N′-[(1E)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-tert-butylbenzohydrazide ethanol monosolvate
Identifieur interne : 002493 ( Main/Curation ); précédent : 002492; suivant : 002494N′-[(1E)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-tert-butylbenzohydrazide ethanol monosolvate
Auteurs : A. Thirugnanasundar [Inde] ; K. Parthipan [Inde] ; V. S. Xavier Anthonisamy [Inde] ; G. Chakkaravarthi [Inde] ; G. Rajagopal [Inde]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2011.
Abstract
In the title compound, C18H18BrClN2O2·C2H6O, the hydroxy group forms an intramolecular O—H⋯N hydrogen bond, which influences the conformation of the Shiff base molecule, where the two aromatic rings form a dihedral angle of 21.67 (8)°. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds link two Shiff base molecules and two solvent molecules into a centrosymmetric heterotetramer. Weak intermolecular C—H⋯O interactions link further tetramers related by translation along the
Url:
DOI: 10.1107/S160053681104027X
PubMed: 22219898
PubMed Central: 3247593
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PMC:3247593Le document en format XML
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′-[(1<italic>E</italic>
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-butylbenzohydrazide ethanol monosolvate</title>
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′-[(1<italic>E</italic>
)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-<italic>tert</italic>
-butylbenzohydrazide ethanol monosolvate</title>
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<front><div type="abstract" xml:lang="en"><p>In the title compound, C<sub>18</sub>
H<sub>18</sub>
BrClN<sub>2</sub>
O<sub>2</sub>
·C<sub>2</sub>
H<sub>6</sub>
O, the hydroxy group forms an intramolecular O—H⋯N hydrogen bond, which influences the conformation of the Shiff base molecule, where the two aromatic rings form a dihedral angle of 21.67 (8)°. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds link two Shiff base molecules and two solvent molecules into a centrosymmetric heterotetramer. Weak intermolecular C—H⋯O interactions link further tetramers related by translation along the <italic>a</italic>
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