Crystal structure of alluaudite-type Na4Co(MoO4)3
Identifieur interne : 000161 ( Main/Merge ); précédent : 000160; suivant : 000162Crystal structure of alluaudite-type Na4Co(MoO4)3
Auteurs : Rawia Nasri [Tunisie] ; Noura Fakhar Bourguiba [Tunisie] ; Mohamed Faouzi Zid [Tunisie] ; Ahmed Driss [Tunisie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2014.
Abstract
The title compound, tetrasodium cobalt(II) tris[molybdate(IV)], was prepared by solid-state reactions. The structure is isotypic with Na3In2(AsO4)3 and Na3In2(PO4)3. The main structural feature is the presence of infinite chains of edge-sharing
Url:
DOI: 10.1107/S1600536814016729
PubMed: 25309171
PubMed Central: 4186203
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Co(MoO<sub>4</sub>
)<sub>3</sub>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Crystal structure of alluaudite-type Na<sub>4</sub>
Co(MoO<sub>4</sub>
)<sub>3</sub>
</title>
<author><name sortKey="Nasri, Rawia" sort="Nasri, Rawia" uniqKey="Nasri R" first="Rawia" last="Nasri">Rawia Nasri</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis,<country>Tunisia</country>
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<country xml:lang="fr">Tunisie</country>
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<author><name sortKey="Fakhar Bourguiba, Noura" sort="Fakhar Bourguiba, Noura" uniqKey="Fakhar Bourguiba N" first="Noura" last="Fakhar Bourguiba">Noura Fakhar Bourguiba</name>
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<author><name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name>
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<author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
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<front><div type="abstract" xml:lang="en"><p>The title compound, tetrasodium cobalt(II) tris[molybdate(IV)], was prepared by solid-state reactions. The structure is isotypic with Na<sub>3</sub>
In<sub>2</sub>
(AsO<sub>4</sub>
)<sub>3</sub>
and Na<sub>3</sub>
In<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
. The main structural feature is the presence of infinite chains of edge-sharing <italic>X</italic>
<sub>2</sub>
O<sub>10</sub>
(<italic>X</italic>
= Co/Na) dimers, which are linked by MoO<sub>4</sub>
tetrahedra, forming a three-dimensional framework enclosing two types of hexagonal tunnels in which Na<sup>+</sup>
cations reside. In this alluaudite structure, Co and Na atoms are located at the same general site with occupancies of 0.503 (5) and 0.497 (6), respectively. The other three Na and one of the two Mo atoms lie on special positions (site symmetries 2, -1, 2 and 2, respectively). The structure is compared with similar structures and other members of alluaudite family.</p>
</div>
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