The Comparison of Hydrochloric Acid and Phosphoric Acid Treatments in the Preparation of Montmorillonite Catalysts for RNA Synthesis.
Identifieur interne : 000B02 ( PubMed/Checkpoint ); précédent : 000B01; suivant : 000B03The Comparison of Hydrochloric Acid and Phosphoric Acid Treatments in the Preparation of Montmorillonite Catalysts for RNA Synthesis.
Auteurs : Michael Frank Aldersley [États-Unis] ; Prakash C. Joshi [États-Unis] ; Yixing Huang [États-Unis]Source :
- Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life [ 1573-0875 ] ; 2017.
Descripteurs français
- KwdFr :
- MESH :
- synthèse chimique : ARN.
- Acide chlorhydrique, Acides phosphoriques, Bentonite, Catalyse.
English descriptors
- KwdEn :
- MESH :
- chemical , chemical synthesis : RNA.
- chemical , chemistry : Bentonite, Hydrochloric Acid, Phosphoric Acids.
- Catalysis.
Abstract
The treatment of clay minerals with a preliminary acid wash and titration to pH 7 has proven to generate catalysts for the most interesting of oligomerization reactions in which activated RNA-nucleotides generate oligomers up to 40-mers. Significantly, not all clay minerals become catalytic following this treatment and none are catalytic in the absence of such treatment. The washing procedure has been modified and explored further using phosphoric acid and the outcomes are compared to those obtained when clay samples are prepared following a hydrochloric acid wash.
DOI: 10.1007/s11084-017-9533-6
PubMed: 28210992
Affiliations:
Links toward previous steps (curation, corpus...)
Links to Exploration step
pubmed:28210992Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">The Comparison of Hydrochloric Acid and Phosphoric Acid Treatments in the Preparation of Montmorillonite Catalysts for RNA Synthesis.</title>
<author><name sortKey="Aldersley, Michael Frank" sort="Aldersley, Michael Frank" uniqKey="Aldersley M" first="Michael Frank" last="Aldersley">Michael Frank Aldersley</name>
<affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180, USA. alderm@rpi.edu.</nlm:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180</wicri:regionArea>
<wicri:noRegion>12180</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Joshi, Prakash C" sort="Joshi, Prakash C" uniqKey="Joshi P" first="Prakash C" last="Joshi">Prakash C. Joshi</name>
<affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180, USA.</nlm:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180</wicri:regionArea>
<wicri:noRegion>12180</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Huang, Yixing" sort="Huang, Yixing" uniqKey="Huang Y" first="Yixing" last="Huang">Yixing Huang</name>
<affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180, USA.</nlm:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180</wicri:regionArea>
<wicri:noRegion>12180</wicri:noRegion>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PubMed</idno>
<date when="2017">2017</date>
<idno type="RBID">pubmed:28210992</idno>
<idno type="pmid">28210992</idno>
<idno type="doi">10.1007/s11084-017-9533-6</idno>
<idno type="wicri:Area/PubMed/Corpus">000D78</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000D78</idno>
<idno type="wicri:Area/PubMed/Curation">000D78</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000D78</idno>
<idno type="wicri:Area/PubMed/Checkpoint">000B02</idno>
<idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">000B02</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">The Comparison of Hydrochloric Acid and Phosphoric Acid Treatments in the Preparation of Montmorillonite Catalysts for RNA Synthesis.</title>
<author><name sortKey="Aldersley, Michael Frank" sort="Aldersley, Michael Frank" uniqKey="Aldersley M" first="Michael Frank" last="Aldersley">Michael Frank Aldersley</name>
<affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180, USA. alderm@rpi.edu.</nlm:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180</wicri:regionArea>
<wicri:noRegion>12180</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Joshi, Prakash C" sort="Joshi, Prakash C" uniqKey="Joshi P" first="Prakash C" last="Joshi">Prakash C. Joshi</name>
<affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180, USA.</nlm:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180</wicri:regionArea>
<wicri:noRegion>12180</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Huang, Yixing" sort="Huang, Yixing" uniqKey="Huang Y" first="Yixing" last="Huang">Yixing Huang</name>
<affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180, USA.</nlm:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180</wicri:regionArea>
<wicri:noRegion>12180</wicri:noRegion>
</affiliation>
</author>
</analytic>
<series><title level="j">Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life</title>
<idno type="eISSN">1573-0875</idno>
<imprint><date when="2017" type="published">2017</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bentonite (chemistry)</term>
<term>Catalysis</term>
<term>Hydrochloric Acid (chemistry)</term>
<term>Phosphoric Acids (chemistry)</term>
<term>RNA (chemical synthesis)</term>
</keywords>
<keywords scheme="KwdFr" xml:lang="fr"><term>ARN (synthèse chimique)</term>
<term>Acide chlorhydrique ()</term>
<term>Acides phosphoriques ()</term>
<term>Bentonite ()</term>
<term>Catalyse</term>
</keywords>
<keywords scheme="MESH" type="chemical" qualifier="chemical synthesis" xml:lang="en"><term>RNA</term>
</keywords>
<keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Bentonite</term>
<term>Hydrochloric Acid</term>
<term>Phosphoric Acids</term>
</keywords>
<keywords scheme="MESH" qualifier="synthèse chimique" xml:lang="fr"><term>ARN</term>
</keywords>
<keywords scheme="MESH" xml:lang="en"><term>Catalysis</term>
</keywords>
<keywords scheme="MESH" xml:lang="fr"><term>Acide chlorhydrique</term>
<term>Acides phosphoriques</term>
<term>Bentonite</term>
<term>Catalyse</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">The treatment of clay minerals with a preliminary acid wash and titration to pH 7 has proven to generate catalysts for the most interesting of oligomerization reactions in which activated RNA-nucleotides generate oligomers up to 40-mers. Significantly, not all clay minerals become catalytic following this treatment and none are catalytic in the absence of such treatment. The washing procedure has been modified and explored further using phosphoric acid and the outcomes are compared to those obtained when clay samples are prepared following a hydrochloric acid wash.</div>
</front>
</TEI>
<pubmed><MedlineCitation Status="MEDLINE" Owner="NLM"><PMID Version="1">28210992</PMID>
<DateCompleted><Year>2018</Year>
<Month>05</Month>
<Day>31</Day>
</DateCompleted>
<DateRevised><Year>2018</Year>
<Month>11</Month>
<Day>13</Day>
</DateRevised>
<Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1573-0875</ISSN>
<JournalIssue CitedMedium="Internet"><Volume>47</Volume>
<Issue>3</Issue>
<PubDate><Year>2017</Year>
<Month>Sep</Month>
</PubDate>
</JournalIssue>
<Title>Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life</Title>
<ISOAbbreviation>Orig Life Evol Biosph</ISOAbbreviation>
</Journal>
<ArticleTitle>The Comparison of Hydrochloric Acid and Phosphoric Acid Treatments in the Preparation of Montmorillonite Catalysts for RNA Synthesis.</ArticleTitle>
<Pagination><MedlinePgn>297-304</MedlinePgn>
</Pagination>
<ELocationID EIdType="doi" ValidYN="Y">10.1007/s11084-017-9533-6</ELocationID>
<Abstract><AbstractText>The treatment of clay minerals with a preliminary acid wash and titration to pH 7 has proven to generate catalysts for the most interesting of oligomerization reactions in which activated RNA-nucleotides generate oligomers up to 40-mers. Significantly, not all clay minerals become catalytic following this treatment and none are catalytic in the absence of such treatment. The washing procedure has been modified and explored further using phosphoric acid and the outcomes are compared to those obtained when clay samples are prepared following a hydrochloric acid wash.</AbstractText>
</Abstract>
<AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Aldersley</LastName>
<ForeName>Michael Frank</ForeName>
<Initials>MF</Initials>
<AffiliationInfo><Affiliation>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180, USA. alderm@rpi.edu.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Joshi</LastName>
<ForeName>Prakash C</ForeName>
<Initials>PC</Initials>
<AffiliationInfo><Affiliation>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180, USA.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Huang</LastName>
<ForeName>Yixing</ForeName>
<Initials>Y</Initials>
<AffiliationInfo><Affiliation>Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180, USA.</Affiliation>
</AffiliationInfo>
</Author>
</AuthorList>
<Language>eng</Language>
<GrantList CompleteYN="Y"><Grant><GrantID>Undergraduate Research</GrantID>
<Agency>Rensselaer Polytechnic Institute (US)</Agency>
<Country></Country>
</Grant>
</GrantList>
<PublicationTypeList><PublicationType UI="D003160">Comparative Study</PublicationType>
<PublicationType UI="D016428">Journal Article</PublicationType>
</PublicationTypeList>
<ArticleDate DateType="Electronic"><Year>2017</Year>
<Month>02</Month>
<Day>16</Day>
</ArticleDate>
</Article>
<MedlineJournalInfo><Country>Netherlands</Country>
<MedlineTA>Orig Life Evol Biosph</MedlineTA>
<NlmUniqueID>8610391</NlmUniqueID>
<ISSNLinking>0169-6149</ISSNLinking>
</MedlineJournalInfo>
<ChemicalList><Chemical><RegistryNumber>0</RegistryNumber>
<NameOfSubstance UI="D010756">Phosphoric Acids</NameOfSubstance>
</Chemical>
<Chemical><RegistryNumber>1302-78-9</RegistryNumber>
<NameOfSubstance UI="D001546">Bentonite</NameOfSubstance>
</Chemical>
<Chemical><RegistryNumber>63231-63-0</RegistryNumber>
<NameOfSubstance UI="D012313">RNA</NameOfSubstance>
</Chemical>
<Chemical><RegistryNumber>E4GA8884NN</RegistryNumber>
<NameOfSubstance UI="C030242">phosphoric acid</NameOfSubstance>
</Chemical>
<Chemical><RegistryNumber>QTT17582CB</RegistryNumber>
<NameOfSubstance UI="D006851">Hydrochloric Acid</NameOfSubstance>
</Chemical>
</ChemicalList>
<CitationSubset>IM</CitationSubset>
<CitationSubset>S</CitationSubset>
<MeshHeadingList><MeshHeading><DescriptorName UI="D001546" MajorTopicYN="N">Bentonite</DescriptorName>
<QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName>
</MeshHeading>
<MeshHeading><DescriptorName UI="D002384" MajorTopicYN="N">Catalysis</DescriptorName>
</MeshHeading>
<MeshHeading><DescriptorName UI="D006851" MajorTopicYN="N">Hydrochloric Acid</DescriptorName>
<QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName>
</MeshHeading>
<MeshHeading><DescriptorName UI="D010756" MajorTopicYN="N">Phosphoric Acids</DescriptorName>
<QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName>
</MeshHeading>
<MeshHeading><DescriptorName UI="D012313" MajorTopicYN="N">RNA</DescriptorName>
<QualifierName UI="Q000138" MajorTopicYN="Y">chemical synthesis</QualifierName>
</MeshHeading>
</MeshHeadingList>
<KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">Activated nucleotides</Keyword>
<Keyword MajorTopicYN="N">Montmorillonite</Keyword>
<Keyword MajorTopicYN="N">Oligonucleotides</Keyword>
</KeywordList>
</MedlineCitation>
<PubmedData><History><PubMedPubDate PubStatus="received"><Year>2016</Year>
<Month>11</Month>
<Day>29</Day>
</PubMedPubDate>
<PubMedPubDate PubStatus="accepted"><Year>2017</Year>
<Month>01</Month>
<Day>26</Day>
</PubMedPubDate>
<PubMedPubDate PubStatus="pubmed"><Year>2017</Year>
<Month>2</Month>
<Day>18</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="medline"><Year>2018</Year>
<Month>6</Month>
<Day>1</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="entrez"><Year>2017</Year>
<Month>2</Month>
<Day>18</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
</History>
<PublicationStatus>ppublish</PublicationStatus>
<ArticleIdList><ArticleId IdType="pubmed">28210992</ArticleId>
<ArticleId IdType="doi">10.1007/s11084-017-9533-6</ArticleId>
<ArticleId IdType="pii">10.1007/s11084-017-9533-6</ArticleId>
</ArticleIdList>
<ReferenceList><Reference><Citation>J Am Chem Soc. 2006 Jul 12;128(27):8914-9</Citation>
<ArticleIdList><ArticleId IdType="pubmed">16819887</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Orig Life Evol Biosph. 2007 Feb;37(1):3-26</Citation>
<ArticleIdList><ArticleId IdType="pubmed">17160436</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Proc Natl Acad Sci U S A. 2010 Mar 9;107(10):4585-9</Citation>
<ArticleIdList><ArticleId IdType="pubmed">20176971</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Science. 2008 Aug 8;321(5890):830-3</Citation>
<ArticleIdList><ArticleId IdType="pubmed">18687963</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Biochem Biophys Res Commun. 2015 Jun 26;462(2):99-104</Citation>
<ArticleIdList><ArticleId IdType="pubmed">25888789</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Orig Life Evol Biosph. 2006 Aug;36(4):343-61</Citation>
<ArticleIdList><ArticleId IdType="pubmed">16915351</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>J Am Soc Mass Spectrom. 2006 Sep;17(9):1265-70</Citation>
<ArticleIdList><ArticleId IdType="pubmed">16809045</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Philos Trans R Soc Lond B Biol Sci. 2006 Oct 29;361(1474):1777-86; discussion 1786</Citation>
<ArticleIdList><ArticleId IdType="pubmed">17008218</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>J Am Chem Soc. 2009 Sep 23;131(37):13369-74</Citation>
<ArticleIdList><ArticleId IdType="pubmed">19719166</ArticleId>
</ArticleIdList>
</Reference>
</ReferenceList>
</PubmedData>
</pubmed>
<affiliations><list><country><li>États-Unis</li>
</country>
</list>
<tree><country name="États-Unis"><noRegion><name sortKey="Aldersley, Michael Frank" sort="Aldersley, Michael Frank" uniqKey="Aldersley M" first="Michael Frank" last="Aldersley">Michael Frank Aldersley</name>
</noRegion>
<name sortKey="Huang, Yixing" sort="Huang, Yixing" uniqKey="Huang Y" first="Yixing" last="Huang">Yixing Huang</name>
<name sortKey="Joshi, Prakash C" sort="Joshi, Prakash C" uniqKey="Joshi P" first="Prakash C" last="Joshi">Prakash C. Joshi</name>
</country>
</tree>
</affiliations>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Sante/explor/MersV1/Data/PubMed/Checkpoint
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000B02 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/PubMed/Checkpoint/biblio.hfd -nk 000B02 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Sante |area= MersV1 |flux= PubMed |étape= Checkpoint |type= RBID |clé= pubmed:28210992 |texte= The Comparison of Hydrochloric Acid and Phosphoric Acid Treatments in the Preparation of Montmorillonite Catalysts for RNA Synthesis. }}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/PubMed/Checkpoint/RBID.i -Sk "pubmed:28210992" \ | HfdSelect -Kh $EXPLOR_AREA/Data/PubMed/Checkpoint/biblio.hfd \ | NlmPubMed2Wicri -a MersV1
This area was generated with Dilib version V0.6.33. |