The Comparison of Hydrochloric Acid and Phosphoric Acid Treatments in the Preparation of Montmorillonite Catalysts for RNA Synthesis.
Identifieur interne : 001953 ( Ncbi/Merge ); précédent : 001952; suivant : 001954The Comparison of Hydrochloric Acid and Phosphoric Acid Treatments in the Preparation of Montmorillonite Catalysts for RNA Synthesis.
Auteurs : Michael Frank Aldersley [États-Unis] ; Prakash C. Joshi [États-Unis] ; Yixing Huang [États-Unis]Source :
- Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life [ 1573-0875 ] ; 2017.
Descripteurs français
- KwdFr :
- MESH :
- synthèse chimique : ARN.
- Acide chlorhydrique, Acides phosphoriques, Bentonite, Catalyse.
English descriptors
- KwdEn :
- MESH :
- chemical , chemical synthesis : RNA.
- chemical , chemistry : Bentonite, Hydrochloric Acid, Phosphoric Acids.
- Catalysis.
Abstract
The treatment of clay minerals with a preliminary acid wash and titration to pH 7 has proven to generate catalysts for the most interesting of oligomerization reactions in which activated RNA-nucleotides generate oligomers up to 40-mers. Significantly, not all clay minerals become catalytic following this treatment and none are catalytic in the absence of such treatment. The washing procedure has been modified and explored further using phosphoric acid and the outcomes are compared to those obtained when clay samples are prepared following a hydrochloric acid wash.
DOI: 10.1007/s11084-017-9533-6
PubMed: 28210992
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pubmed:28210992Le document en format XML
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<front><div type="abstract" xml:lang="en">The treatment of clay minerals with a preliminary acid wash and titration to pH 7 has proven to generate catalysts for the most interesting of oligomerization reactions in which activated RNA-nucleotides generate oligomers up to 40-mers. Significantly, not all clay minerals become catalytic following this treatment and none are catalytic in the absence of such treatment. The washing procedure has been modified and explored further using phosphoric acid and the outcomes are compared to those obtained when clay samples are prepared following a hydrochloric acid wash.</div>
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