Self‐Assembly of Perylene Monoimide Substituted Hexa‐peri‐hexabenzocoronenes: Dyads and Triads at Surfaces
Identifieur interne : 000498 ( Istex/Corpus ); précédent : 000497; suivant : 000499Self‐Assembly of Perylene Monoimide Substituted Hexa‐peri‐hexabenzocoronenes: Dyads and Triads at Surfaces
Auteurs : P. Samorì ; A. Fechtenkötter ; E. Reuther ; M. Watson ; N. Severin ; K. Müllen ; J. RabeSource :
- Advanced Materials [ 0935-9648 ] ; 2006-05-15.
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Abstract
Nanoscale phase‐segregated functional architectures can be formed both in monolayers at the solid/liquid interface and in the bulk by self‐assembling electron‐acceptor–electron‐donor dyads and triads based on hexa‐peri‐hexabenzocoronene (HBC) and perylene monoimide (PMI). The figure shows charge transfer through the vertically segregated HBC and PMI channels in the bulk phase.
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DOI: 10.1002/adma.200502391
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ISTEX:BC0EFC10395F67AAC3A9FB6A8F476E821EC35836Le document en format XML
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Reuther</name><affiliations><json:string>Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany</json:string></affiliations></json:item><json:item><name>M. D. Watson</name><affiliations><json:string>Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany</json:string><json:string>Department of Chemistry, University of Kentucky, Lexington, KY 40506‐0055, USA</json:string></affiliations></json:item><json:item><name>N. Severin</name><affiliations><json:string>Department of Physics, Humboldt University Berlin, Newtonstrasse 15, 12489 Berlin, Germany</json:string></affiliations></json:item><json:item><name>K. Müllen</name><affiliations><json:string>Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany</json:string><json:string>E-mail: muellen@mpip‐mainz.mpg.de</json:string></affiliations></json:item><json:item><name>J. P. 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KGaA, Weinheim</p></availability><date>2006</date></publicationStmt><notesStmt><note type="content">*This work was supported by ESF‐SONS‐BIONICS and EU through the TMR project SISITOMAS (FMRX970099), the Marie Curie EST‐SUPER (MEST‐CT‐2004‐008128) and the IP‐NAIMO (NMP4‐CT‐2004‐500355). 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KGaA, Weinheim</copyright><eventGroup><event type="manuscriptReceived" date="2005-11-08"></event><event type="manuscriptAccepted" date="2006-01-09"></event><event type="publishedOnlineEarlyUnpaginated" date="2006-03-24"></event><event type="firstOnline" date="2006-03-24"></event><event type="publishedOnlineFinalForm" date="2006-05-10"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.1 mode:FullText source:HeaderRef result:HeaderRef" date="2010-02-23"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2013-12-31"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-14"></event></eventGroup><numberingGroup><numbering type="pageFirst">1317</numbering><numbering type="pageLast">1321</numbering></numberingGroup><linkGroup><link type="toTypesetVersion" href="file:ADMA.ADMA200502391.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="3"></count><count type="tableTotal" number="0"></count><count type="referenceTotal" number="31"></count></countGroup><titleGroup><title type="main" xml:lang="en">Self‐Assembly of Perylene Monoimide Substituted Hexa‐<i>peri</i>‐hexabenzocoronenes: Dyads and Triads at Surfaces<link href="#fn1"></link></title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#a1 #a2"><personName><givenNames>P.</givenNames><familyName>Samorì</familyName></personName><contactDetails><email>samori@isof.cnr.it</email></contactDetails></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#a3"><personName><givenNames>A.</givenNames><familyName>Fechtenkötter</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#a3"><personName><givenNames>E.</givenNames><familyName>Reuther</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#a3 #a5"><personName><givenNames>M. D.</givenNames><familyName>Watson</familyName></personName></creator><creator xml:id="au5" creatorRole="author" affiliationRef="#a4"><personName><givenNames>N.</givenNames><familyName>Severin</familyName></personName></creator><creator xml:id="au6" creatorRole="author" affiliationRef="#a3"><personName><givenNames>K.</givenNames><familyName>Müllen</familyName></personName><contactDetails><email normalForm="muellen@mpip-mainz.mpg.de">muellen@mpip‐mainz.mpg.de</email></contactDetails></creator><creator xml:id="au7" creatorRole="author" affiliationRef="#a4"><personName><givenNames>J. P.</givenNames><familyName>Rabe</familyName></personName><contactDetails><email normalForm="rabe@physik.hu-berlin.de">rabe@physik.hu‐berlin.de</email></contactDetails></creator></creators><affiliationGroup><affiliation xml:id="a1" countryCode="IT" type="organization"><unparsedAffiliation>Istituto per la Sintesi Organica e la Fotoreattività, Consiglio Nazionale delle Ricerche, via Gobetti 101, 40129 Bologna, Italy</unparsedAffiliation></affiliation><affiliation xml:id="a2" countryCode="FR" type="organization"><unparsedAffiliation>Nanochemistry Laboratory, Institut de Science et d'Ingénierie Supramoléculaires, Université Louis Pasteur, 8, allée Gaspard Monge, 67083 Strasbourg, France</unparsedAffiliation></affiliation><affiliation xml:id="a3" countryCode="DE" type="organization"><unparsedAffiliation>Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany</unparsedAffiliation></affiliation><affiliation xml:id="a4" countryCode="DE" type="organization"><unparsedAffiliation>Department of Physics, Humboldt University Berlin, Newtonstrasse 15, 12489 Berlin, Germany</unparsedAffiliation></affiliation><affiliation xml:id="a5" countryCode="US" type="organization"><unparsedAffiliation>Department of Chemistry, University of Kentucky, Lexington, KY 40506‐0055, USA</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">Conjugated molecules</keyword><keyword xml:id="kwd2">Electron transport</keyword><keyword xml:id="kwd3">Liquid crystals, discotic</keyword><keyword xml:id="kwd4">Molecular electronics</keyword><keyword xml:id="kwd5">Scanning tunneling microscopy</keyword><keyword xml:id="kwd6">Self‐assembly</keyword><keyword xml:id="kwd7">Solar cells</keyword></keywordGroup><supportingInformation><p>Supporting information for this article is available on the WWW under <url href="http://www.wiley-vch.de/contents/jc_2089/2006/c2391_s.pdf">http://www.wiley‐vch.de/contents/jc_2089/2006/c2391_s.pdf</url> or from the author.</p></supportingInformation><abstractGroup><abstract type="graphical" xml:lang="en"><p><b>Nanoscale phase‐segregated functional architectures</b> can be formed both in monolayers at the solid/liquid interface and in the bulk by self‐assembling electron‐acceptor–electron‐donor dyads and triads based on hexa‐<i>peri</i>‐hexabenzocoronene (HBC) and perylene monoimide (PMI). The figure shows charge transfer through the vertically segregated HBC and PMI channels in the bulk phase. <blockFixed type="graphic"><mediaResourceGroup><mediaResource alt="image" eRights="yes" copyright="WILEY-VCH" href="urn:x-wiley:09359648:media:ADMA200502391:content"></mediaResource><mediaResource alt="thumbnail image" rendition="webLoRes" mimeType="image/gif" href=""></mediaResource><mediaResource alt="original image" rendition="webOriginal" mimeType="image/gif" href=""></mediaResource><mediaResource alt="magnified image" rendition="webHiRes" mimeType="image/gif" href=""></mediaResource></mediaResourceGroup></blockFixed></p></abstract></abstractGroup></contentMeta><noteGroup><note xml:id="fn1"><p>This work was supported by ESF‐SONS‐BIONICS and EU through the TMR project SISITOMAS (FMRX970099), the Marie Curie EST‐SUPER (MEST‐CT‐2004‐008128) and the IP‐NAIMO (NMP4‐CT‐2004‐500355). Supporting Information is available online from Wiley InterScience or from the author.</p></note></noteGroup></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Self‐Assembly of Perylene Monoimide Substituted Hexa‐peri‐hexabenzocoronenes: Dyads and Triads at Surfaces</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Self‐Assembly of Perylene Monoimide Substituted Hexa‐peri‐hexabenzocoronenes: Dyads and Triads at Surfaces</title></titleInfo><name type="personal"><namePart type="given">P.</namePart><namePart type="family">Samorì</namePart><affiliation>Istituto per la Sintesi Organica e la Fotoreattività, Consiglio Nazionale delle Ricerche, via Gobetti 101, 40129 Bologna, Italy</affiliation><affiliation>Nanochemistry Laboratory, Institut de Science et d'Ingénierie Supramoléculaires, Université Louis Pasteur, 8, allée Gaspard Monge, 67083 Strasbourg, France</affiliation><affiliation>E-mail: samori@isof.cnr.it</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">A.</namePart><namePart type="family">Fechtenkötter</namePart><affiliation>Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">E.</namePart><namePart type="family">Reuther</namePart><affiliation>Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M. D.</namePart><namePart type="family">Watson</namePart><affiliation>Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany</affiliation><affiliation>Department of Chemistry, University of Kentucky, Lexington, KY 40506‐0055, USA</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">N.</namePart><namePart type="family">Severin</namePart><affiliation>Department of Physics, Humboldt University Berlin, Newtonstrasse 15, 12489 Berlin, Germany</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">K.</namePart><namePart type="family">Müllen</namePart><affiliation>Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany</affiliation><affiliation>E-mail: muellen@mpip‐mainz.mpg.de</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">J. P.</namePart><namePart type="family">Rabe</namePart><affiliation>Department of Physics, Humboldt University Berlin, Newtonstrasse 15, 12489 Berlin, Germany</affiliation><affiliation>E-mail: rabe@physik.hu‐berlin.de</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="article" displayLabel="article"></genre><originInfo><publisher>WILEY‐VCH Verlag</publisher><place><placeTerm type="text">Weinheim</placeTerm></place><dateIssued encoding="w3cdtf">2006-05-15</dateIssued><dateCaptured encoding="w3cdtf">2005-11-08</dateCaptured><dateValid encoding="w3cdtf">2006-01-09</dateValid><copyrightDate encoding="w3cdtf">2006</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType><extent unit="figures">3</extent><extent unit="references">31</extent></physicalDescription><abstract>Nanoscale phase‐segregated functional architectures can be formed both in monolayers at the solid/liquid interface and in the bulk by self‐assembling electron‐acceptor–electron‐donor dyads and triads based on hexa‐peri‐hexabenzocoronene (HBC) and perylene monoimide (PMI). The figure shows charge transfer through the vertically segregated HBC and PMI channels in the bulk phase.</abstract><note type="content">*This work was supported by ESF‐SONS‐BIONICS and EU through the TMR project SISITOMAS (FMRX970099), the Marie Curie EST‐SUPER (MEST‐CT‐2004‐008128) and the IP‐NAIMO (NMP4‐CT‐2004‐500355). Supporting Information is available online from Wiley InterScience or from the author.</note><subject lang="en"><genre>keywords</genre><topic>Conjugated molecules</topic><topic>Electron transport</topic><topic>Liquid crystals, discotic</topic><topic>Molecular electronics</topic><topic>Scanning tunneling microscopy</topic><topic>Self‐assembly</topic><topic>Solar cells</topic></subject><relatedItem type="host"><titleInfo><title>Advanced Materials</title></titleInfo><titleInfo type="abbreviated"><title>Adv. Mater.</title></titleInfo><genre type="journal">journal</genre><note type="content"> Supporting information for this article is available on the WWW under http://www.wiley‐vch.de/contents/jc_2089/2006/c2391_s.pdf or from the author.</note><subject><genre>article-category</genre><topic>Communication</topic></subject><identifier type="ISSN">0935-9648</identifier><identifier type="eISSN">1521-4095</identifier><identifier type="DOI">10.1002/(ISSN)1521-4095</identifier><identifier type="PublisherID">ADMA</identifier><part><date>2006</date><detail type="title"><title>Supramolecular Approaches to Organic Electronics and Nanotechnology</title></detail><detail type="volume"><caption>vol.</caption><number>18</number></detail><detail type="issue"><caption>no.</caption><number>10</number></detail><extent unit="pages"><start>1317</start><end>1321</end><total>5</total></extent></part></relatedItem><identifier type="istex">BC0EFC10395F67AAC3A9FB6A8F476E821EC35836</identifier><identifier type="DOI">10.1002/adma.200502391</identifier><identifier type="ArticleID">ADMA200502391</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2006 WILEY‐VCH Verlag GmbH & Co. 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