A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties
Identifieur interne : 000333 ( France/Analysis ); précédent : 000332; suivant : 000334A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties
Auteurs : R. Olazcuaga [France] ; J. M Dance [France] ; G. Le Flem [France] ; J. Derouet [France] ; L. Beaury [France] ; P. Porcher [France] ; A. El Bouari [Maroc] ; A. El Jazouli [Maroc]Source :
- Journal of Solid State Chemistry [ 0022-4596 ] ; 1999.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with theR3or theR32 space groups. The atomic arrangement is a three-dimensional framework formed by PO4tetrahedra sharing corners with TiO6octahedra. Co2+is located in half of the antiprismM(1) sites in a centered (R3) or off- centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co–O bond.
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DOI: 10.1006/jssc.1998.8097
Affiliations:
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<term>ESR</term>
<term>Experimental study</term>
<term>Magnetic properties</term>
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<front><div type="abstract" xml:lang="en">A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with theR3or theR32 space groups. The atomic arrangement is a three-dimensional framework formed by PO4tetrahedra sharing corners with TiO6octahedra. Co2+is located in half of the antiprismM(1) sites in a centered (R3) or off- centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co–O bond.</div>
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