CobaltMaghrebV1, Main, Curation, bibRecord, 000E09

A New Nasicon-Type Phosphate:Co0.5Ti2(PO4)3II. Simulation of Optical and Magnetic Properties

Identifieur interne : 000E09 ( Main/Curation ); précédent : 000E08; suivant : 000E10

A New Nasicon-Type Phosphate:Co0.5Ti2(PO4)3II. Simulation of Optical and Magnetic Properties

Auteurs : J. Derouet [France] ; L. Beaury [France] ; P. Porcher [France] ; R. Olazcuaga [France] ; J. M. Dance [France] ; G. Le Flem [France] ; A. El Bouari [Maroc] ; A. El Jazouli [Maroc]

Source :

Journal of Solid State Chemistry [ 0022-4596 ] ; 1999.

RBID : ISTEX:BD8CE3E5836376F805B024A2E41B8B6493B2AEBE

Descripteurs français

Pascal (Inist)
- 7170C, 7530C, Champ cristallin, Co O P Ti, Co0,5Ti2(PO4)3, Cobalt phosphate, Composé quaternaire, Etude théorique, Facteur g, Modèle phénoménologique, Méthode semiempirique, Niveau énergie, Polycristal, Susceptibilité magnétique, Titane phosphate.

English descriptors

KwdEn :
- Cobalt phosphates, Crystal field, Energy levels, Magnetic susceptibility, Phenomenological model, Polycrystals, Quaternary compounds, Semiempirical method, Theoretical study, Titanium phosphates, g-factor.

Abstract

The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature andgvalues) of the polycrystalline Co0.5Ti2(PO4)3were simultaneously reproduced by use of a crystal field theory involving a set ofFk,ζ, free ion, andBkqcrystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assignR32 as the space group of the crystal structure.

Url:

https://api.istex.fr/document/BD8CE3E5836376F805B024A2E41B8B6493B2AEBE/fulltext/pdf

DOI: 10.1006/jssc.1998.8098

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Le document en format XML

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<front><div type="abstract" xml:lang="en">The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature andgvalues) of the polycrystalline Co0.5Ti2(PO4)3were simultaneously reproduced by use of a crystal field theory involving a set ofFk,ζ, free ion, andBkqcrystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assignR32 as the space group of the crystal structure.</div>
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. II. Simulation of optical and magnetic properties</title>
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<author><name sortKey="Le Flem, G" sort="Le Flem, G" uniqKey="Le Flem G" first="G." last="Le Flem">G. Le Flem</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Institut de Chimie de la Matière Condensée, CNRS-UPR9048, Av. Dr Schweitzer</s1>
<s2>33608 Pessac</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region>
<region type="old region" nuts="2">Aquitaine</region>
<settlement type="city">Pessac</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="El Bouari, A" sort="El Bouari, A" uniqKey="El Bouari A" first="A." last="El Bouari">A. El Bouari</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Département de Chimie, Faculté des Sciences M'Sik Sidi Othmane, BP 6621</s1>
<s2>Casablanca</s2>
<s3>MAR</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>Casablanca</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="El Jazouli, A" sort="El Jazouli, A" uniqKey="El Jazouli A" first="A." last="El Jazouli">A. El Jazouli</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Département de Chimie, Faculté des Sciences M'Sik Sidi Othmane, BP 6621</s1>
<s2>Casablanca</s2>
<s3>MAR</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>Casablanca</wicri:noRegion>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Journal of solid state chemistry</title>
<title level="j" type="abbreviated">J. solid state chem.</title>
<idno type="ISSN">0022-4596</idno>
<imprint><date when="1999">1999</date>
</imprint>
</series>
</biblStruct>
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<seriesStmt><title level="j" type="main">Journal of solid state chemistry</title>
<title level="j" type="abbreviated">J. solid state chem.</title>
<idno type="ISSN">0022-4596</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cobalt phosphates</term>
<term>Crystal field</term>
<term>Energy levels</term>
<term>Magnetic susceptibility</term>
<term>Phenomenological model</term>
<term>Polycrystals</term>
<term>Quaternary compounds</term>
<term>Semiempirical method</term>
<term>Theoretical study</term>
<term>Titanium phosphates</term>
<term>g-factor</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude théorique</term>
<term>Cobalt phosphate</term>
<term>Titane phosphate</term>
<term>Composé quaternaire</term>
<term>Susceptibilité magnétique</term>
<term>Modèle phénoménologique</term>
<term>Méthode semiempirique</term>
<term>Niveau énergie</term>
<term>Facteur g</term>
<term>Champ cristallin</term>
<term>Polycristal</term>
<term>7170C</term>
<term>7530C</term>
<term>Co0,5Ti2(PO4)3</term>
<term>Co O P Ti</term>
</keywords>
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<front><div type="abstract" xml:lang="en">The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature and g values) of the polycrystalline Co<sub>0.5</sub>
Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
 were simultaneously reproduced by use of a crystal field theory involving a set of F<sup>k</sup>
,ζ, free ion, and B<sup>k</sup>
<sub>q</sub>
 crystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assign R32 as the space group of the crystal structure.</div>
</front>
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<author><name sortKey="Derouet, J" sort="Derouet, J" uniqKey="Derouet J" first="J." last="Derouet">J. Derouet</name>
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<author><name sortKey="Beaury, L" sort="Beaury, L" uniqKey="Beaury L" first="L." last="Beaury">L. Beaury</name>
</author>
<author><name sortKey="Porcher, P" sort="Porcher, P" uniqKey="Porcher P" first="P." last="Porcher">P. Porcher</name>
</author>
<author><name sortKey="Olazcuaga, R" sort="Olazcuaga, R" uniqKey="Olazcuaga R" first="R." last="Olazcuaga">R. Olazcuaga</name>
</author>
<author><name sortKey="Dance, J M" sort="Dance, J M" uniqKey="Dance J" first="J. M." last="Dance">J. M. Dance</name>
</author>
<author><name sortKey="Flem, G Le" sort="Flem, G Le" uniqKey="Flem G" first="G. Le" last="Flem">G. Le Flem</name>
</author>
<author><name sortKey="Bouari, A El" sort="Bouari, A El" uniqKey="Bouari A" first="A. El" last="Bouari">A. El Bouari</name>
</author>
<author><name sortKey="Jazouli, A El" sort="Jazouli, A El" uniqKey="Jazouli A" first="A. El" last="Jazouli">A. El Jazouli</name>
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<author><name sortKey="Derouet, J" sort="Derouet, J" uniqKey="Derouet J" first="J." last="Derouet">J. Derouet</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire de Chimie Appliquée de l'Etat Solide, ENSCP, 11 rue Pierre et Marie Curie, F-75231, Paris Cedex 05</wicri:regionArea>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Beaury, L" sort="Beaury, L" uniqKey="Beaury L" first="L." last="Beaury">L. Beaury</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire de Chimie Appliquée de l'Etat Solide, ENSCP, 11 rue Pierre et Marie Curie, F-75231, Paris Cedex 05</wicri:regionArea>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Porcher, P" sort="Porcher, P" uniqKey="Porcher P" first="P." last="Porcher">P. Porcher</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire de Chimie Appliquée de l'Etat Solide, ENSCP, 11 rue Pierre et Marie Curie, F-75231, Paris Cedex 05</wicri:regionArea>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Olazcuaga, R" sort="Olazcuaga, R" uniqKey="Olazcuaga R" first="R." last="Olazcuaga">R. Olazcuaga</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>Institut de Chimie de la Matière Condensée, CNRS-UPR9048, Av. Dr Schweitzer, F-33608, Pessac</wicri:regionArea>
<placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region>
<region type="old region" nuts="2">Aquitaine</region>
<settlement type="city">Pessac</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Dance, J M" sort="Dance, J M" uniqKey="Dance J" first="J. M." last="Dance">J. M. Dance</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>Institut de Chimie de la Matière Condensée, CNRS-UPR9048, Av. Dr Schweitzer, F-33608, Pessac</wicri:regionArea>
<placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region>
<region type="old region" nuts="2">Aquitaine</region>
<settlement type="city">Pessac</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Flem, G Le" sort="Flem, G Le" uniqKey="Flem G" first="G. Le" last="Flem">G. Le Flem</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>Institut de Chimie de la Matière Condensée, CNRS-UPR9048, Av. Dr Schweitzer, F-33608, Pessac</wicri:regionArea>
<placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region>
<region type="old region" nuts="2">Aquitaine</region>
<settlement type="city">Pessac</settlement>
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</author>
<author><name sortKey="Bouari, A El" sort="Bouari, A El" uniqKey="Bouari A" first="A. El" last="Bouari">A. El Bouari</name>
<affiliation wicri:level="1"><country xml:lang="fr">Maroc</country>
<wicri:regionArea>Département de Chimie, Faculté des Sciences M'Sik Sidi Othmane, 6621, Casablanca</wicri:regionArea>
<wicri:noRegion>Casablanca</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Jazouli, A El" sort="Jazouli, A El" uniqKey="Jazouli A" first="A. El" last="Jazouli">A. El Jazouli</name>
<affiliation wicri:level="1"><country xml:lang="fr">Maroc</country>
<wicri:regionArea>Département de Chimie, Faculté des Sciences M'Sik Sidi Othmane, 6621, Casablanca</wicri:regionArea>
<wicri:noRegion>Casablanca</wicri:noRegion>
</affiliation>
</author>
</analytic>
<monogr></monogr>
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<title level="j" type="abbrev">YJSSC</title>
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<imprint><publisher>ELSEVIER</publisher>
<date type="published" when="1999">1999</date>
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<front><div type="abstract" xml:lang="en">The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature andgvalues) of the polycrystalline Co0.5Ti2(PO4)3were simultaneously reproduced by use of a crystal field theory involving a set ofFk,ζ, free ion, andBkqcrystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assignR32 as the space group of the crystal structure.</div>
</front>
</TEI>
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A New Nasicon-Type Phosphate:Co0.5Ti2(PO4)3II. Simulation of Optical and Magnetic Properties

A New Nasicon-Type Phosphate:Co0.5Ti2(PO4)3II. Simulation of Optical and Magnetic Properties

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