Enhancing surface activity in silicon microreactors : Use of black silicon and alumina as catalyst supports for chemical and biological applications
Identifieur interne : 000396 ( PascalFrancis/Checkpoint ); précédent : 000395; suivant : 000397Enhancing surface activity in silicon microreactors : Use of black silicon and alumina as catalyst supports for chemical and biological applications
Auteurs : Marilyne Roumanie [France] ; Cyril Delattre [France] ; Frédérique Mittler [France] ; Gilles Marchand [France] ; Valérie Meille [France] ; Claude De Bellefon [France] ; Christophe Pijolat [France] ; Guy Tournier [France] ; Patrick Pouteau [France]Source :
- Chemical engineering journal : (1996) [ 1385-8947 ] ; 2008.
Descripteurs français
- Pascal (Inist)
- Microréacteur, Support catalyseur, Catalyseur sur support, Réaction chimique, Production, Aire superficielle, Nanostructure, Microusinage, Suspension colloïdale, Réaction catalytique, Oxydation, Catalyse hétérogène, Pulvérisation irradiation, Porosité, Réaction enzymatique, Modélisation, Activité catalytique, Cinétique.
- Wicri :
- topic : Production.
English descriptors
- KwdEn :
Abstract
When surface-supported chemical reactions are performed in microsystems, high production rate cannot be obtained due to the intrinsically low surface area. Increasing the active surface area of silicon microsystems is a challenge that is addressed in this paper using two original approaches: (i) modifying the structure of silicon by creating nanostructures (black silicon) using conventional etching processes of silicon micromachining or (ii) depositing a layer of porous γ-alurnina by washcoating a colloidal suspension of boehmite onto the silicon surface. The catalytic oxidation of carbon monoxide on platinum was chosen as a first test reaction in the domain of heterogeneous catalysis. In order to perform this reaction, platinum was either deposited by sputtering on silicon devices with black silicon nanostructuration, or impregnated inside the porosity of an alumina layer previously deposited on a silicon device. For specific biological applications, such as proteins analysis, some biological reactions could be advantageously achieved in microsystems using surface-supported species. As an example, an enzymatic reaction was carried out using silicon devices modified with black silicon nanostructuration and further functionalized with trypsin as a model enzyme. The catalytic activity was compared between silicon devices with the same two types of catalysts, comprising or not an enhancement of the surface activity. A minimum 10-fold increase in catalytic activity was estimated from kinetic measurements and represents the augmentation of the active surface really available for reactions. It was also shown how these catalytic materials were integrated in a microreactor increasing its catalytic active surface without modifying its global size.
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Fauriel</s1><s2>42023 Saint Etienne</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Saint Etienne</settlement></placeName></affiliation></author><author><name sortKey="Delattre, Cyril" sort="Delattre, Cyril" uniqKey="Delattre C" first="Cyril" last="Delattre">Cyril Delattre</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire d'Electronique et de Technologie de l'Information, CEA-LETI/DTBS, 17 rue Martyrs</s1><s2>38054 Grenoble</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Grenoble</settlement></placeName></affiliation></author><author><name sortKey="Mittler, Frederique" sort="Mittler, Frederique" uniqKey="Mittler F" first="Frédérique" last="Mittler">Frédérique Mittler</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire d'Electronique et de Technologie de l'Information, CEA-LETI/DTBS, 17 rue Martyrs</s1><s2>38054 Grenoble</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Grenoble</settlement></placeName></affiliation></author><author><name sortKey="Marchand, Gilles" sort="Marchand, Gilles" uniqKey="Marchand G" first="Gilles" last="Marchand">Gilles Marchand</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire d'Electronique et de Technologie de l'Information, CEA-LETI/DTBS, 17 rue Martyrs</s1><s2>38054 Grenoble</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Grenoble</settlement></placeName></affiliation></author><author><name sortKey="Meille, Valerie" sort="Meille, Valerie" uniqKey="Meille V" first="Valérie" last="Meille">Valérie Meille</name><affiliation wicri:level="3"><inist:fA14 i1="03"><s1>Laboratoire de Génie des Procédés Catalytiques, CNRS-CPE, 43 bd 11 novembre 1918, BP 2077</s1><s2>69616 Villeurbanne</s2><s3>FRA</s3><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Villeurbanne</settlement></placeName></affiliation></author><author><name sortKey="De Bellefon, Claude" sort="De Bellefon, Claude" uniqKey="De Bellefon C" first="Claude" last="De Bellefon">Claude De Bellefon</name><affiliation wicri:level="3"><inist:fA14 i1="03"><s1>Laboratoire de Génie des Procédés Catalytiques, CNRS-CPE, 43 bd 11 novembre 1918, BP 2077</s1><s2>69616 Villeurbanne</s2><s3>FRA</s3><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Villeurbanne</settlement></placeName></affiliation></author><author><name sortKey="Pijolat, Christophe" sort="Pijolat, Christophe" uniqKey="Pijolat C" first="Christophe" last="Pijolat">Christophe Pijolat</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Ecole des Mines de Saint Etienne, Centre SPIN, Dpt MICC, LPMG-UMR CNRS 5148, 58 Cours Fauriel</s1><s2>42023 Saint Etienne</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Saint Etienne</settlement></placeName></affiliation></author><author><name sortKey="Tournier, Guy" sort="Tournier, Guy" uniqKey="Tournier G" first="Guy" last="Tournier">Guy Tournier</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Ecole des Mines de Saint Etienne, Centre SPIN, Dpt MICC, LPMG-UMR CNRS 5148, 58 Cours Fauriel</s1><s2>42023 Saint Etienne</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Saint Etienne</settlement></placeName></affiliation></author><author><name sortKey="Pouteau, Patrick" sort="Pouteau, Patrick" uniqKey="Pouteau P" first="Patrick" last="Pouteau">Patrick Pouteau</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire d'Electronique et de Technologie de l'Information, CEA-LETI/DTBS, 17 rue Martyrs</s1><s2>38054 Grenoble</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Grenoble</settlement></placeName></affiliation></author></analytic><series><title level="j" type="main">Chemical engineering journal : (1996)</title><title level="j" type="abbreviated">Chem. eng. j. : (1996)</title><idno type="ISSN">1385-8947</idno><imprint><date when="2008">2008</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Chemical engineering journal : (1996)</title><title level="j" type="abbreviated">Chem. eng. j. : (1996)</title><idno type="ISSN">1385-8947</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Catalyst activity</term><term>Catalyst support</term><term>Catalytic reaction</term><term>Chemical reaction</term><term>Colloidal suspension</term><term>Enzymatic reaction</term><term>Heterogeneous catalysis</term><term>Kinetics</term><term>Micromachining</term><term>Microreactor</term><term>Modeling</term><term>Nanostructure</term><term>Oxidation</term><term>Porosity</term><term>Production</term><term>Sputtering</term><term>Supported catalyst</term><term>Surface area</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Microréacteur</term><term>Support catalyseur</term><term>Catalyseur sur support</term><term>Réaction chimique</term><term>Production</term><term>Aire superficielle</term><term>Nanostructure</term><term>Microusinage</term><term>Suspension colloïdale</term><term>Réaction catalytique</term><term>Oxydation</term><term>Catalyse hétérogène</term><term>Pulvérisation irradiation</term><term>Porosité</term><term>Réaction enzymatique</term><term>Modélisation</term><term>Activité catalytique</term><term>Cinétique</term></keywords><keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Production</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">When surface-supported chemical reactions are performed in microsystems, high production rate cannot be obtained due to the intrinsically low surface area. Increasing the active surface area of silicon microsystems is a challenge that is addressed in this paper using two original approaches: (i) modifying the structure of silicon by creating nanostructures (black silicon) using conventional etching processes of silicon micromachining or (ii) depositing a layer of porous γ-alurnina by washcoating a colloidal suspension of boehmite onto the silicon surface. The catalytic oxidation of carbon monoxide on platinum was chosen as a first test reaction in the domain of heterogeneous catalysis. In order to perform this reaction, platinum was either deposited by sputtering on silicon devices with black silicon nanostructuration, or impregnated inside the porosity of an alumina layer previously deposited on a silicon device. For specific biological applications, such as proteins analysis, some biological reactions could be advantageously achieved in microsystems using surface-supported species. As an example, an enzymatic reaction was carried out using silicon devices modified with black silicon nanostructuration and further functionalized with trypsin as a model enzyme. The catalytic activity was compared between silicon devices with the same two types of catalysts, comprising or not an enhancement of the surface activity. A minimum 10-fold increase in catalytic activity was estimated from kinetic measurements and represents the augmentation of the active surface really available for reactions. It was also shown how these catalytic materials were integrated in a microreactor increasing its catalytic active surface without modifying its global size.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1385-8947</s0></fA01><fA03 i2="1"><s0>Chem. eng. j. : (1996)</s0></fA03><fA05><s2>135</s2></fA05><fA06><s3>SUP1</s3></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Enhancing surface activity in silicon microreactors : Use of black silicon and alumina as catalyst supports for chemical and biological applications</s1></fA08><fA09 i1="01" i2="1" l="ENG"><s1>Microreaction Technology, IMRET 9: Proceedings of the Ninth International Conference on Microreaction Technology</s1></fA09><fA11 i1="01" i2="1"><s1>ROUMANIE (Marilyne)</s1></fA11><fA11 i1="02" i2="1"><s1>DELATTRE (Cyril)</s1></fA11><fA11 i1="03" i2="1"><s1>MITTLER (Frédérique)</s1></fA11><fA11 i1="04" i2="1"><s1>MARCHAND (Gilles)</s1></fA11><fA11 i1="05" i2="1"><s1>MEILLE (Valérie)</s1></fA11><fA11 i1="06" i2="1"><s1>DE BELLEFON (Claude)</s1></fA11><fA11 i1="07" i2="1"><s1>PIJOLAT (Christophe)</s1></fA11><fA11 i1="08" i2="1"><s1>TOURNIER (Guy)</s1></fA11><fA11 i1="09" i2="1"><s1>POUTEAU (Patrick)</s1></fA11><fA12 i1="01" i2="1"><s1>SCHÜTTE (Rüdiger)</s1><s9>ed.</s9></fA12><fA12 i1="02" i2="1"><s1>RENKEN (Albert)</s1><s9>ed.</s9></fA12><fA12 i1="03" i2="1"><s1>KLEMM (Elias)</s1><s9>ed.</s9></fA12><fA12 i1="04" i2="1"><s1>LIAUW (Marcel A.)</s1><s9>ed.</s9></fA12><fA12 i1="05" i2="1"><s1>MATLOSZ (Michael)</s1><s9>ed.</s9></fA12><fA14 i1="01"><s1>Ecole des Mines de Saint Etienne, Centre SPIN, Dpt MICC, LPMG-UMR CNRS 5148, 58 Cours Fauriel</s1><s2>42023 Saint Etienne</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ></fA14><fA14 i1="02"><s1>Laboratoire d'Electronique et de Technologie de l'Information, CEA-LETI/DTBS, 17 rue Martyrs</s1><s2>38054 Grenoble</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>9 aut.</sZ></fA14><fA14 i1="03"><s1>Laboratoire de Génie des Procédés Catalytiques, CNRS-CPE, 43 bd 11 novembre 1918, BP 2077</s1><s2>69616 Villeurbanne</s2><s3>FRA</s3><sZ>5 aut.</sZ><sZ>6 aut.</sZ></fA14><fA15 i1="01"><s1>Process Technology & Engineering, Evonik Degussa GmbH, Rodenbacher Chaussee 4</s1><s2>63457 Hanau (Wolfgang)</s2><s3>DEU</s3><sZ>1 aut.</sZ></fA15><fA15 i1="02"><s1>Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), SB-ISIC-LGRC-Station 6, Bâtiment CH / CH J2 500</s1><s2>1015 Lausanne</s2><s3>CHE</s3><sZ>2 aut.</sZ></fA15><fA15 i1="03"><s1>Chemnitz University of Technology, Faculty of Natural Sciences, Department of Chemical Technology</s1><s2>09107 Chemnitz</s2><s3>DEU</s3><sZ>3 aut.</sZ></fA15><fA15 i1="04"><s1>Technical Chemistry and Reaction Engineering, ITMC, RWTH Aachen, Worringerweg 1</s1><s2>52074 Aachen</s2><s3>DEU</s3><sZ>4 aut.</sZ></fA15><fA15 i1="05"><s1>CNRS-ENSIC, Laboratoire des Sciences du Genie Chimique, 1, rue Grandville</s1><s2>54001 Nancy</s2><s3>FRA</s3><sZ>5 aut.</sZ></fA15><fA20><s2>S317-S326</s2></fA20><fA21><s1>2008</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>14678</s2><s5>354000173568260490</s5></fA43><fA44><s0>0000</s0><s1>© 2008 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>29 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>08-0055193</s0></fA47><fA60><s1>P</s1><s2>C</s2></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Chemical engineering journal : (1996)</s0></fA64><fA66 i1="01"><s0>NLD</s0></fA66><fC01 i1="01" l="ENG"><s0>When surface-supported chemical reactions are performed in microsystems, high production rate cannot be obtained due to the intrinsically low surface area. Increasing the active surface area of silicon microsystems is a challenge that is addressed in this paper using two original approaches: (i) modifying the structure of silicon by creating nanostructures (black silicon) using conventional etching processes of silicon micromachining or (ii) depositing a layer of porous γ-alurnina by washcoating a colloidal suspension of boehmite onto the silicon surface. The catalytic oxidation of carbon monoxide on platinum was chosen as a first test reaction in the domain of heterogeneous catalysis. In order to perform this reaction, platinum was either deposited by sputtering on silicon devices with black silicon nanostructuration, or impregnated inside the porosity of an alumina layer previously deposited on a silicon device. For specific biological applications, such as proteins analysis, some biological reactions could be advantageously achieved in microsystems using surface-supported species. As an example, an enzymatic reaction was carried out using silicon devices modified with black silicon nanostructuration and further functionalized with trypsin as a model enzyme. The catalytic activity was compared between silicon devices with the same two types of catalysts, comprising or not an enhancement of the surface activity. A minimum 10-fold increase in catalytic activity was estimated from kinetic measurements and represents the augmentation of the active surface really available for reactions. It was also shown how these catalytic materials were integrated in a microreactor increasing its catalytic active surface without modifying its global size.</s0></fC01><fC02 i1="01" i2="X"><s0>001D07H</s0></fC02><fC02 i1="02" i2="X"><s0>001C01A03B</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Microréacteur</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Microreactor</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Microreactor</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Support catalyseur</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Catalyst support</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Soporte catalizador</s0><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Catalyseur sur support</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Supported catalyst</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Catalizador sobre soporte</s0><s5>03</s5></fC03><fC03 i1="04" i2="X" l="FRE"><s0>Réaction chimique</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="ENG"><s0>Chemical reaction</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="SPA"><s0>Reacción química</s0><s5>04</s5></fC03><fC03 i1="05" i2="X" l="FRE"><s0>Production</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="ENG"><s0>Production</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="SPA"><s0>Producción</s0><s5>05</s5></fC03><fC03 i1="06" i2="X" l="FRE"><s0>Aire superficielle</s0><s5>06</s5></fC03><fC03 i1="06" i2="X" l="ENG"><s0>Surface area</s0><s5>06</s5></fC03><fC03 i1="06" i2="X" l="SPA"><s0>Area superficial</s0><s5>06</s5></fC03><fC03 i1="07" i2="X" l="FRE"><s0>Nanostructure</s0><s5>07</s5></fC03><fC03 i1="07" i2="X" l="ENG"><s0>Nanostructure</s0><s5>07</s5></fC03><fC03 i1="07" i2="X" l="SPA"><s0>Nanoestructura</s0><s5>07</s5></fC03><fC03 i1="08" i2="X" l="FRE"><s0>Microusinage</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="ENG"><s0>Micromachining</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="SPA"><s0>Micromaquinado</s0><s5>08</s5></fC03><fC03 i1="09" i2="X" l="FRE"><s0>Suspension colloïdale</s0><s5>09</s5></fC03><fC03 i1="09" i2="X" l="ENG"><s0>Colloidal suspension</s0><s5>09</s5></fC03><fC03 i1="09" i2="X" l="SPA"><s0>Suspensión coloidal</s0><s5>09</s5></fC03><fC03 i1="10" i2="X" l="FRE"><s0>Réaction catalytique</s0><s5>10</s5></fC03><fC03 i1="10" i2="X" l="ENG"><s0>Catalytic reaction</s0><s5>10</s5></fC03><fC03 i1="10" i2="X" l="SPA"><s0>Reacción catalítica</s0><s5>10</s5></fC03><fC03 i1="11" i2="X" l="FRE"><s0>Oxydation</s0><s5>11</s5></fC03><fC03 i1="11" i2="X" l="ENG"><s0>Oxidation</s0><s5>11</s5></fC03><fC03 i1="11" i2="X" l="SPA"><s0>Oxidación</s0><s5>11</s5></fC03><fC03 i1="12" i2="X" l="FRE"><s0>Catalyse hétérogène</s0><s5>12</s5></fC03><fC03 i1="12" i2="X" l="ENG"><s0>Heterogeneous catalysis</s0><s5>12</s5></fC03><fC03 i1="12" i2="X" l="SPA"><s0>Catálisis heterogénea</s0><s5>12</s5></fC03><fC03 i1="13" i2="X" l="FRE"><s0>Pulvérisation irradiation</s0><s5>13</s5></fC03><fC03 i1="13" i2="X" l="ENG"><s0>Sputtering</s0><s5>13</s5></fC03><fC03 i1="13" i2="X" l="SPA"><s0>Pulverización irradiación</s0><s5>13</s5></fC03><fC03 i1="14" i2="X" l="FRE"><s0>Porosité</s0><s5>14</s5></fC03><fC03 i1="14" i2="X" l="ENG"><s0>Porosity</s0><s5>14</s5></fC03><fC03 i1="14" i2="X" l="SPA"><s0>Porosidad</s0><s5>14</s5></fC03><fC03 i1="15" i2="X" l="FRE"><s0>Réaction enzymatique</s0><s5>15</s5></fC03><fC03 i1="15" i2="X" l="ENG"><s0>Enzymatic reaction</s0><s5>15</s5></fC03><fC03 i1="15" i2="X" l="SPA"><s0>Reacción enzimática</s0><s5>15</s5></fC03><fC03 i1="16" i2="X" l="FRE"><s0>Modélisation</s0><s5>16</s5></fC03><fC03 i1="16" i2="X" l="ENG"><s0>Modeling</s0><s5>16</s5></fC03><fC03 i1="16" i2="X" l="SPA"><s0>Modelización</s0><s5>16</s5></fC03><fC03 i1="17" i2="X" l="FRE"><s0>Activité catalytique</s0><s5>17</s5></fC03><fC03 i1="17" i2="X" l="ENG"><s0>Catalyst activity</s0><s5>17</s5></fC03><fC03 i1="17" i2="X" l="SPA"><s0>Actividad catalítica</s0><s5>17</s5></fC03><fC03 i1="18" i2="X" l="FRE"><s0>Cinétique</s0><s5>18</s5></fC03><fC03 i1="18" i2="X" l="ENG"><s0>Kinetics</s0><s5>18</s5></fC03><fC03 i1="18" i2="X" l="SPA"><s0>Cinética</s0><s5>18</s5></fC03><fN21><s1>028</s1></fN21><fN44 i1="01"><s1>OTO</s1></fN44><fN82><s1>OTO</s1></fN82></pA><pR><fA30 i1="01" i2="1" l="ENG"><s1>IMRET 9 : International Conference on Microreaction Technology</s1><s2>9</s2><s3>Potsdam DEU</s3><s4>2006-09-06</s4></fA30></pR></standard></inist><affiliations><list><country><li>France</li></country><region><li>Auvergne-Rhône-Alpes</li><li>Rhône-Alpes</li></region><settlement><li>Grenoble</li><li>Saint Etienne</li><li>Villeurbanne</li></settlement></list><tree><country name="France"><region name="Auvergne-Rhône-Alpes"><name sortKey="Roumanie, Marilyne" sort="Roumanie, Marilyne" uniqKey="Roumanie M" first="Marilyne" last="Roumanie">Marilyne Roumanie</name></region><name sortKey="De Bellefon, Claude" sort="De Bellefon, Claude" uniqKey="De Bellefon C" first="Claude" last="De Bellefon">Claude De Bellefon</name><name sortKey="Delattre, Cyril" sort="Delattre, Cyril" uniqKey="Delattre C" first="Cyril" last="Delattre">Cyril Delattre</name><name sortKey="Marchand, Gilles" sort="Marchand, Gilles" uniqKey="Marchand G" first="Gilles" last="Marchand">Gilles Marchand</name><name sortKey="Meille, Valerie" sort="Meille, Valerie" uniqKey="Meille V" first="Valérie" last="Meille">Valérie Meille</name><name sortKey="Mittler, Frederique" sort="Mittler, Frederique" uniqKey="Mittler F" first="Frédérique" last="Mittler">Frédérique Mittler</name><name sortKey="Pijolat, Christophe" sort="Pijolat, Christophe" uniqKey="Pijolat C" first="Christophe" last="Pijolat">Christophe Pijolat</name><name sortKey="Pouteau, Patrick" sort="Pouteau, Patrick" uniqKey="Pouteau P" first="Patrick" last="Pouteau">Patrick Pouteau</name><name sortKey="Tournier, Guy" sort="Tournier, Guy" uniqKey="Tournier G" first="Guy" last="Tournier">Guy Tournier</name></country></tree></affiliations></record>Pour manipuler ce document 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