An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions
Identifieur interne : 008618 ( Main/Merge ); précédent : 008617; suivant : 008619An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions
Auteurs : Philip C. Andrews [Australie] ; Alan R. Kennedy ; Robert E. Mulvey [Royaume-Uni] ; Colin L. Raston [Australie] ; Brett A. Roberts [Australie] ; René B. RowlingsSource :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2000-06-02.
English descriptors
Abstract
Six arene anions in a cationic [K6Mg6N12]6+ ring (see picture, arene=benzene) are reported in the mixed‐metal macrocyclic amide of 24 (!) ring atoms. The macrocycle is produced through a very effective synthesis, in which the anions are selectively monodeprotonated.
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DOI: 10.1002/1521-3773(20000602)39:11<1960::AID-ANIE1960>3.0.CO;2-D
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The macrocycle is produced through a very effective synthesis, in which the anions are selectively monodeprotonated.</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
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