Tetrakis(μ-2-phenylacetato-κ2O:O′)bis{[4-(dimethylamino)pyridine-κN1]cobalt(II)}
Identifieur interne : 000208 ( Main/Merge ); précédent : 000207; suivant : 000209Tetrakis(μ-2-phenylacetato-κ2O:O′)bis{[4-(dimethylamino)pyridine-κN1]cobalt(II)}
Auteurs : Meriem Benslimane [Algérie] ; Yasmine Kheira Redjel [Algérie] ; Georges Dénès [Canada] ; Hocine Merazig [Algérie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.
Abstract
The title compound, [Co2(C8H7O2)4(C7H10N2)2], crystallizes as a centrosymmetric dimer containing two CoII atoms bridged by four bidentate phenylacetate ligands in
Url:
DOI: 10.1107/S1600536813023258
PubMed: 24427006
PubMed Central: 3884428
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<italic>O</italic>
:<italic>O</italic>
′)bis{[4-(dimethylamino)pyridine-κ<italic>N</italic>
<sup>1</sup>
]cobalt(II)}</title>
<author><name sortKey="Benslimane, Meriem" sort="Benslimane, Meriem" uniqKey="Benslimane M" first="Meriem" last="Benslimane">Meriem Benslimane</name>
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<country xml:lang="fr">Algérie</country>
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<country xml:lang="fr">Algérie</country>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Tetrakis(μ-2-phenylacetato-κ<sup>2</sup>
<italic>O</italic>
:<italic>O</italic>
′)bis{[4-(dimethylamino)pyridine-κ<italic>N</italic>
<sup>1</sup>
]cobalt(II)}</title>
<author><name sortKey="Benslimane, Meriem" sort="Benslimane, Meriem" uniqKey="Benslimane M" first="Meriem" last="Benslimane">Meriem Benslimane</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
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<country xml:lang="fr">Algérie</country>
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<author><name sortKey="Redjel, Yasmine Kheira" sort="Redjel, Yasmine Kheira" uniqKey="Redjel Y" first="Yasmine Kheira" last="Redjel">Yasmine Kheira Redjel</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
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<country xml:lang="fr">Canada</country>
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<author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
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<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<front><div type="abstract" xml:lang="en"><p>The title compound, [Co<sub>2</sub>
(C<sub>8</sub>
H<sub>7</sub>
O<sub>2</sub>
)<sub>4</sub>
(C<sub>7</sub>
H<sub>10</sub>
N<sub>2</sub>
)<sub>2</sub>
], crystallizes as a centrosymmetric dimer containing two Co<sup>II</sup>
atoms bridged by four bidentate phenylacetate ligands in <italic>syn–syn</italic>
bridging modes. Each Co<sup>II</sup>
atom is five-coordinated by four O atoms from four different carboxylate ligands and the ring N atom of a 4-(dimethylamino)pyridine unit, generating a distorted square-pyramidal geometry in which the four O atoms form the basal plane and the N atom occupies the axial position. In the crystal, C—H⋯O interactions link the dinuclear complex molecules into a three-dimensional network.</p>
</div>
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