Tetra-kis(μ-2-phenyl-acetato-κ(2) O:O')bis-{[4-(di-methyl-amino)-pyridine-κN (1)]cobalt(II)}.
Identifieur interne : 000030 ( PubMed/Curation ); précédent : 000029; suivant : 000031Tetra-kis(μ-2-phenyl-acetato-κ(2) O:O')bis-{[4-(di-methyl-amino)-pyridine-κN (1)]cobalt(II)}.
Auteurs : Meriem Benslimane [Algérie] ; Yasmine Kheira Redjel [Algérie] ; Georges Dénès [Canada] ; Hocine Merazig [Algérie]Source :
- Acta crystallographica. Section E, Structure reports online ; 2013.
Abstract
The title compound, [Co2(C8H7O2)4(C7H10N2)2], crystallizes as a centrosymmetric dimer containing two Co(II) atoms bridged by four bidentate phenyl-acetate ligands in syn-syn bridging modes. Each Co(II) atom is five-coordinated by four O atoms from four different carboxyl-ate ligands and the ring N atom of a 4-(di-methyl-amino)-pyridine unit, generating a distorted square-pyramidal geometry in which the four O atoms form the basal plane and the N atom occupies the axial position. In the crystal, C-H⋯O inter-actions link the dinuclear complex mol-ecules into a three-dimensional network.
DOI: 10.1107/S1600536813023258
PubMed: 24427006
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Constantine</wicri:regionArea></affiliation></author><author><name sortKey="Redjel, Yasmine Kheira" sort="Redjel, Yasmine Kheira" uniqKey="Redjel Y" first="Yasmine Kheira" last="Redjel">Yasmine Kheira Redjel</name><affiliation wicri:level="1"><nlm:affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine, Algeria.</nlm:affiliation><country xml:lang="fr">Algérie</country><wicri:regionArea>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine</wicri:regionArea></affiliation></author><author><name sortKey="Denes, Georges" sort="Denes, Georges" uniqKey="Denes G" first="Georges" last="Dénès">Georges Dénès</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry and Biochemistry, Concordia University, Montréal, Canada.</nlm:affiliation><country xml:lang="fr">Canada</country><wicri:regionArea>Department of Chemistry and Biochemistry, Concordia University, Montréal</wicri:regionArea></affiliation></author><author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name><affiliation wicri:level="1"><nlm:affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine, Algeria.</nlm:affiliation><country xml:lang="fr">Algérie</country><wicri:regionArea>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta crystallographica. 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In the crystal, C-H⋯O inter-actions link the dinuclear complex mol-ecules into a three-dimensional network.</div></front></TEI><pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">24427006</PMID><DateCreated><Year>2014</Year><Month>1</Month><Day>15</Day></DateCreated><DateCompleted><Year>2014</Year><Month>01</Month><Day>15</Day></DateCompleted><DateRevised><Year>2014</Year><Month>1</Month><Day>24</Day></DateRevised><Article PubModel="Electronic-eCollection"><Journal><JournalIssue CitedMedium="Print"><Volume>69</Volume><Issue>Pt 9</Issue><PubDate><Year>2013</Year></PubDate></JournalIssue><Title>Acta crystallographica. Section E, Structure reports online</Title><ISOAbbreviation>Acta Crystallogr Sect E Struct Rep Online</ISOAbbreviation></Journal><ArticleTitle>Tetra-kis(μ-2-phenyl-acetato-κ(2) O:O')bis-{[4-(di-methyl-amino)-pyridine-κN (1)]cobalt(II)}.</ArticleTitle><Pagination><MedlinePgn>m517-8</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1107/S1600536813023258</ELocationID><Abstract><AbstractText>The title compound, [Co2(C8H7O2)4(C7H10N2)2], crystallizes as a centrosymmetric dimer containing two Co(II) atoms bridged by four bidentate phenyl-acetate ligands in syn-syn bridging modes. Each Co(II) atom is five-coordinated by four O atoms from four different carboxyl-ate ligands and the ring N atom of a 4-(di-methyl-amino)-pyridine unit, generating a distorted square-pyramidal geometry in which the four O atoms form the basal plane and the N atom occupies the axial position. In the crystal, C-H⋯O inter-actions link the dinuclear complex mol-ecules into a three-dimensional network.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Benslimane</LastName><ForeName>Meriem</ForeName><Initials>M</Initials><AffiliationInfo><Affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine, Algeria.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Redjel</LastName><ForeName>Yasmine Kheira</ForeName><Initials>YK</Initials><AffiliationInfo><Affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine, Algeria.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Dénès</LastName><ForeName>Georges</ForeName><Initials>G</Initials><AffiliationInfo><Affiliation>Department of Chemistry and Biochemistry, Concordia University, Montréal, Canada.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Merazig</LastName><ForeName>Hocine</ForeName><Initials>H</Initials><AffiliationInfo><Affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine, Algeria.</Affiliation></AffiliationInfo></Author></AuthorList><Language>ENG</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2013</Year><Month>Aug</Month><Day>23</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>Acta Crystallogr Sect E Struct Rep Online</MedlineTA><NlmUniqueID>101089178</NlmUniqueID><ISSNLinking>1600-5368</ISSNLinking></MedlineJournalInfo><OtherID Source="NLM">PMC3884428</OtherID></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2013</Year><Month>8</Month><Day>05</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2013</Year><Month>8</Month><Day>19</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2014</Year><Month>1</Month><Day>16</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2014</Year><Month>1</Month><Day>16</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2014</Year><Month>1</Month><Day>16</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>epublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">24427006</ArticleId><ArticleId IdType="doi">10.1107/S1600536813023258</ArticleId><ArticleId IdType="pii">lr2113</ArticleId><ArticleId IdType="pmc">PMC3884428</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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