CobaltMaghrebV1, PubMed, Corpus, bibRecord, 000017

Crystal structure of alluaudite-type Na4Co(MoO4)3.

Identifieur interne : 000017 ( PubMed/Corpus ); précédent : 000016; suivant : 000018

Crystal structure of alluaudite-type Na4Co(MoO4)3.

Auteurs : Rawia Nasri ; Noura Fakhar Bourguiba ; Mohamed Faouzi Zid ; Ahmed Driss

Source :

Acta crystallographica. Section E, Structure reports online ; 2014.

RBID : pubmed:25309171

Abstract

The title compound, tetra-sodium cobalt(II) tris-[molyb-date(IV)], was prepared by solid-state reactions. The structure is isotypic with Na3In2(AsO4)3 and Na3In2(PO4)3. The main structural feature is the presence of infinite chains of edge-sharing X 2O10 (X = Co/Na) dimers, which are linked by MoO4 tetra-hedra, forming a three-dimensional framework enclosing two types of hexa-gonal tunnels in which Na(+) cations reside. In this alluaudite structure, Co and Na atoms are located at the same general site with occupancies of 0.503 (5) and 0.497 (6), respectively. The other three Na and one of the two Mo atoms lie on special positions (site symmetries 2, -1, 2 and 2, respectively). The structure is compared with similar structures and other members of alluaudite family.

DOI: 10.1107/S1600536814016729
PubMed: 25309171

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pubmed:25309171

Le document en format XML

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<author><name sortKey="Nasri, Rawia" sort="Nasri, Rawia" uniqKey="Nasri R" first="Rawia" last="Nasri">Rawia Nasri</name>
<affiliation><nlm:affiliation>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis, Tunisia.</nlm:affiliation>
</affiliation>
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<author><name sortKey="Fakhar Bourguiba, Noura" sort="Fakhar Bourguiba, Noura" uniqKey="Fakhar Bourguiba N" first="Noura" last="Fakhar Bourguiba">Noura Fakhar Bourguiba</name>
<affiliation><nlm:affiliation>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis, Tunisia.</nlm:affiliation>
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<author><name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name>
<affiliation><nlm:affiliation>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis, Tunisia.</nlm:affiliation>
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<author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
<affiliation><nlm:affiliation>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis, Tunisia.</nlm:affiliation>
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<sourceDesc><biblStruct><analytic><title xml:lang="en">Crystal structure of alluaudite-type Na4Co(MoO4)3.</title>
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<author><name sortKey="Fakhar Bourguiba, Noura" sort="Fakhar Bourguiba, Noura" uniqKey="Fakhar Bourguiba N" first="Noura" last="Fakhar Bourguiba">Noura Fakhar Bourguiba</name>
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<author><name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name>
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<author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
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<series><title level="j">Acta crystallographica. Section E, Structure reports online</title>
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<front><div type="abstract" xml:lang="en">The title compound, tetra-sodium cobalt(II) tris-[molyb-date(IV)], was prepared by solid-state reactions. The structure is isotypic with Na3In2(AsO4)3 and Na3In2(PO4)3. The main structural feature is the presence of infinite chains of edge-sharing X 2O10 (X = Co/Na) dimers, which are linked by MoO4 tetra-hedra, forming a three-dimensional framework enclosing two types of hexa-gonal tunnels in which Na(+) cations reside. In this alluaudite structure, Co and Na atoms are located at the same general site with occupancies of 0.503 (5) and 0.497 (6), respectively. The other three Na and one of the two Mo atoms lie on special positions (site symmetries 2, -1, 2 and 2, respectively). The structure is compared with similar structures and other members of alluaudite family.</div>
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<Abstract><AbstractText>The title compound, tetra-sodium cobalt(II) tris-[molyb-date(IV)], was prepared by solid-state reactions. The structure is isotypic with Na3In2(AsO4)3 and Na3In2(PO4)3. The main structural feature is the presence of infinite chains of edge-sharing X 2O10 (X = Co/Na) dimers, which are linked by MoO4 tetra-hedra, forming a three-dimensional framework enclosing two types of hexa-gonal tunnels in which Na(+) cations reside. In this alluaudite structure, Co and Na atoms are located at the same general site with occupancies of 0.503 (5) and 0.497 (6), respectively. The other three Na and one of the two Mo atoms lie on special positions (site symmetries 2, -1, 2 and 2, respectively). The structure is compared with similar structures and other members of alluaudite family.</AbstractText>
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<KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">X-ray diffraction</Keyword>
<Keyword MajorTopicYN="N">alluaudite</Keyword>
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Crystal structure of alluaudite-type Na4Co(MoO4)3.

Crystal structure of alluaudite-type Na4Co(MoO4)3.

Source :

Abstract

Links to Exploration step

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Pour manipuler ce document sous Unix (Dilib)

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Pour générer des pages wiki