CobaltMaghrebV1, Pmc, Checkpoint, bibRecord, 000176

Tetrakis(μ-2-phenylacetato-κ2O:O′)bis{[4-(dimethylamino)pyridine-κN1]cobalt(II)}

Identifieur interne : 000176 ( Pmc/Checkpoint ); précédent : 000175; suivant : 000177

Tetrakis(μ-2-phenylacetato-κ2O:O′)bis{[4-(dimethylamino)pyridine-κN1]cobalt(II)}

Auteurs : Meriem Benslimane [Algérie] ; Yasmine Kheira Redjel [Algérie] ; Georges Dénès [Canada] ; Hocine Merazig [Algérie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.

RBID : PMC:3884428

Abstract

The title compound, [Co₂(C₈H₇O₂)₄(C₇H₁₀N₂)₂], crystallizes as a centrosymmetric dimer containing two Co^II atoms bridged by four bidentate phenylacetate ligands in syn–syn bridging modes. Each Co^II atom is five-coordinated by four O atoms from four different carboxylate ligands and the ring N atom of a 4-(dimethylamino)pyridine unit, generating a distorted square-pyramidal geometry in which the four O atoms form the basal plane and the N atom occupies the axial position. In the crystal, C—H⋯O interactions link the dinuclear complex molecules into a three-dimensional network.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884428

DOI: 10.1107/S1600536813023258
PubMed: 24427006
PubMed Central: 3884428

Affiliations:

Algérie, Canada

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Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Tetrakis(μ-2-phenylacetato-κ<sup>2</sup>
<italic>O</italic>
:<italic>O</italic>
′)bis{[4-(dimethylamino)pyridine-κ<italic>N</italic>
<sup>1</sup>
]cobalt(II)}</title>
<author><name sortKey="Benslimane, Meriem" sort="Benslimane, Meriem" uniqKey="Benslimane M" first="Meriem" last="Benslimane">Meriem Benslimane</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Redjel, Yasmine Kheira" sort="Redjel, Yasmine Kheira" uniqKey="Redjel Y" first="Yasmine Kheira" last="Redjel">Yasmine Kheira Redjel</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Denes, Georges" sort="Denes, Georges" uniqKey="Denes G" first="Georges" last="Dénès">Georges Dénès</name>
<affiliation wicri:level="1"><nlm:aff id="b">Department of Chemistry and Biochemistry, Concordia University, Montréal,<country>Canada</country>
</nlm:aff>
<country xml:lang="fr">Canada</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Tetrakis(μ-2-phenylacetato-κ<sup>2</sup>
<italic>O</italic>
:<italic>O</italic>
′)bis{[4-(dimethylamino)pyridine-κ<italic>N</italic>
<sup>1</sup>
]cobalt(II)}</title>
<author><name sortKey="Benslimane, Meriem" sort="Benslimane, Meriem" uniqKey="Benslimane M" first="Meriem" last="Benslimane">Meriem Benslimane</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Redjel, Yasmine Kheira" sort="Redjel, Yasmine Kheira" uniqKey="Redjel Y" first="Yasmine Kheira" last="Redjel">Yasmine Kheira Redjel</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Denes, Georges" sort="Denes, Georges" uniqKey="Denes G" first="Georges" last="Dénès">Georges Dénès</name>
<affiliation wicri:level="1"><nlm:aff id="b">Department of Chemistry and Biochemistry, Concordia University, Montréal,<country>Canada</country>
</nlm:aff>
<country xml:lang="fr">Canada</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2013">2013</date>
</imprint>
</series>
</biblStruct>
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</teiHeader>
<front><div type="abstract" xml:lang="en"><p>The title compound, [Co<sub>2</sub>
(C<sub>8</sub>
H<sub>7</sub>
O<sub>2</sub>
)<sub>4</sub>
(C<sub>7</sub>
H<sub>10</sub>
N<sub>2</sub>
)<sub>2</sub>
], crystallizes as a centrosymmetric dimer containing two Co<sup>II</sup>
 atoms bridged by four bidentate phenylacetate ligands in <italic>syn–syn</italic>
 bridging modes. Each Co<sup>II</sup>
 atom is five-coordinated by four O atoms from four different carboxylate ligands and the ring N atom of a 4-(dimethylamino)pyridine unit, generating a distorted square-pyramidal geometry in which the four O atoms form the basal plane and the N atom occupies the axial position. In the crystal, C—H⋯O interactions link the dinuclear complex molecules into a three-dimensional network.</p>
</div>
</front>
<back><div1 type="bibliography"><listBibl><biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
</listBibl>
</div1>
</back>
</TEI>
<pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
  <front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id>
<journal-id journal-id-type="iso-abbrev">Acta Crystallogr Sect E Struct Rep Online</journal-id>
<journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id>
<journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title>
</journal-title-group>
<issn pub-type="epub">1600-5368</issn>
<publisher><publisher-name>International Union of Crystallography</publisher-name>
</publisher>
</journal-meta>
<article-meta><article-id pub-id-type="pmid">24427006</article-id>
<article-id pub-id-type="pmc">3884428</article-id>
<article-id pub-id-type="publisher-id">lr2113</article-id>
<article-id pub-id-type="doi">10.1107/S1600536813023258</article-id>
<article-id pub-id-type="coden">ACSEBH</article-id>
<article-id pub-id-type="pii">S1600536813023258</article-id>
<article-categories><subj-group subj-group-type="heading"><subject>Metal-Organic Papers</subject>
</subj-group>
</article-categories>
<title-group><article-title>Tetrakis(μ-2-phenylacetato-κ<sup>2</sup>
<italic>O</italic>
:<italic>O</italic>
′)bis{[4-(dimethylamino)pyridine-κ<italic>N</italic>
<sup>1</sup>
]cobalt(II)}</article-title>
<alt-title><italic>[Co<sub>2</sub>
(C<sub>8</sub>
H<sub>7</sub>
O<sub>2</sub>
)<sub>4</sub>
(C<sub>7</sub>
H<sub>10</sub>
N<sub>2</sub>
)<sub>2</sub>
]</italic>
</alt-title>
</title-group>
<contrib-group><contrib contrib-type="author"><name><surname>Benslimane</surname>
<given-names>Meriem</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
<xref ref-type="corresp" rid="cor">*</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Redjel</surname>
<given-names>Yasmine Kheira</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Dénès</surname>
<given-names>Georges</given-names>
</name>
<xref ref-type="aff" rid="b">b</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Merazig</surname>
<given-names>Hocine</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<aff id="a"><label>a</label>
Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
</aff>
<aff id="b"><label>b</label>
Department of Chemistry and Biochemistry, Concordia University, Montréal,<country>Canada</country>
</aff>
</contrib-group>
<author-notes><corresp id="cor">Correspondence e-mail: <email>b_meriem80@yahoo.fr</email>
</corresp>
</author-notes>
<pub-date pub-type="collection"><day>01</day>
<month>9</month>
<year>2013</year>
</pub-date>
<pub-date pub-type="epub"><day>23</day>
<month>8</month>
<year>2013</year>
</pub-date>
<pub-date pub-type="pmc-release"><day>23</day>
<month>8</month>
<year>2013</year>
</pub-date>
<pmc-comment> PMC Release delay is 0 months and 0 days and was based on the 
 							. </pmc-comment>
      <volume>69</volume>
<issue>Pt 9</issue>
<issue-id pub-id-type="publisher-id">e130900</issue-id>
<fpage>m517</fpage>
<lpage>m518</lpage>
<history><date date-type="received"><day>05</day>
<month>8</month>
<year>2013</year>
</date>
<date date-type="accepted"><day>19</day>
<month>8</month>
<year>2013</year>
</date>
</history>
<permissions><copyright-statement>© Benslimane et al. 2013</copyright-statement>
<copyright-year>2013</copyright-year>
<license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p>
</license>
</permissions>
<self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536813023258">A full version of this article is available from Crystallography Journals Online.</self-uri>
<abstract><p>The title compound, [Co<sub>2</sub>
(C<sub>8</sub>
H<sub>7</sub>
O<sub>2</sub>
)<sub>4</sub>
(C<sub>7</sub>
H<sub>10</sub>
N<sub>2</sub>
)<sub>2</sub>
], crystallizes as a centrosymmetric dimer containing two Co<sup>II</sup>
 atoms bridged by four bidentate phenylacetate ligands in <italic>syn–syn</italic>
 bridging modes. Each Co<sup>II</sup>
 atom is five-coordinated by four O atoms from four different carboxylate ligands and the ring N atom of a 4-(dimethylamino)pyridine unit, generating a distorted square-pyramidal geometry in which the four O atoms form the basal plane and the N atom occupies the axial position. In the crystal, C—H⋯O interactions link the dinuclear complex molecules into a three-dimensional network.</p>
</abstract>
</article-meta>
</front>
<floats-group><table-wrap id="table1" position="float"><label>Table 1</label>
<caption><title>Hydrogen-bond geometry (Å, °)</title>
</caption>
<table frame="hsides" rules="groups"><thead valign="bottom"><tr><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom">H⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H⋯<italic>A</italic>
</th>
</tr>
</thead>
<tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">C6—H6<italic>A</italic>
⋯O2<sup>i</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.96</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.53</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">3.337 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">142</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">C23—H23⋯O3<sup>ii</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.93</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.58</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">3.469 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">159</td>
</tr>
</tbody>
</table>
<table-wrap-foot><p>Symmetry codes: (i) <inline-formula><inline-graphic xlink:href="e-69-0m517-efi2.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (ii) <inline-formula><inline-graphic xlink:href="e-69-0m517-efi3.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
.</p>
</table-wrap-foot>
</table-wrap>
</floats-group>
</pmc>
<affiliations><list><country><li>Algérie</li>
<li>Canada</li>
</country>
</list>
<tree><country name="Algérie"><noRegion><name sortKey="Benslimane, Meriem" sort="Benslimane, Meriem" uniqKey="Benslimane M" first="Meriem" last="Benslimane">Meriem Benslimane</name>
</noRegion>
<name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
<name sortKey="Redjel, Yasmine Kheira" sort="Redjel, Yasmine Kheira" uniqKey="Redjel Y" first="Yasmine Kheira" last="Redjel">Yasmine Kheira Redjel</name>
</country>
<country name="Canada"><noRegion><name sortKey="Denes, Georges" sort="Denes, Georges" uniqKey="Denes G" first="Georges" last="Dénès">Georges Dénès</name>
</noRegion>
</country>
</tree>
</affiliations>
</record>

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Tetra­kis(μ-2-phenyl­acetato-κ2O:O′)bis­{[4-(di­methyl­amino)­pyridine-κN1]cobalt(II)}

Tetra­kis(μ-2-phenyl­acetato-κ2O:O′)bis­{[4-(di­methyl­amino)­pyridine-κN1]cobalt(II)}

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Abstract

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Tetrakis(μ-2-phenylacetato-κ2O:O′)bis{[4-(dimethylamino)pyridine-κN1]cobalt(II)}

Tetrakis(μ-2-phenylacetato-κ2O:O′)bis{[4-(dimethylamino)pyridine-κN1]cobalt(II)}