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Czochralski growth of RE3Ga5SiO14 (RE=La, Pr, Nd) single crystals for the analysis of the influence of rare earth substitution on piezoelectricity

Identifieur interne : 001318 ( Istex/Corpus ); précédent : 001317; suivant : 001319

Czochralski growth of RE3Ga5SiO14 (RE=La, Pr, Nd) single crystals for the analysis of the influence of rare earth substitution on piezoelectricity

Auteurs : J. Sato ; H. Takeda ; H. Morikoshi ; K. Shimamura ; P. Rudolph ; T. Fukuda

Source :

RBID : ISTEX:3287437C1195150D8C9800326310A9111BDB9E49

English descriptors

Abstract

Abstract: Pr3Ga5SiO14 and Nd3Ga5SiO14 single crystals with constant diameter of 22mm and lengths up to 145mm have been grown by the Czochralski method. The phase identification, site occupancy of cations and axial lattice parameter distribution were determined by X-ray analysis. The transmission spectra within the 340–3200nm wavelength region were measured. The centre of interest are the piezoelectric properties of (2 1̄ 0) and (0 1 0) plates in comparison with former grown La3Ga5SiO14 crystals in order to find out the influence of the rare earth substitution of La3+ by Pr3+ and Nd3+ on the piezoelectric strain constant d11. A decrease of |d11| with increasing atomic number was found giving the hint to the substitution of lanthanum by further elements with larger atomic radii.

Url:
DOI: 10.1016/S0022-0248(98)00362-5

Links to Exploration step

ISTEX:3287437C1195150D8C9800326310A9111BDB9E49

Le document en format XML

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<div type="abstract" xml:lang="en">Abstract: Pr3Ga5SiO14 and Nd3Ga5SiO14 single crystals with constant diameter of 22mm and lengths up to 145mm have been grown by the Czochralski method. The phase identification, site occupancy of cations and axial lattice parameter distribution were determined by X-ray analysis. The transmission spectra within the 340–3200nm wavelength region were measured. The centre of interest are the piezoelectric properties of (2 1̄ 0) and (0 1 0) plates in comparison with former grown La3Ga5SiO14 crystals in order to find out the influence of the rare earth substitution of La3+ by Pr3+ and Nd3+ on the piezoelectric strain constant d11. A decrease of |d11| with increasing atomic number was found giving the hint to the substitution of lanthanum by further elements with larger atomic radii.</div>
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<note type="content">Fig. 1: Projections of the RE3Ga5SiO14 structure along the [1 0 0] (a) and normal to the [0 0 1] direction (b).</note>
<note type="content">Fig. 2: Scheme of the Czochralski growth arrangement with (1,2) – alumina after heaters, (3) – alumina seed holder, (4) – seed, (5) – growing crystal, (6) – melt, (7) – granular ZrO2 isolation, (8) – alumina tumbler, (9) – RF coil and, (10) – alumina pedestal.</note>
<note type="content">Fig. 3: Grown Nd3Ga5SiO14 single crystal.</note>
<note type="content">Fig. 4: Unstable grown Pr3Ga5SiO14 crystal with facetting and spiral growth phenomena.</note>
<note type="content">Fig. 5: Pr3Ga5Si14 single-crystal stable grown in an increased temperature gradient.</note>
<note type="content">Fig. 6: Transmission spectra of Pr3Ga5SiO14 and Nd3Ga5SiO14 crystals obtained from (0 0 1) wafers with a thickness of 0.4mm.</note>
<note type="content">Fig. 7: Axial lattice parameter distribution in Nd3Ga5SiO14 and Pr3Ga5SiO14 CZ crystals grown with pulling rates 1.5 and 1.0mm/h, respectively.</note>
<note type="content">Fig. 8: Piezoelectric strain constant |d11| versus rare earth substitution of Czochralski grown RE3Ga5SiO14 crystals.</note>
<note type="content">Table 1: The site occupancies of cations in RE3Ga5SiO14 crystals (R=3.9%, Rw=4.0%: La3Ga5SiO14; R=3.2%, Rw=3.7%: Pr3Ga5SiO14; R=3.7%, Rw=4.1%: Nd3Ga5SiO14)</note>
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<p>Pr3Ga5SiO14 and Nd3Ga5SiO14 single crystals with constant diameter of 22mm and lengths up to 145mm have been grown by the Czochralski method. The phase identification, site occupancy of cations and axial lattice parameter distribution were determined by X-ray analysis. The transmission spectra within the 340–3200nm wavelength region were measured. The centre of interest are the piezoelectric properties of (2 1̄ 0) and (0 1 0) plates in comparison with former grown La3Ga5SiO14 crystals in order to find out the influence of the rare earth substitution of La3+ by Pr3+ and Nd3+ on the piezoelectric strain constant d11. A decrease of |d11| with increasing atomic number was found giving the hint to the substitution of lanthanum by further elements with larger atomic radii.</p>
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<term>Czochralski growth</term>
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<term>Gallates</term>
</item>
<item>
<term>Rare earth substitution</term>
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<term>Transmittance</term>
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<item>
<term>Piezoelectricity</term>
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<head>
<ce:title>Czochralski growth of RE
<ce:inf>3</ce:inf>
Ga
<ce:inf>5</ce:inf>
SiO
<ce:inf>14</ce:inf>
(RE=La, Pr, Nd) single crystals for the analysis of the influence of rare earth substitution on piezoelectricity</ce:title>
<ce:author-group>
<ce:author>
<ce:given-name>J.</ce:given-name>
<ce:surname>Sato</ce:surname>
<ce:cross-ref refid="AFF1">a</ce:cross-ref>
<ce:cross-ref refid="CORR1">*</ce:cross-ref>
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<ce:author>
<ce:given-name>H.</ce:given-name>
<ce:surname>Takeda</ce:surname>
<ce:cross-ref refid="AFF1">a</ce:cross-ref>
</ce:author>
<ce:author>
<ce:given-name>H.</ce:given-name>
<ce:surname>Morikoshi</ce:surname>
<ce:cross-ref refid="AFF2">b</ce:cross-ref>
</ce:author>
<ce:author>
<ce:given-name>K.</ce:given-name>
<ce:surname>Shimamura</ce:surname>
<ce:cross-ref refid="AFF1">a</ce:cross-ref>
</ce:author>
<ce:author>
<ce:given-name>P.</ce:given-name>
<ce:surname>Rudolph</ce:surname>
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<ce:sup>1</ce:sup>
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<ce:author>
<ce:given-name>T.</ce:given-name>
<ce:surname>Fukuda</ce:surname>
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<ce:textfn>Institute for Materials Research, Tohoku University, Katahira 2-1-1, Aoba-Ku, Sendai 980-8577, Japan</ce:textfn>
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<ce:textfn>Materials Research Center, TDK Corporation, Matsugasita 570-4, Minamihatori, Narita 286-0805, Japan</ce:textfn>
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<ce:label>*</ce:label>
<ce:text>Corresponding author. Fax: +81 22 215 2104; e-mail: juns@lexus.imr.tohoku.ac.jp.</ce:text>
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<ce:note-para>Permanent address: Institute of Crystal Growth, Rudower Chaussee 6, 12489 Berlin, Germany.</ce:note-para>
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<ce:section-title>Abstract</ce:section-title>
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<ce:simple-para>Pr
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Ga
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SiO
<ce:inf>14</ce:inf>
and Nd
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Ga
<ce:inf>5</ce:inf>
SiO
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single crystals with constant diameter of 22
<ce:hsp sp="0.25"></ce:hsp>
mm and lengths up to 145
<ce:hsp sp="0.25"></ce:hsp>
mm have been grown by the Czochralski method. The phase identification, site occupancy of cations and axial lattice parameter distribution were determined by X-ray analysis. The transmission spectra within the 340–3200
<ce:hsp sp="0.25"></ce:hsp>
nm wavelength region were measured. The centre of interest are the piezoelectric properties of (2 1̄ 0) and (0 1 0) plates in comparison with former grown La
<ce:inf>3</ce:inf>
Ga
<ce:inf>5</ce:inf>
SiO
<ce:inf>14</ce:inf>
crystals in order to find out the influence of the rare earth substitution of La
<ce:sup>3+</ce:sup>
by Pr
<ce:sup>3+</ce:sup>
and Nd
<ce:sup>3+</ce:sup>
on the piezoelectric strain constant
<ce:italic>d</ce:italic>
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. A decrease of |
<ce:italic>d</ce:italic>
<ce:inf>11</ce:inf>
| with increasing atomic number was found giving the hint to the substitution of lanthanum by further elements with larger atomic radii.</ce:simple-para>
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<ce:text>Gallates</ce:text>
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<abstract lang="en">Abstract: Pr3Ga5SiO14 and Nd3Ga5SiO14 single crystals with constant diameter of 22mm and lengths up to 145mm have been grown by the Czochralski method. The phase identification, site occupancy of cations and axial lattice parameter distribution were determined by X-ray analysis. The transmission spectra within the 340–3200nm wavelength region were measured. The centre of interest are the piezoelectric properties of (2 1̄ 0) and (0 1 0) plates in comparison with former grown La3Ga5SiO14 crystals in order to find out the influence of the rare earth substitution of La3+ by Pr3+ and Nd3+ on the piezoelectric strain constant d11. A decrease of |d11| with increasing atomic number was found giving the hint to the substitution of lanthanum by further elements with larger atomic radii.</abstract>
<note type="content">Fig. 1: Projections of the RE3Ga5SiO14 structure along the [1 0 0] (a) and normal to the [0 0 1] direction (b).</note>
<note type="content">Fig. 2: Scheme of the Czochralski growth arrangement with (1,2) – alumina after heaters, (3) – alumina seed holder, (4) – seed, (5) – growing crystal, (6) – melt, (7) – granular ZrO2 isolation, (8) – alumina tumbler, (9) – RF coil and, (10) – alumina pedestal.</note>
<note type="content">Fig. 3: Grown Nd3Ga5SiO14 single crystal.</note>
<note type="content">Fig. 4: Unstable grown Pr3Ga5SiO14 crystal with facetting and spiral growth phenomena.</note>
<note type="content">Fig. 5: Pr3Ga5Si14 single-crystal stable grown in an increased temperature gradient.</note>
<note type="content">Fig. 6: Transmission spectra of Pr3Ga5SiO14 and Nd3Ga5SiO14 crystals obtained from (0 0 1) wafers with a thickness of 0.4mm.</note>
<note type="content">Fig. 7: Axial lattice parameter distribution in Nd3Ga5SiO14 and Pr3Ga5SiO14 CZ crystals grown with pulling rates 1.5 and 1.0mm/h, respectively.</note>
<note type="content">Fig. 8: Piezoelectric strain constant |d11| versus rare earth substitution of Czochralski grown RE3Ga5SiO14 crystals.</note>
<note type="content">Table 1: The site occupancies of cations in RE3Ga5SiO14 crystals (R=3.9%, Rw=4.0%: La3Ga5SiO14; R=3.2%, Rw=3.7%: Pr3Ga5SiO14; R=3.7%, Rw=4.1%: Nd3Ga5SiO14)</note>
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