Crystal structure of bis(4-nitroaniline-κN1)(5,10,15,20-tetraphenylporphyrinato-κ4N)cobalt(III) chloride dichloromethane monosolvate
Identifieur interne : 000160 ( Main/Merge ); précédent : 000159; suivant : 000161Crystal structure of bis(4-nitroaniline-κN1)(5,10,15,20-tetraphenylporphyrinato-κ4N)cobalt(III) chloride dichloromethane monosolvate
Auteurs : Yassine Belghith [Tunisie] ; Anissa Mansour [Arabie saoudite] ; Habib Nasri [Tunisie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2014.
Abstract
The reaction of [CoIII(TPP)Cl] (TPP is the dianion of 5,10,15,20-tetraphenylporphyrin) with an excess of 4-nitroaniline in dichloromethane leads to the title compound, [CoIII(C44H28N4)(C6H6N2O2)2]Cl·CH2Cl2. The CoIII ion lies on an inversion centre and is octahedrally coordinated by two N atoms of the NH2 groups of the two 4-nitroaniline
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DOI: 10.1107/S1600536814016274
PubMed: 25309176
PubMed Central: 4186082
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)(5,10,15,20-tetraphenylporphyrinato-κ<sup>4</sup>
<italic>N</italic>
)cobalt(III) chloride dichloromethane monosolvate</title>
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<author><name sortKey="Nasri, Habib" sort="Nasri, Habib" uniqKey="Nasri H" first="Habib" last="Nasri">Habib Nasri</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Crystal structure of bis(4-nitroaniline-κ<italic>N</italic>
<sup>1</sup>
)(5,10,15,20-tetraphenylporphyrinato-κ<sup>4</sup>
<italic>N</italic>
)cobalt(III) chloride dichloromethane monosolvate</title>
<author><name sortKey="Belghith, Yassine" sort="Belghith, Yassine" uniqKey="Belghith Y" first="Yassine" last="Belghith">Yassine Belghith</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l’environnement, 5019 Monastir, University of Monastir,<country>Tunisia</country>
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<country xml:lang="fr">Tunisie</country>
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<author><name sortKey="Mansour, Anissa" sort="Mansour, Anissa" uniqKey="Mansour A" first="Anissa" last="Mansour">Anissa Mansour</name>
<affiliation wicri:level="1"><nlm:aff id="b">University of Dammam, PO Box 1982, Dammam, Kingdom of<country>Saudi Arabia</country>
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<country xml:lang="fr">Arabie saoudite</country>
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<author><name sortKey="Nasri, Habib" sort="Nasri, Habib" uniqKey="Nasri H" first="Habib" last="Nasri">Habib Nasri</name>
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<country xml:lang="fr">Tunisie</country>
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<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
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<front><div type="abstract" xml:lang="en"><p>The reaction of [Co<sup>III</sup>
(TPP)Cl] (TPP is the dianion of 5,10,15,20-tetraphenylporphyrin) with an excess of 4-nitroaniline in dichloromethane leads to the title compound, [Co<sup>III</sup>
(C<sub>44</sub>
H<sub>28</sub>
N<sub>4</sub>
)(C<sub>6</sub>
H<sub>6</sub>
N<sub>2</sub>
O<sub>2</sub>
)<sub>2</sub>
]Cl·CH<sub>2</sub>
Cl<sub>2</sub>
. The Co<sup>III</sup>
ion lies on an inversion centre and is octahedrally coordinated by two N atoms of the NH<sub>2</sub>
groups of the two 4-nitroaniline <italic>trans</italic>
-axial ligands and four pyrrole N atoms of the porphyrin. The asymmetric unit contains one half of the [Co<sup>III</sup>
(TPP)(4-nitroaniline)<sub>2</sub>
]<sup>+</sup>
ion complex, one chloride counter-ion (lying on a twofold rotation axis) and one half dichloromethane solvent molecule, where the C atom lies on a twofold rotation axis. The average equatorial Co—N(pyrrole) distance (Co—Np) is 1.982 (2) Å and the axial Co—N(4-nitroaniline) bond length is 2.006 (2) Å. The crystal packing is stabilized by an N—H⋯Cl hydrogen bond between the N atom of the amino group of the 4-nitroaniline axial ligand and the chloride counter-ion. The supramolecular architecture is further stabilized by weak C—H⋯π interactions.</p>
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