Azide-selective sensor based on tripodal iron complex for direct azide determination in aqueous samples.
Identifieur interne : 000826 ( Ncbi/Checkpoint ); précédent : 000825; suivant : 000827Azide-selective sensor based on tripodal iron complex for direct azide determination in aqueous samples.
Auteurs : Ashok Kumar Singh [Inde] ; Udai P. Singh ; Vaibhave Aggarwal ; Sameena MehtabSource :
- Analytical and bioanalytical chemistry [ 1618-2650 ] ; 2008.
English descriptors
- KwdEn :
- MESH :
- chemical , analysis : Azides.
- chemical , chemistry : Tea.
- chemical , urine : Azides.
- chemistry : Citrus sinensis.
- methods : Potentiometry.
- standards : Potentiometry.
- Electrodes, Solutions, Water.
Abstract
A potentiometric azide-selective sensor based on the use of iron(III) hydrotris(3,5-dimethylpyrazolyl)borate acetylacetonate chloride [Tp(Me2)Fe(acac)Cl] as a neutral carrier for an azide-selective electrode is reported. Effect of various plasticizers, viz. o-nitrophenyloctyl ether (o-NPOE), dioctylphthalate (DOP), dibutylphthalate (DBP), and benzylacetate (BA), and an anion excluder, hexadecyltrimethylammonium bromide (HTAB), with [Tp(Me2)Fe(acac)Cl] complex in poly(vinyl chloride) (PVC) were studied. The best performance was obtained with a membrane composition of [Tp(Me2)Fe(acac)Cl]/HTAB/DOP/PVC in a ratio of 5:2:190:100 (w/w). The sensor exhibits significantly enhanced selectivity toward azide ions over the concentration range 6.3 x 10(-7) to 1.0 x 10(-2) M with a lower detection limit of 3.8 x 10(-7) M and a Nernstian slope of 59.4 +/- 1.1 mV decade(-1). Influences of the membrane composition, pH and possible interfering anions were investigated on the response properties of the electrode. Fast and stable response, good reproducibility, long-term stability and applicability over a wide pH range (3.5-9.0) are demonstrated. The sensor has a response time of 14 s and can be used for at least 45 days without any considerable divergence in the potential response. The proposed electrode shows fairly good discrimination of azide from several inorganic and organic anions. It was successfully applied to the direct determination of azide in orange juice, tea extracts and human urine samples.
DOI: 10.1007/s00216-008-2129-2
PubMed: 18458882
Affiliations:
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Azide-selective sensor based on tripodal iron complex for direct azide determination in aqueous samples.</title><author><name sortKey="Singh, Ashok Kumar" sort="Singh, Ashok Kumar" uniqKey="Singh A" first="Ashok Kumar" last="Singh">Ashok Kumar Singh</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry, Indian Institute of Technology-Roorkee, Roorkee, 247 667, India. akscyfcy@iitr.ernet.in</nlm:affiliation><country xml:lang="fr">Inde</country><wicri:regionArea>Department of Chemistry, Indian Institute of Technology-Roorkee, Roorkee, 247 667</wicri:regionArea><wicri:noRegion>247 667</wicri:noRegion></affiliation></author><author><name sortKey="Singh, Udai P" sort="Singh, Udai P" uniqKey="Singh U" first="Udai P" last="Singh">Udai P. Singh</name></author><author><name sortKey="Aggarwal, Vaibhave" sort="Aggarwal, Vaibhave" uniqKey="Aggarwal V" first="Vaibhave" last="Aggarwal">Vaibhave Aggarwal</name></author><author><name sortKey="Mehtab, Sameena" sort="Mehtab, Sameena" uniqKey="Mehtab S" first="Sameena" last="Mehtab">Sameena Mehtab</name></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2008">2008</date><idno type="RBID">pubmed:18458882</idno><idno type="pmid">18458882</idno><idno type="doi">10.1007/s00216-008-2129-2</idno><idno type="wicri:Area/PubMed/Corpus">000A38</idno><idno type="wicri:Area/PubMed/Curation">000A38</idno><idno type="wicri:Area/PubMed/Checkpoint">000A38</idno><idno type="wicri:Area/Ncbi/Merge">000826</idno><idno type="wicri:Area/Ncbi/Curation">000826</idno><idno type="wicri:Area/Ncbi/Checkpoint">000826</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Azide-selective sensor based on tripodal iron complex for direct azide determination in aqueous samples.</title><author><name sortKey="Singh, Ashok Kumar" sort="Singh, Ashok Kumar" uniqKey="Singh A" first="Ashok Kumar" last="Singh">Ashok Kumar Singh</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry, Indian Institute of Technology-Roorkee, Roorkee, 247 667, India. akscyfcy@iitr.ernet.in</nlm:affiliation><country xml:lang="fr">Inde</country><wicri:regionArea>Department of Chemistry, Indian Institute of Technology-Roorkee, Roorkee, 247 667</wicri:regionArea><wicri:noRegion>247 667</wicri:noRegion></affiliation></author><author><name sortKey="Singh, Udai P" sort="Singh, Udai P" uniqKey="Singh U" first="Udai P" last="Singh">Udai P. Singh</name></author><author><name sortKey="Aggarwal, Vaibhave" sort="Aggarwal, Vaibhave" uniqKey="Aggarwal V" first="Vaibhave" last="Aggarwal">Vaibhave Aggarwal</name></author><author><name sortKey="Mehtab, Sameena" sort="Mehtab, Sameena" uniqKey="Mehtab S" first="Sameena" last="Mehtab">Sameena Mehtab</name></author></analytic><series><title level="j">Analytical and bioanalytical chemistry</title><idno type="eISSN">1618-2650</idno><imprint><date when="2008" type="published">2008</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Azides (analysis)</term><term>Azides (urine)</term><term>Citrus sinensis (chemistry)</term><term>Electrodes</term><term>Potentiometry (methods)</term><term>Potentiometry (standards)</term><term>Solutions</term><term>Tea (chemistry)</term><term>Water</term></keywords><keywords scheme="MESH" type="chemical" qualifier="analysis" xml:lang="en"><term>Azides</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Tea</term></keywords><keywords scheme="MESH" type="chemical" qualifier="urine" xml:lang="en"><term>Azides</term></keywords><keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Citrus sinensis</term></keywords><keywords scheme="MESH" qualifier="methods" xml:lang="en"><term>Potentiometry</term></keywords><keywords scheme="MESH" qualifier="standards" xml:lang="en"><term>Potentiometry</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Electrodes</term><term>Solutions</term><term>Water</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A potentiometric azide-selective sensor based on the use of iron(III) hydrotris(3,5-dimethylpyrazolyl)borate acetylacetonate chloride [Tp(Me2)Fe(acac)Cl] as a neutral carrier for an azide-selective electrode is reported. Effect of various plasticizers, viz. o-nitrophenyloctyl ether (o-NPOE), dioctylphthalate (DOP), dibutylphthalate (DBP), and benzylacetate (BA), and an anion excluder, hexadecyltrimethylammonium bromide (HTAB), with [Tp(Me2)Fe(acac)Cl] complex in poly(vinyl chloride) (PVC) were studied. The best performance was obtained with a membrane composition of [Tp(Me2)Fe(acac)Cl]/HTAB/DOP/PVC in a ratio of 5:2:190:100 (w/w). The sensor exhibits significantly enhanced selectivity toward azide ions over the concentration range 6.3 x 10(-7) to 1.0 x 10(-2) M with a lower detection limit of 3.8 x 10(-7) M and a Nernstian slope of 59.4 +/- 1.1 mV decade(-1). Influences of the membrane composition, pH and possible interfering anions were investigated on the response properties of the electrode. Fast and stable response, good reproducibility, long-term stability and applicability over a wide pH range (3.5-9.0) are demonstrated. The sensor has a response time of 14 s and can be used for at least 45 days without any considerable divergence in the potential response. The proposed electrode shows fairly good discrimination of azide from several inorganic and organic anions. It was successfully applied to the direct determination of azide in orange juice, tea extracts and human urine samples.</div></front></TEI><affiliations><list><country><li>Inde</li></country></list><tree><noCountry><name sortKey="Aggarwal, Vaibhave" sort="Aggarwal, Vaibhave" uniqKey="Aggarwal V" first="Vaibhave" last="Aggarwal">Vaibhave Aggarwal</name><name sortKey="Mehtab, Sameena" sort="Mehtab, Sameena" uniqKey="Mehtab S" first="Sameena" last="Mehtab">Sameena Mehtab</name><name sortKey="Singh, Udai P" sort="Singh, Udai P" uniqKey="Singh U" first="Udai P" last="Singh">Udai P. Singh</name></noCountry><country name="Inde"><noRegion><name sortKey="Singh, Ashok Kumar" sort="Singh, Ashok Kumar" uniqKey="Singh A" first="Ashok Kumar" last="Singh">Ashok Kumar Singh</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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