N′-[(1E)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-tert-butylbenzohydrazide ethanol monosolvate
Identifieur interne : 000916 ( Ncbi/Merge ); précédent : 000915; suivant : 000917N′-[(1E)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-tert-butylbenzohydrazide ethanol monosolvate
Auteurs : A. Thirugnanasundar [Inde] ; K. Parthipan [Inde] ; V. S. Xavier Anthonisamy [Inde] ; G. Chakkaravarthi [Inde] ; G. Rajagopal [Inde]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2011.
Abstract
In the title compound, C18H18BrClN2O2·C2H6O, the hydroxy group forms an intramolecular O—H⋯N hydrogen bond, which influences the conformation of the Shiff base molecule, where the two aromatic rings form a dihedral angle of 21.67 (8)°. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds link two Shiff base molecules and two solvent molecules into a centrosymmetric heterotetramer. Weak intermolecular C—H⋯O interactions link further tetramers related by translation along the
Url:
DOI: 10.1107/S160053681104027X
PubMed: 22219898
PubMed Central: 3247593
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PMC:3247593Le document en format XML
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′-[(1<italic>E</italic>
)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-<italic>tert</italic>
-butylbenzohydrazide ethanol monosolvate</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main"><italic>N</italic>
′-[(1<italic>E</italic>
)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-<italic>tert</italic>
-butylbenzohydrazide ethanol monosolvate</title>
<author><name sortKey="Thirugnanasundar, A" sort="Thirugnanasundar, A" uniqKey="Thirugnanasundar A" first="A." last="Thirugnanasundar">A. Thirugnanasundar</name>
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<front><div type="abstract" xml:lang="en"><p>In the title compound, C<sub>18</sub>
H<sub>18</sub>
BrClN<sub>2</sub>
O<sub>2</sub>
·C<sub>2</sub>
H<sub>6</sub>
O, the hydroxy group forms an intramolecular O—H⋯N hydrogen bond, which influences the conformation of the Shiff base molecule, where the two aromatic rings form a dihedral angle of 21.67 (8)°. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds link two Shiff base molecules and two solvent molecules into a centrosymmetric heterotetramer. Weak intermolecular C—H⋯O interactions link further tetramers related by translation along the <italic>a</italic>
axis into chains.</p>
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′-[(1<italic>E</italic>
)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-<italic>tert</italic>
-butylbenzohydrazide ethanol monosolvate</title>
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′-[(1<italic>E</italic>
)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-<italic>tert</italic>
-butylbenzohydrazide ethanol monosolvate</title>
<author><name sortKey="Thirugnanasundar, A" sort="Thirugnanasundar, A" uniqKey="Thirugnanasundar A" first="A." last="Thirugnanasundar">A. Thirugnanasundar</name>
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</nlm:aff>
<country xml:lang="fr">Inde</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
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<author><name sortKey="Parthipan, K" sort="Parthipan, K" uniqKey="Parthipan K" first="K." last="Parthipan">K. Parthipan</name>
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</nlm:aff>
<country xml:lang="fr">Inde</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="Anthonisamy, V S Xavier" sort="Anthonisamy, V S Xavier" uniqKey="Anthonisamy V" first="V. S. Xavier" last="Anthonisamy">V. S. Xavier Anthonisamy</name>
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</nlm:aff>
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<author><name sortKey="Chakkaravarthi, G" sort="Chakkaravarthi, G" uniqKey="Chakkaravarthi G" first="G." last="Chakkaravarthi">G. Chakkaravarthi</name>
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</nlm:aff>
<country xml:lang="fr">Inde</country>
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<front><div type="abstract" xml:lang="en"><p>In the title compound, C<sub>18</sub>
H<sub>18</sub>
BrClN<sub>2</sub>
O<sub>2</sub>
·C<sub>2</sub>
H<sub>6</sub>
O, the hydroxy group forms an intramolecular O—H⋯N hydrogen bond, which influences the conformation of the Shiff base molecule, where the two aromatic rings form a dihedral angle of 21.67 (8)°. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds link two Shiff base molecules and two solvent molecules into a centrosymmetric heterotetramer. Weak intermolecular C—H⋯O interactions link further tetramers related by translation along the <italic>a</italic>
axis into chains.</p>
</div>
</front>
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<pubmed><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">N'-[(1E)-3-Bromo-5-chloro-2-hy-droxy-benzyl-idene]-4-tert-butyl-benzo-hydrazide ethanol monosolvate.</title>
<author><name sortKey="Thirugnanasundar, A" sort="Thirugnanasundar, A" uniqKey="Thirugnanasundar A" first="A" last="Thirugnanasundar">A. Thirugnanasundar</name>
</author>
<author><name sortKey="Parthipan, K" sort="Parthipan, K" uniqKey="Parthipan K" first="K" last="Parthipan">K. Parthipan</name>
</author>
<author><name sortKey="Anthonisamy, V S Xavier" sort="Anthonisamy, V S Xavier" uniqKey="Anthonisamy V" first="V S Xavier" last="Anthonisamy">V S Xavier Anthonisamy</name>
</author>
<author><name sortKey="Chakkaravarthi, G" sort="Chakkaravarthi, G" uniqKey="Chakkaravarthi G" first="G" last="Chakkaravarthi">G. Chakkaravarthi</name>
</author>
<author><name sortKey="Rajagopal, G" sort="Rajagopal, G" uniqKey="Rajagopal G" first="G" last="Rajagopal">G. Rajagopal</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PubMed</idno>
<date when="2011">2011</date>
<idno type="RBID">pubmed:22219898</idno>
<idno type="pmid">22219898</idno>
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<sourceDesc><biblStruct><analytic><title xml:lang="en">N'-[(1E)-3-Bromo-5-chloro-2-hy-droxy-benzyl-idene]-4-tert-butyl-benzo-hydrazide ethanol monosolvate.</title>
<author><name sortKey="Thirugnanasundar, A" sort="Thirugnanasundar, A" uniqKey="Thirugnanasundar A" first="A" last="Thirugnanasundar">A. Thirugnanasundar</name>
</author>
<author><name sortKey="Parthipan, K" sort="Parthipan, K" uniqKey="Parthipan K" first="K" last="Parthipan">K. Parthipan</name>
</author>
<author><name sortKey="Anthonisamy, V S Xavier" sort="Anthonisamy, V S Xavier" uniqKey="Anthonisamy V" first="V S Xavier" last="Anthonisamy">V S Xavier Anthonisamy</name>
</author>
<author><name sortKey="Chakkaravarthi, G" sort="Chakkaravarthi, G" uniqKey="Chakkaravarthi G" first="G" last="Chakkaravarthi">G. Chakkaravarthi</name>
</author>
<author><name sortKey="Rajagopal, G" sort="Rajagopal, G" uniqKey="Rajagopal G" first="G" last="Rajagopal">G. Rajagopal</name>
</author>
</analytic>
<series><title level="j">Acta crystallographica. Section E, Structure reports online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2011" type="published">2011</date>
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<front><div type="abstract" xml:lang="en">In the title compound, C(18)H(18)BrClN(2)O(2)·C(2)H(6)O, the hy-droxy group forms an intra-molecular O-H⋯N hydrogen bond, which influences the conformation of the Shiff base mol-ecule, where the two aromatic rings form a dihedral angle of 21.67 (8)°. Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link two Shiff base mol-ecules and two solvent mol-ecules into a centrosymmetric heterotetra-mer. Weak inter-molecular C-H⋯O inter-actions link further tetra-mers related by translation along the a axis into chains.</div>
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