An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions
Identifieur interne : 000E03 ( Istex/Corpus ); précédent : 000E02; suivant : 000E04An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions
Auteurs : Philip C. Andrews ; Alan R. Kennedy ; Robert E. Mulvey ; Colin L. Raston ; Brett A. Roberts ; René B. RowlingsSource :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2000-06-02.
English descriptors
Abstract
Six arene anions in a cationic [K6Mg6N12]6+ ring (see picture, arene=benzene) are reported in the mixed‐metal macrocyclic amide of 24 (!) ring atoms. The macrocycle is produced through a very effective synthesis, in which the anions are selectively monodeprotonated.
Url:
DOI: 10.1002/1521-3773(20000602)39:11<1960::AID-ANIE1960>3.0.CO;2-D
Links to Exploration step
ISTEX:C452AF1664939252F03FAB375D340FA5E9741510Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions</title>
<author><name sortKey="Andrews, Philip C" sort="Andrews, Philip C" uniqKey="Andrews P" first="Philip C." last="Andrews">Philip C. Andrews</name>
<affiliation><mods:affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Kennedy, Alan R" sort="Kennedy, Alan R" uniqKey="Kennedy A" first="Alan R." last="Kennedy">Alan R. Kennedy</name>
<affiliation><mods:affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Mulvey, Robert E" sort="Mulvey, Robert E" uniqKey="Mulvey R" first="Robert E." last="Mulvey">Robert E. Mulvey</name>
<affiliation><mods:affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</mods:affiliation>
</affiliation>
<affiliation><mods:affiliation>E-mail: r.e.mulvey@strath.ac.uk</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Raston, Colin L" sort="Raston, Colin L" uniqKey="Raston C" first="Colin L." last="Raston">Colin L. Raston</name>
<affiliation><mods:affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Roberts, Brett A" sort="Roberts, Brett A" uniqKey="Roberts B" first="Brett A." last="Roberts">Brett A. Roberts</name>
<affiliation><mods:affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Rowlings, Rene B" sort="Rowlings, Rene B" uniqKey="Rowlings R" first="René B." last="Rowlings">René B. Rowlings</name>
<affiliation><mods:affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</mods:affiliation>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:C452AF1664939252F03FAB375D340FA5E9741510</idno>
<date when="2000" year="2000">2000</date>
<idno type="doi">10.1002/1521-3773(20000602)39:11<1960::AID-ANIE1960>3.0.CO;2-D</idno>
<idno type="url">https://api.istex.fr/document/C452AF1664939252F03FAB375D340FA5E9741510/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">000E03</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions</title>
<author><name sortKey="Andrews, Philip C" sort="Andrews, Philip C" uniqKey="Andrews P" first="Philip C." last="Andrews">Philip C. Andrews</name>
<affiliation><mods:affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Kennedy, Alan R" sort="Kennedy, Alan R" uniqKey="Kennedy A" first="Alan R." last="Kennedy">Alan R. Kennedy</name>
<affiliation><mods:affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Mulvey, Robert E" sort="Mulvey, Robert E" uniqKey="Mulvey R" first="Robert E." last="Mulvey">Robert E. Mulvey</name>
<affiliation><mods:affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</mods:affiliation>
</affiliation>
<affiliation><mods:affiliation>E-mail: r.e.mulvey@strath.ac.uk</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Raston, Colin L" sort="Raston, Colin L" uniqKey="Raston C" first="Colin L." last="Raston">Colin L. Raston</name>
<affiliation><mods:affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Roberts, Brett A" sort="Roberts, Brett A" uniqKey="Roberts B" first="Brett A." last="Roberts">Brett A. Roberts</name>
<affiliation><mods:affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Rowlings, Rene B" sort="Rowlings, Rene B" uniqKey="Rowlings R" first="René B." last="Rowlings">René B. Rowlings</name>
<affiliation><mods:affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</mods:affiliation>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j">Angewandte Chemie International Edition</title>
<title level="j" type="abbrev">Angew. Chem. Int. Ed.</title>
<idno type="ISSN">1433-7851</idno>
<idno type="eISSN">1521-3773</idno>
<imprint><publisher>WILEY‐VCH Verlag GmbH</publisher>
<pubPlace>Weinheim</pubPlace>
<date type="published" when="2000-06-02">2000-06-02</date>
<biblScope unit="volume">39</biblScope>
<biblScope unit="issue">11</biblScope>
<biblScope unit="page" from="1960">1960</biblScope>
<biblScope unit="page" to="1962">1962</biblScope>
</imprint>
<idno type="ISSN">1433-7851</idno>
</series>
<idno type="istex">C452AF1664939252F03FAB375D340FA5E9741510</idno>
<idno type="DOI">10.1002/1521-3773(20000602)39:11<1960::AID-ANIE1960>3.0.CO;2-D</idno>
<idno type="ArticleID">ANIE1960</idno>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">1433-7851</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>alkali metals</term>
<term>alkaline earth metals</term>
<term>amides</term>
<term>macrocycles</term>
<term>template synthesis</term>
</keywords>
</textClass>
<langUsage><language ident="en">en</language>
</langUsage>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Six arene anions in a cationic [K6Mg6N12]6+ ring (see picture, arene=benzene) are reported in the mixed‐metal macrocyclic amide of 24 (!) ring atoms. The macrocycle is produced through a very effective synthesis, in which the anions are selectively monodeprotonated.</div>
</front>
</TEI>
<istex><corpusName>wiley</corpusName>
<author><json:item><name>Philip C. Andrews Dr.</name>
<affiliations><json:string>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</json:string>
</affiliations>
</json:item>
<json:item><name>Alan R. Kennedy Dr.</name>
<affiliations><json:string>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</json:string>
</affiliations>
</json:item>
<json:item><name>Robert E. Mulvey Prof.</name>
<affiliations><json:string>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</json:string>
<json:string>E-mail: r.e.mulvey@strath.ac.uk</json:string>
</affiliations>
</json:item>
<json:item><name>Colin L. Raston Prof.</name>
<affiliations><json:string>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</json:string>
</affiliations>
</json:item>
<json:item><name>Brett A. Roberts</name>
<affiliations><json:string>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</json:string>
</affiliations>
</json:item>
<json:item><name>René B. Rowlings Dr.</name>
<affiliations><json:string>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</json:string>
</affiliations>
</json:item>
</author>
<subject><json:item><lang><json:string>eng</json:string>
</lang>
<value>alkali metals</value>
</json:item>
<json:item><lang><json:string>eng</json:string>
</lang>
<value>alkaline earth metals</value>
</json:item>
<json:item><lang><json:string>eng</json:string>
</lang>
<value>amides</value>
</json:item>
<json:item><lang><json:string>eng</json:string>
</lang>
<value>macrocycles</value>
</json:item>
<json:item><lang><json:string>eng</json:string>
</lang>
<value>template synthesis</value>
</json:item>
</subject>
<articleId><json:string>ANIE1960</json:string>
</articleId>
<language><json:string>eng</json:string>
</language>
<abstract>Six arene anions in a cationic [K6Mg6N12]6+ ring (see picture, arene=benzene) are reported in the mixed‐metal macrocyclic amide of 24 (!) ring atoms. The macrocycle is produced through a very effective synthesis, in which the anions are selectively monodeprotonated.</abstract>
<qualityIndicators><score>2.998</score>
<pdfVersion>1.2</pdfVersion>
<pdfPageSize>595 x 842 pts (A4)</pdfPageSize>
<refBibsNative>false</refBibsNative>
<keywordCount>5</keywordCount>
<abstractCharCount>266</abstractCharCount>
<pdfWordCount>2530</pdfWordCount>
<pdfCharCount>14619</pdfCharCount>
<pdfPageCount>3</pdfPageCount>
<abstractWordCount>39</abstractWordCount>
</qualityIndicators>
<title>An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions</title>
<genre.original><json:string>shortCommunication</json:string>
</genre.original>
<genre><json:string>brief-communication</json:string>
</genre>
<host><volume>39</volume>
<publisherId><json:string>ANIE</json:string>
</publisherId>
<pages><total>3</total>
<last>1962</last>
<first>1960</first>
</pages>
<issn><json:string>1433-7851</json:string>
</issn>
<issue>11</issue>
<subject><json:item><value>Communication</value>
</json:item>
</subject>
<genre><json:string>journal</json:string>
</genre>
<language><json:string>unknown</json:string>
</language>
<eissn><json:string>1521-3773</json:string>
</eissn>
<title>Angewandte Chemie International Edition</title>
<doi><json:string>10.1002/(ISSN)1521-3773</json:string>
</doi>
</host>
<publicationDate>2000</publicationDate>
<copyrightDate>2000</copyrightDate>
<doi><json:string>10.1002/1521-3773(20000602)39:11>1960::AID-ANIE1960>3.0.CO;2-D</json:string>
</doi>
<id>C452AF1664939252F03FAB375D340FA5E9741510</id>
<score>1</score>
<fulltext><json:item><original>true</original>
<mimetype>application/pdf</mimetype>
<extension>pdf</extension>
<uri>https://api.istex.fr/document/C452AF1664939252F03FAB375D340FA5E9741510/fulltext/pdf</uri>
</json:item>
<json:item><original>false</original>
<mimetype>application/zip</mimetype>
<extension>zip</extension>
<uri>https://api.istex.fr/document/C452AF1664939252F03FAB375D340FA5E9741510/fulltext/zip</uri>
</json:item>
<istex:fulltextTEI uri="https://api.istex.fr/document/C452AF1664939252F03FAB375D340FA5E9741510/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions</title>
<respStmt xml:id="ISTEX-API" resp="Références bibliographiques récupérées via GROBID" name="ISTEX-API (INIST-CNRS)"></respStmt>
</titleStmt>
<publicationStmt><authority>ISTEX</authority>
<publisher>WILEY‐VCH Verlag GmbH</publisher>
<pubPlace>Weinheim</pubPlace>
<availability><p>WILEY</p>
</availability>
<date>2000</date>
</publicationStmt>
<sourceDesc><biblStruct type="inbook"><analytic><title level="a" type="main" xml:lang="en">An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions</title>
<author><persName><forename type="first">Philip C.</forename>
<surname>Andrews</surname>
</persName>
<roleName type="degree">Dr.</roleName>
<affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</affiliation>
</author>
<author><persName><forename type="first">Alan R.</forename>
<surname>Kennedy</surname>
</persName>
<roleName type="degree">Dr.</roleName>
<affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</affiliation>
</author>
<author><persName><forename type="first">Robert E.</forename>
<surname>Mulvey</surname>
</persName>
<roleName type="degree">Prof.</roleName>
<email>r.e.mulvey@strath.ac.uk</email>
<affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</affiliation>
</author>
<author><persName><forename type="first">Colin L.</forename>
<surname>Raston</surname>
</persName>
<roleName type="degree">Prof.</roleName>
<affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</affiliation>
</author>
<author><persName><forename type="first">Brett A.</forename>
<surname>Roberts</surname>
</persName>
<affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</affiliation>
</author>
<author><persName><forename type="first">René B.</forename>
<surname>Rowlings</surname>
</persName>
<roleName type="degree">Dr.</roleName>
<affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</affiliation>
</author>
</analytic>
<monogr><title level="j">Angewandte Chemie International Edition</title>
<title level="j" type="abbrev">Angew. Chem. Int. Ed.</title>
<idno type="pISSN">1433-7851</idno>
<idno type="eISSN">1521-3773</idno>
<idno type="DOI">10.1002/(ISSN)1521-3773</idno>
<imprint><publisher>WILEY‐VCH Verlag GmbH</publisher>
<pubPlace>Weinheim</pubPlace>
<date type="published" when="2000-06-02"></date>
<biblScope unit="volume">39</biblScope>
<biblScope unit="issue">11</biblScope>
<biblScope unit="page" from="1960">1960</biblScope>
<biblScope unit="page" to="1962">1962</biblScope>
</imprint>
</monogr>
<idno type="istex">C452AF1664939252F03FAB375D340FA5E9741510</idno>
<idno type="DOI">10.1002/1521-3773(20000602)39:11<1960::AID-ANIE1960>3.0.CO;2-D</idno>
<idno type="ArticleID">ANIE1960</idno>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><creation><date>2000</date>
</creation>
<langUsage><language ident="en">en</language>
</langUsage>
<abstract xml:lang="en" style="graphical"><p>Six arene anions in a cationic [K6Mg6N12]6+ ring (see picture, arene=benzene) are reported in the mixed‐metal macrocyclic amide of 24 (!) ring atoms. The macrocycle is produced through a very effective synthesis, in which the anions are selectively monodeprotonated.</p>
</abstract>
<textClass xml:lang="en"><keywords scheme="keyword"><list><head>keywords</head>
<item><term>alkali metals</term>
</item>
<item><term>alkaline earth metals</term>
</item>
<item><term>amides</term>
</item>
<item><term>macrocycles</term>
</item>
<item><term>template synthesis</term>
</item>
</list>
</keywords>
</textClass>
<textClass><keywords scheme="Journal Subject"><list><head>article-category</head>
<item><term>Communication</term>
</item>
</list>
</keywords>
</textClass>
</profileDesc>
<revisionDesc><change when="2000-02-07">Received</change>
<change when="2000-06-02">Published</change>
<change xml:id="refBibs-istex" who="#ISTEX-API" when="2016-4-24">References added</change>
</revisionDesc>
</teiHeader>
</istex:fulltextTEI>
<json:item><original>false</original>
<mimetype>text/plain</mimetype>
<extension>txt</extension>
<uri>https://api.istex.fr/document/C452AF1664939252F03FAB375D340FA5E9741510/fulltext/txt</uri>
</json:item>
</fulltext>
<metadata><istex:metadataXml wicri:clean="Wiley component found"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration>
<istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>WILEY‐VCH Verlag GmbH</publisherName>
<publisherLoc>Weinheim</publisherLoc>
</publisherInfo>
<doi registered="yes">10.1002/(ISSN)1521-3773</doi>
<issn type="print">1433-7851</issn>
<issn type="electronic">1521-3773</issn>
<idGroup><id type="product" value="ANIE"></id>
</idGroup>
<titleGroup><title type="main" xml:lang="en" sort="ANGEWANDTE CHEMIE INTERNATIONAL EDITION">Angewandte Chemie International Edition</title>
<title type="short">Angew. Chem. Int. Ed.</title>
</titleGroup>
</publicationMeta>
<publicationMeta level="part" position="110"><doi origin="wiley" registered="yes">10.1002/1521-3773(20000602)39:11<>1.0.CO;2-0</doi>
<numberingGroup><numbering type="journalVolume" number="39">39</numbering>
<numbering type="journalIssue">11</numbering>
</numberingGroup>
<coverDate startDate="2000-06-02">June 2, 2000</coverDate>
</publicationMeta>
<publicationMeta level="unit" type="shortCommunication" position="18" status="forIssue"><doi origin="wiley" registered="yes">10.1002/1521-3773(20000602)39:11<1960::AID-ANIE1960>3.0.CO;2-D</doi>
<idGroup><id type="unit" value="ANIE1960"></id>
</idGroup>
<countGroup><count type="pageTotal" number="3"></count>
</countGroup>
<titleGroup><title type="articleCategory">Communication</title>
</titleGroup>
<copyright ownership="publisher">Copyright © 2000 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany</copyright>
<eventGroup><event type="manuscriptReceived" date="2000-02-07"></event>
<event type="firstOnline" date="2000-06-14"></event>
<event type="publishedOnlineFinalForm" date="2000-06-14"></event>
<event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.4.7 mode:FullText source:Header result:Header" date="2011-02-24"></event>
<event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-01-03"></event>
<event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-14"></event>
</eventGroup>
<numberingGroup><numbering type="pageFirst">1960</numbering>
<numbering type="pageLast">1962</numbering>
</numberingGroup>
<linkGroup><link type="toTypesetVersion" href="file:ANIE.ANIE1960.pdf"></link>
</linkGroup>
</publicationMeta>
<contentMeta><countGroup><count type="figureTotal" number="12"></count>
<count type="tableTotal" number="0"></count>
<count type="referenceTotal" number="14"></count>
</countGroup>
<titleGroup><title type="main" xml:lang="en">An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions</title>
</titleGroup>
<creators><creator xml:id="au1" creatorRole="author" affiliationRef="#afb"><personName><givenNames>Philip C.</givenNames>
<familyName>Andrews</familyName>
<degrees>Dr.</degrees>
</personName>
</creator>
<creator xml:id="au2" creatorRole="author" affiliationRef="#afa"><personName><givenNames>Alan R.</givenNames>
<familyName>Kennedy</familyName>
<degrees>Dr.</degrees>
</personName>
</creator>
<creator xml:id="au3" creatorRole="author" affiliationRef="#afa"><personName><givenNames>Robert E.</givenNames>
<familyName>Mulvey</familyName>
<degrees>Prof.</degrees>
</personName>
<contactDetails><email>r.e.mulvey@strath.ac.uk</email>
</contactDetails>
</creator>
<creator xml:id="au4" creatorRole="author" affiliationRef="#afb"><personName><givenNames>Colin L.</givenNames>
<familyName>Raston</familyName>
<degrees>Prof.</degrees>
</personName>
</creator>
<creator xml:id="au5" creatorRole="author" affiliationRef="#afb"><personName><givenNames>Brett A.</givenNames>
<familyName>Roberts</familyName>
</personName>
</creator>
<creator xml:id="au6" creatorRole="author" affiliationRef="#afa"><personName><givenNames>René B.</givenNames>
<familyName>Rowlings</familyName>
<degrees>Dr.</degrees>
</personName>
</creator>
</creators>
<affiliationGroup><affiliation xml:id="afa" countryCode="GB" type="organization"><unparsedAffiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</unparsedAffiliation>
</affiliation>
<affiliation xml:id="afb" countryCode="AU" type="organization"><unparsedAffiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</unparsedAffiliation>
</affiliation>
</affiliationGroup>
<keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">alkali metals</keyword>
<keyword xml:id="kwd2">alkaline earth metals</keyword>
<keyword xml:id="kwd3">amides</keyword>
<keyword xml:id="kwd4">macrocycles</keyword>
<keyword xml:id="kwd5">template synthesis</keyword>
</keywordGroup>
<abstractGroup><abstract type="graphical" xml:lang="en"><p><b>Six arene anions</b>
in a cationic [K<sub>6</sub>
Mg<sub>6</sub>
N<sub>12</sub>
]<sup>6+</sup>
ring (see picture, arene=benzene) are reported in the mixed‐metal macrocyclic amide of 24 (!) ring atoms. The macrocycle is produced through a very effective synthesis, in which the anions are selectively monodeprotonated.<blockFixed type="graphic"><mediaResourceGroup><mediaResource alt="image" eRights="yes" copyright="WILEY-VCH" href="urn:x-wiley:14337851:media:ANIE1960:content"></mediaResource>
<mediaResource alt="thumbnail image" rendition="webLoRes" mimeType="image/gif" resourceExtraInfo="missing" href=""></mediaResource>
<mediaResource alt="original image" rendition="webOriginal" mimeType="image/x-unknown" resourceExtraInfo="missingGifOrJpg" href=""></mediaResource>
<mediaResource alt="magnified image" rendition="webHiRes" mimeType="image/x-unknown" resourceExtraInfo="missingGifOrJpg" href=""></mediaResource>
</mediaResourceGroup>
</blockFixed>
</p>
</abstract>
</abstractGroup>
</contentMeta>
<noteGroup><note xml:id="fnxx" numbered="no"><p>This work was supported by the UK Engineering and Physical Science Research Council (Grant award No. GR/M78113). Thanks are also extended to Dr. P. J. Nichols for help with the crystallographic work.</p>
</note>
</noteGroup>
</header>
</component>
</istex:document>
</istex:metadataXml>
<mods version="3.6"><titleInfo lang="en"><title>An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions</title>
</titleInfo>
<titleInfo type="alternative" contentType="CDATA" lang="en"><title>An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions</title>
</titleInfo>
<name type="personal"><namePart type="given">Philip C.</namePart>
<namePart type="family">Andrews</namePart>
<namePart type="termsOfAddress">Dr.</namePart>
<affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Alan R.</namePart>
<namePart type="family">Kennedy</namePart>
<namePart type="termsOfAddress">Dr.</namePart>
<affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Robert E.</namePart>
<namePart type="family">Mulvey</namePart>
<namePart type="termsOfAddress">Prof.</namePart>
<affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</affiliation>
<affiliation>E-mail: r.e.mulvey@strath.ac.uk</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Colin L.</namePart>
<namePart type="family">Raston</namePart>
<namePart type="termsOfAddress">Prof.</namePart>
<affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Brett A.</namePart>
<namePart type="family">Roberts</namePart>
<affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">René B.</namePart>
<namePart type="family">Rowlings</namePart>
<namePart type="termsOfAddress">Dr.</namePart>
<affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<typeOfResource>text</typeOfResource>
<genre type="brief-communication" displayLabel="shortCommunication"></genre>
<originInfo><publisher>WILEY‐VCH Verlag GmbH</publisher>
<place><placeTerm type="text">Weinheim</placeTerm>
</place>
<dateIssued encoding="w3cdtf">2000-06-02</dateIssued>
<dateCaptured encoding="w3cdtf">2000-02-07</dateCaptured>
<copyrightDate encoding="w3cdtf">2000</copyrightDate>
</originInfo>
<language><languageTerm type="code" authority="rfc3066">en</languageTerm>
<languageTerm type="code" authority="iso639-2b">eng</languageTerm>
</language>
<physicalDescription><internetMediaType>text/html</internetMediaType>
<extent unit="figures">12</extent>
<extent unit="references">14</extent>
</physicalDescription>
<abstract type="graphical" lang="en">Six arene anions in a cationic [K6Mg6N12]6+ ring (see picture, arene=benzene) are reported in the mixed‐metal macrocyclic amide of 24 (!) ring atoms. The macrocycle is produced through a very effective synthesis, in which the anions are selectively monodeprotonated.</abstract>
<subject lang="en"><genre>keywords</genre>
<topic>alkali metals</topic>
<topic>alkaline earth metals</topic>
<topic>amides</topic>
<topic>macrocycles</topic>
<topic>template synthesis</topic>
</subject>
<relatedItem type="host"><titleInfo><title>Angewandte Chemie International Edition</title>
</titleInfo>
<titleInfo type="abbreviated"><title>Angew. Chem. Int. Ed.</title>
</titleInfo>
<genre type="journal">journal</genre>
<subject><genre>article-category</genre>
<topic>Communication</topic>
</subject>
<identifier type="ISSN">1433-7851</identifier>
<identifier type="eISSN">1521-3773</identifier>
<identifier type="DOI">10.1002/(ISSN)1521-3773</identifier>
<identifier type="PublisherID">ANIE</identifier>
<part><date>2000</date>
<detail type="volume"><caption>vol.</caption>
<number>39</number>
</detail>
<detail type="issue"><caption>no.</caption>
<number>11</number>
</detail>
<extent unit="pages"><start>1960</start>
<end>1962</end>
<total>3</total>
</extent>
</part>
</relatedItem>
<identifier type="istex">C452AF1664939252F03FAB375D340FA5E9741510</identifier>
<identifier type="DOI">10.1002/1521-3773(20000602)39:11<1960::AID-ANIE1960>3.0.CO;2-D</identifier>
<identifier type="ArticleID">ANIE1960</identifier>
<accessCondition type="use and reproduction" contentType="copyright">Copyright © 2000 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany</accessCondition>
<recordInfo><recordContentSource>WILEY</recordContentSource>
<recordOrigin>WILEY‐VCH Verlag GmbH</recordOrigin>
</recordInfo>
</mods>
</metadata>
<serie></serie>
</istex>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Ticri/CIDE/explor/HapticV1/Data/Istex/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000E03 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Istex/Corpus/biblio.hfd -nk 000E03 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Ticri/CIDE |area= HapticV1 |flux= Istex |étape= Corpus |type= RBID |clé= ISTEX:C452AF1664939252F03FAB375D340FA5E9741510 |texte= An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions }}
![]() | This area was generated with Dilib version V0.6.23. | ![]() |