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<seriesStmt><title level="j" type="main">Advanced engineering materials : (Print)</title>
<title level="j" type="abbreviated">Adv. eng. mater. : (Print)</title>
<idno type="ISSN">1438-1656</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bond angle</term>
<term>Centrosymmetrical crystals</term>
<term>Crystal growth</term>
<term>Crystal structure</term>
<term>Hydrogen bonds</term>
<term>Hydrothermal growth</term>
<term>Interatomic distances</term>
<term>Monocrystals</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Structure cristalline</term>
<term>Méthode hydrothermale</term>
<term>Diffraction RX</term>
<term>Liaison hydrogène</term>
<term>Croissance cristalline</term>
<term>Distance interatomique</term>
<term>Angle liaison</term>
<term>Cristal centrosymétrique</term>
<term>Monocristal</term>
<term>Cobalt hydrogénoborophosphate</term>
<term>Sodium hydrogénoborophosphate</term>
<term>NaCoH2BP2O9</term>
<term>6166F</term>
<term>B Co H Na O P</term>
</keywords>
</textClass>
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<front><div type="abstract" xml:lang="en">A new sodium cobalt hydrogen borophosphate, NaCoH<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single-crystal x-ray diffraction method]. The structure consists in anionic groups I(H<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
)<sup>3-</sup>
]<sub>2</sub>
 (centrosymmetric units [HP(2)O<sub>3</sub>
O<sub>1/2</sub>
-HBO<sub>2</sub>
O<sub>2</sub>
/<sub>2</sub>
-P(1)O<sub>3</sub>
O<sub>1/2</sub>
]<sub>2</sub>
) which are interconnected by sharing corners with the Co<sub>2</sub>
O<sub>10</sub>
 bioctahedral units. The framework connection is reinforced by hydrogen bonds.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1438-1656</s0>
</fA01>
<fA03 i2="1"><s0>Adv. eng. mater. : (Print)</s0>
</fA03>
<fA05><s2>6</s2>
</fA05>
<fA06><s2>10</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>GUESMI (Abderrahmen)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>DRISS (Ahmed)</s1>
</fA11>
<fA14 i1="01"><s1>Institut préparatoire aux études d'ingénieur, Rue Ibnou Eljazzar</s1>
<s2>Monastir, 5090</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences</s1>
<s2>El Manar, 2092, Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</fA14>
<fA20><s2>796, 840-842 [4 p.]</s2>
</fA20>
<fA21><s1>2004</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>27060</s2>
<s5>354000122700220110</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2005 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>23 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>05-0020473</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
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<fA64 i1="01" i2="1"><s0>Advanced engineering materials : (Print)</s0>
</fA64>
<fA66 i1="01"><s0>DEU</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>A new sodium cobalt hydrogen borophosphate, NaCoH<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single-crystal x-ray diffraction method]. The structure consists in anionic groups I(H<sub>2</sub>
BP<sub>2</sub>
O<sub>9</sub>
)<sup>3-</sup>
]<sub>2</sub>
 (centrosymmetric units [HP(2)O<sub>3</sub>
O<sub>1/2</sub>
-HBO<sub>2</sub>
O<sub>2</sub>
/<sub>2</sub>
-P(1)O<sub>3</sub>
O<sub>1/2</sub>
]<sub>2</sub>
) which are interconnected by sharing corners with the Co<sub>2</sub>
O<sub>10</sub>
 bioctahedral units. The framework connection is reinforced by hydrogen bonds.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A66F</s0>
</fC02>
<fC02 i1="02" i2="3"><s0>001B60A66</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>03</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>03</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Méthode hydrothermale</s0>
<s5>04</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Hydrothermal growth</s0>
<s5>04</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Método hidrotermal</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>05</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>XRD</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Liaison hydrogène</s0>
<s5>06</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Hydrogen bonds</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Croissance cristalline</s0>
<s5>07</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Crystal growth</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Distance interatomique</s0>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Interatomic distances</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Angle liaison</s0>
<s5>09</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Bond angle</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Cristal centrosymétrique</s0>
<s5>14</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Centrosymmetrical crystals</s0>
<s5>14</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Cristal centrosimétrico</s0>
<s5>14</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Monocristal</s0>
<s5>17</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Monocrystals</s0>
<s5>17</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Cobalt hydrogénoborophosphate</s0>
<s4>INC</s4>
<s5>53</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Sodium hydrogénoborophosphate</s0>
<s4>INC</s4>
<s5>54</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>NaCoH2BP2O9</s0>
<s4>INC</s4>
<s5>55</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>B Co H Na O P</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>48</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>48</s5>
</fC07>
<fN21><s1>010</s1>
</fN21>
<fN44 i1="01"><s1>PSI</s1>
</fN44>
<fN82><s1>PSI</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH2BP2O9

Synthesis, characterization and crystal structure of a new cobalt borophosphate, NaCoH2BP2O9

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Descripteurs français

English descriptors

Abstract

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Links to Exploration step

Le document en format XML

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