A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties
Identifieur interne : 000473 ( Istex/Corpus ); précédent : 000472; suivant : 000474A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties
Auteurs : R. Olazcuaga ; J. M Dance ; G. Le Flem ; J. Derouet ; L. Beaury ; P. Porcher ; A. El Bouari ; A. El JazouliSource :
- Journal of Solid State Chemistry [ 0022-4596 ] ; 1999.
Abstract
A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with theR3or theR32 space groups. The atomic arrangement is a three-dimensional framework formed by PO4tetrahedra sharing corners with TiO6octahedra. Co2+is located in half of the antiprismM(1) sites in a centered (R3) or off- centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co–O bond.
Url:
DOI: 10.1006/jssc.1998.8097
Links to Exploration step
ISTEX:7EA26E1087D5A09E41F4A2B3CD8F29121642B61BLe document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties</title><author><name sortKey="Olazcuaga, R" sort="Olazcuaga, R" uniqKey="Olazcuaga R" first="R" last="Olazcuaga">R. Olazcuaga</name><affiliation><mods:affiliation>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Dance, J M" sort="Dance, J M" uniqKey="Dance J" first="J. M" last="Dance">J. M Dance</name><affiliation><mods:affiliation>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Flem, G Le" sort="Flem, G Le" uniqKey="Flem G" first="G. Le" last="Flem">G. Le Flem</name><affiliation><mods:affiliation>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Derouet, J" sort="Derouet, J" uniqKey="Derouet J" first="J" last="Derouet">J. Derouet</name><affiliation><mods:affiliation>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Beaury, L" sort="Beaury, L" uniqKey="Beaury L" first="L" last="Beaury">L. Beaury</name><affiliation><mods:affiliation>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Porcher, P" sort="Porcher, P" uniqKey="Porcher P" first="P" last="Porcher">P. Porcher</name><affiliation><mods:affiliation>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Bouari, A El" sort="Bouari, A El" uniqKey="Bouari A" first="A. El" last="Bouari">A. El Bouari</name><affiliation><mods:affiliation>Laboratoire de Chimie des Matériaux Solides, Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, 6621, Casablanca, Morocco</mods:affiliation></affiliation></author><author><name sortKey="Jazouli, A El" sort="Jazouli, A El" uniqKey="Jazouli A" first="A. El" last="Jazouli">A. El Jazouli</name><affiliation><mods:affiliation>Laboratoire de Chimie des Matériaux Solides, Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, 6621, Casablanca, Morocco</mods:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:7EA26E1087D5A09E41F4A2B3CD8F29121642B61B</idno><date when="1999" year="1999">1999</date><idno type="doi">10.1006/jssc.1998.8097</idno><idno type="url">https://api.istex.fr/document/7EA26E1087D5A09E41F4A2B3CD8F29121642B61B/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">000473</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000473</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties</title><author><name sortKey="Olazcuaga, R" sort="Olazcuaga, R" uniqKey="Olazcuaga R" first="R" last="Olazcuaga">R. Olazcuaga</name><affiliation><mods:affiliation>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Dance, J M" sort="Dance, J M" uniqKey="Dance J" first="J. M" last="Dance">J. M Dance</name><affiliation><mods:affiliation>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Flem, G Le" sort="Flem, G Le" uniqKey="Flem G" first="G. Le" last="Flem">G. Le Flem</name><affiliation><mods:affiliation>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Derouet, J" sort="Derouet, J" uniqKey="Derouet J" first="J" last="Derouet">J. Derouet</name><affiliation><mods:affiliation>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Beaury, L" sort="Beaury, L" uniqKey="Beaury L" first="L" last="Beaury">L. Beaury</name><affiliation><mods:affiliation>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Porcher, P" sort="Porcher, P" uniqKey="Porcher P" first="P" last="Porcher">P. Porcher</name><affiliation><mods:affiliation>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Bouari, A El" sort="Bouari, A El" uniqKey="Bouari A" first="A. El" last="Bouari">A. El Bouari</name><affiliation><mods:affiliation>Laboratoire de Chimie des Matériaux Solides, Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, 6621, Casablanca, Morocco</mods:affiliation></affiliation></author><author><name sortKey="Jazouli, A El" sort="Jazouli, A El" uniqKey="Jazouli A" first="A. El" last="Jazouli">A. El Jazouli</name><affiliation><mods:affiliation>Laboratoire de Chimie des Matériaux Solides, Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, 6621, Casablanca, Morocco</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Journal of Solid State Chemistry</title><title level="j" type="abbrev">YJSSC</title><idno type="ISSN">0022-4596</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1999">1999</date><biblScope unit="volume">143</biblScope><biblScope unit="issue">2</biblScope><biblScope unit="page" from="224">224</biblScope><biblScope unit="page" to="229">229</biblScope></imprint><idno type="ISSN">0022-4596</idno></series><idno type="istex">7EA26E1087D5A09E41F4A2B3CD8F29121642B61B</idno><idno type="DOI">10.1006/jssc.1998.8097</idno><idno type="PII">S0022-4596(98)98097-5</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0022-4596</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with theR3or theR32 space groups. The atomic arrangement is a three-dimensional framework formed by PO4tetrahedra sharing corners with TiO6octahedra. Co2+is located in half of the antiprismM(1) sites in a centered (R3) or off- centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co–O bond.</div></front></TEI><istex><corpusName>elsevier</corpusName><author><json:item><name>R Olazcuaga</name><affiliations><json:string>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</json:string></affiliations></json:item><json:item><name>J.M Dance</name><affiliations><json:string>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</json:string></affiliations></json:item><json:item><name>G.Le Flem</name><affiliations><json:string>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</json:string></affiliations></json:item><json:item><name>J Derouet</name><affiliations><json:string>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</json:string></affiliations></json:item><json:item><name>L Beaury</name><affiliations><json:string>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</json:string></affiliations></json:item><json:item><name>P Porcher</name><affiliations><json:string>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</json:string></affiliations></json:item><json:item><name>A.El Bouari</name><affiliations><json:string>Laboratoire de Chimie des Matériaux Solides, Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, 6621, Casablanca, Morocco</json:string></affiliations></json:item><json:item><name>A.El Jazouli</name><affiliations><json:string>Laboratoire de Chimie des Matériaux Solides, Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, 6621, Casablanca, Morocco</json:string></affiliations></json:item></author><language><json:string>eng</json:string></language><originalGenre><json:string>Full-length article</json:string></originalGenre><abstract>A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with theR3or theR32 space groups. The atomic arrangement is a three-dimensional framework formed by PO4tetrahedra sharing corners with TiO6octahedra. Co2+is located in half of the antiprismM(1) sites in a centered (R3) or off- centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co–O bond.</abstract><qualityIndicators><score>3.412</score><pdfVersion>1.2</pdfVersion><pdfPageSize>615 x 789 pts</pdfPageSize><refBibsNative>true</refBibsNative><keywordCount>0</keywordCount><abstractCharCount>518</abstractCharCount><pdfWordCount>2488</pdfWordCount><pdfCharCount>14151</pdfCharCount><pdfPageCount>6</pdfPageCount><abstractWordCount>77</abstractWordCount></qualityIndicators><title>A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties</title><pii><json:string>S0022-4596(98)98097-5</json:string></pii><genre><json:string>research-article</json:string></genre><host><volume>143</volume><pii><json:string>S0022-4596(00)X0040-0</json:string></pii><pages><last>229</last><first>224</first></pages><issn><json:string>0022-4596</json:string></issn><issue>2</issue><genre><json:string>journal</json:string></genre><language><json:string>unknown</json:string></language><title>Journal of Solid State Chemistry</title><publicationDate>1999</publicationDate></host><categories><wos><json:string>CHEMISTRY, INORGANIC & NUCLEAR</json:string><json:string>CHEMISTRY, PHYSICAL</json:string></wos></categories><publicationDate>1999</publicationDate><copyrightDate>1999</copyrightDate><doi><json:string>10.1006/jssc.1998.8097</json:string></doi><id>7EA26E1087D5A09E41F4A2B3CD8F29121642B61B</id><score>0.13813703</score><fulltext><json:item><original>true</original><mimetype>application/pdf</mimetype><extension>pdf</extension><uri>https://api.istex.fr/document/7EA26E1087D5A09E41F4A2B3CD8F29121642B61B/fulltext/pdf</uri></json:item><json:item><original>false</original><mimetype>application/zip</mimetype><extension>zip</extension><uri>https://api.istex.fr/document/7EA26E1087D5A09E41F4A2B3CD8F29121642B61B/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/7EA26E1087D5A09E41F4A2B3CD8F29121642B61B/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>ELSEVIER</publisher><availability><p>©1999 Academic Press</p></availability><date>1999</date></publicationStmt><notesStmt><note type="content">Section title: Regular Article</note></notesStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a" type="main" xml:lang="en">A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties</title><author xml:id="author-1"><persName><forename type="first">R</forename><surname>Olazcuaga</surname></persName><affiliation>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</affiliation></author><author xml:id="author-2"><persName><forename type="first">J.M</forename><surname>Dance</surname></persName><affiliation>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</affiliation></author><author xml:id="author-3"><persName><forename type="first">G.Le</forename><surname>Flem</surname></persName><affiliation>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</affiliation></author><author xml:id="author-4"><persName><forename type="first">J</forename><surname>Derouet</surname></persName><affiliation>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</affiliation></author><author xml:id="author-5"><persName><forename type="first">L</forename><surname>Beaury</surname></persName><affiliation>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</affiliation></author><author xml:id="author-6"><persName><forename type="first">P</forename><surname>Porcher</surname></persName><affiliation>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</affiliation></author><author xml:id="author-7"><persName><forename type="first">A.El</forename><surname>Bouari</surname></persName><affiliation>Laboratoire de Chimie des Matériaux Solides, Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, 6621, Casablanca, Morocco</affiliation></author><author xml:id="author-8"><persName><forename type="first">A.El</forename><surname>Jazouli</surname></persName><affiliation>Laboratoire de Chimie des Matériaux Solides, Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, 6621, Casablanca, Morocco</affiliation></author></analytic><monogr><title level="j">Journal of Solid State Chemistry</title><title level="j" type="abbrev">YJSSC</title><idno type="pISSN">0022-4596</idno><idno type="PII">S0022-4596(00)X0040-0</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1999"></date><biblScope unit="volume">143</biblScope><biblScope unit="issue">2</biblScope><biblScope unit="page" from="224">224</biblScope><biblScope unit="page" to="229">229</biblScope></imprint></monogr><idno type="istex">7EA26E1087D5A09E41F4A2B3CD8F29121642B61B</idno><idno type="DOI">10.1006/jssc.1998.8097</idno><idno type="PII">S0022-4596(98)98097-5</idno></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>1999</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en"><p>A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with theR3or theR32 space groups. The atomic arrangement is a three-dimensional framework formed by PO4tetrahedra sharing corners with TiO6octahedra. Co2+is located in half of the antiprismM(1) sites in a centered (R3) or off- centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co–O bond.</p></abstract></profileDesc><revisionDesc><change when="1998-11-04">Modified</change><change when="1999">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><original>false</original><mimetype>text/plain</mimetype><extension>txt</extension><uri>https://api.istex.fr/document/7EA26E1087D5A09E41F4A2B3CD8F29121642B61B/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: tail"><istex:xmlDeclaration>version="1.0" encoding="utf-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"></istex:docType><istex:document><converted-article version="4.5.2" docsubtype="fla" xml:lang="en"><item-info><jid>YJSSC</jid><aid>98097</aid><ce:pii>S0022-4596(98)98097-5</ce:pii><ce:doi>10.1006/jssc.1998.8097</ce:doi><ce:copyright type="full-transfer" year="1999">Academic Press</ce:copyright></item-info><head><ce:dochead><ce:textfn>Regular Article</ce:textfn></ce:dochead><ce:title>A New Nasicon-Type Phosphate Co<ce:inf>0.5</ce:inf>Ti<ce:inf>2</ce:inf>(PO<ce:inf>4</ce:inf>)<ce:inf>3</ce:inf>: I. Elaboration, Optical and Magnetic Properties</ce:title><ce:author-group><ce:author><ce:given-name>R</ce:given-name><ce:surname>Olazcuaga</ce:surname><ce:cross-ref refid="QA1"><ce:sup>a</ce:sup></ce:cross-ref><ce:cross-ref refid="QFN1"><ce:sup>1</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>J.M</ce:given-name><ce:surname>Dance</ce:surname><ce:cross-ref refid="QA1"><ce:sup>a</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>G.Le</ce:given-name><ce:surname>Flem</ce:surname><ce:cross-ref refid="QA1"><ce:sup>a</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>J</ce:given-name><ce:surname>Derouet</ce:surname><ce:cross-ref refid="QA2"><ce:sup>b</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>L</ce:given-name><ce:surname>Beaury</ce:surname><ce:cross-ref refid="QA2"><ce:sup>b</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>P</ce:given-name><ce:surname>Porcher</ce:surname><ce:cross-ref refid="QA2"><ce:sup>b</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>A.El</ce:given-name><ce:surname>Bouari</ce:surname><ce:cross-ref refid="QA3"><ce:sup>c</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>A.El</ce:given-name><ce:surname>Jazouli</ce:surname><ce:cross-ref refid="QA3"><ce:sup>c</ce:sup></ce:cross-ref></ce:author><ce:affiliation id="QA1"><ce:label>a</ce:label><ce:textfn>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</ce:textfn></ce:affiliation><ce:affiliation id="QA2"><ce:label>b</ce:label><ce:textfn>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</ce:textfn></ce:affiliation><ce:affiliation id="QA3"><ce:label>c</ce:label><ce:textfn>Laboratoire de Chimie des Matériaux Solides, Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, 6621, Casablanca, Morocco</ce:textfn></ce:affiliation><ce:footnote id="QFN1"><ce:label>1</ce:label><ce:note-para>To whom correspondence should be addressed: ICMCB, Château Brivazac, 87, Avenue du Docteur A. Schweitzer, 33608 Pessac Cedex, France. Fax: 33(0) 5.56.84.27.61. E-mail: olaz@chimsol.icmcb.u-bordeaux.fr.</ce:note-para></ce:footnote></ce:author-group><ce:date-received day="28" month="2" year="1997"></ce:date-received><ce:date-revised day="4" month="11" year="1998"></ce:date-revised><ce:date-accepted day="7" month="12" year="1998"></ce:date-accepted><ce:abstract><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para>A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with the<ce:italic>R</ce:italic><math altimg="si1.gif"><rm><ovl type="bar">3</ovl></rm></math>or the<ce:italic>R</ce:italic>32 space groups. The atomic arrangement is a three-dimensional framework formed by PO<ce:inf>4</ce:inf>tetrahedra sharing corners with TiO<ce:inf>6</ce:inf>octahedra. Co<ce:sup>2+</ce:sup>is located in half of the antiprism<ce:italic>M</ce:italic>(1) sites in a centered (<ce:italic>R</ce:italic><math altimg="si2.gif"><rm><ovl type="bar">3</ovl></rm></math>) or off- centered (<ce:italic>R</ce:italic>32) position. The optical, EPR and magnetic data can account for a pure ionic Co–O bond.</ce:simple-para></ce:abstract-sec></ce:abstract></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties</title></titleInfo><titleInfo type="alternative" lang="en" contentType="CDATA"><title>A New Nasicon-Type Phosphate Co</title></titleInfo><name type="personal"><namePart type="given">R</namePart><namePart type="family">Olazcuaga</namePart><affiliation>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</affiliation><description>To whom correspondence should be addressed: ICMCB, Château Brivazac, 87, Avenue du Docteur A. Schweitzer, 33608 Pessac Cedex, France. Fax: 33(0) 5.56.84.27.61. E-mail: olaz@chimsol.icmcb.u-bordeaux.fr.</description><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">J.M</namePart><namePart type="family">Dance</namePart><affiliation>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">G.Le</namePart><namePart type="family">Flem</namePart><affiliation>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer, 33608, Pessac Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">J</namePart><namePart type="family">Derouet</namePart><affiliation>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">L</namePart><namePart type="family">Beaury</namePart><affiliation>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">P</namePart><namePart type="family">Porcher</namePart><affiliation>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand, 92195, Meudon Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">A.El</namePart><namePart type="family">Bouari</namePart><affiliation>Laboratoire de Chimie des Matériaux Solides, Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, 6621, Casablanca, Morocco</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">A.El</namePart><namePart type="family">Jazouli</namePart><affiliation>Laboratoire de Chimie des Matériaux Solides, Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, 6621, Casablanca, Morocco</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article"></genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">1999</dateIssued><dateModified encoding="w3cdtf">1998-11-04</dateModified><copyrightDate encoding="w3cdtf">1999</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="en">A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with theR3or theR32 space groups. The atomic arrangement is a three-dimensional framework formed by PO4tetrahedra sharing corners with TiO6octahedra. Co2+is located in half of the antiprismM(1) sites in a centered (R3) or off- centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co–O bond.</abstract><note type="content">Section title: Regular Article</note><relatedItem type="host"><titleInfo><title>Journal of Solid State Chemistry</title></titleInfo><titleInfo type="abbreviated"><title>YJSSC</title></titleInfo><genre type="journal">journal</genre><originInfo><dateIssued encoding="w3cdtf">199903</dateIssued></originInfo><identifier type="ISSN">0022-4596</identifier><identifier type="PII">S0022-4596(00)X0040-0</identifier><part><date>199903</date><detail type="volume"><number>143</number><caption>vol.</caption></detail><detail type="issue"><number>2</number><caption>no.</caption></detail><extent unit="issue pages"><start>145</start><end>303</end></extent><extent unit="pages"><start>224</start><end>229</end></extent></part></relatedItem><identifier type="istex">7EA26E1087D5A09E41F4A2B3CD8F29121642B61B</identifier><identifier type="DOI">10.1006/jssc.1998.8097</identifier><identifier type="PII">S0022-4596(98)98097-5</identifier><accessCondition type="use and reproduction" contentType="copyright">©1999 Academic Press</accessCondition><recordInfo><recordContentSource>ELSEVIER</recordContentSource><recordOrigin>Academic Press, ©1999</recordOrigin></recordInfo></mods></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/Istex/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000473 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Istex/Corpus/biblio.hfd -nk 000473 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Terre
|area= CobaltMaghrebV1
|flux= Istex
|étape= Corpus
|type= RBID
|clé= ISTEX:7EA26E1087D5A09E41F4A2B3CD8F29121642B61B
|texte= A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties
}}
| This area was generated with Dilib version V0.6.32. |  |