AustralieFrV1, Istex, Corpus, bibRecord, 000F69

In Situ Study of Catalytic Processes: Neutron Diffraction of a Methanol Synthesis Catalyst at Industrially Relevant Pressure

Identifieur interne : 000F69 ( Istex/Corpus ); précédent : 000F68; suivant : 000F70

In Situ Study of Catalytic Processes: Neutron Diffraction of a Methanol Synthesis Catalyst at Industrially Relevant Pressure

Auteurs : Timur Kandemir ; Frank Girgsdies ; Thomas C. Hansen ; Klaus-Dieter Liss ; Igor Kasatkin ; Edward L. Kunkes ; Gregor Wowsnick ; Nikolas Jacobsen ; Robert Schlögl ; Malte Behrens

Source :

Angewandte Chemie International Edition [ 1433-7851 ] ; 2013-05-03.

RBID : ISTEX:5329AFCC9597EC39DACFC574C9BD6C15F7512670

English descriptors

Abstract

Studying the workplace: An industrial methanol synthesis catalyst operating at high pressure was studied by in situ neutron diffraction. The peculiar microstructure of Cu/ZnO/Al2O3 nanocatalysts was found to be stable under reaction conditions. Stacking fault annealing and brass formation was only observed at temperatures higher than used in the methanol synthesis process, providing support for active role of defects in this catalyst system.

Url:

https://api.istex.fr/document/5329AFCC9597EC39DACFC574C9BD6C15F7512670/fulltext/pdf

DOI: 10.1002/anie.201209539

Links to Exploration step

ISTEX:5329AFCC9597EC39DACFC574C9BD6C15F7512670

Le document en format XML

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<front><div type="abstract">Studying the workplace: An industrial methanol synthesis catalyst operating at high pressure was studied by in situ neutron diffraction. The peculiar microstructure of Cu/ZnO/Al2O3 nanocatalysts was found to be stable under reaction conditions. Stacking fault annealing and brass formation was only observed at temperatures higher than used in the methanol synthesis process, providing support for active role of defects in this catalyst system.</div>
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<abstractGroup><abstract type="graphical" xml:lang="en"><p><b>Studying the workplace</b>
: An industrial methanol synthesis catalyst operating at high pressure was studied by in situ neutron diffraction. The peculiar microstructure of Cu/ZnO/Al<sub>2</sub>
O<sub>3</sub>
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<noteGroup><note xml:id="nss"><p>The authors would like to thank M. Tovar, A. Daramsy, S. Olsen, and E. Stotz for technical support. Financial support was given by the DFG (BE 4767/1‐1) and by the Bayerisches Wissenschaftsministerium (NW‐0810‐0002). ILL and ANSTO are acknowledged for the allocation of beamtime.</p>
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<abstract>Studying the workplace: An industrial methanol synthesis catalyst operating at high pressure was studied by in situ neutron diffraction. The peculiar microstructure of Cu/ZnO/Al2O3 nanocatalysts was found to be stable under reaction conditions. Stacking fault annealing and brass formation was only observed at temperatures higher than used in the methanol synthesis process, providing support for active role of defects in this catalyst system.</abstract>
<note type="content">*The authors would like to thank M. Tovar, A. Daramsy, S. Olsen, and E. Stotz for technical support. Financial support was given by the DFG (BE 4767/1‐1) and by the Bayerisches Wissenschaftsministerium (NW‐0810‐0002). ILL and ANSTO are acknowledged for the allocation of beamtime.</note>
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In Situ Study of Catalytic Processes: Neutron Diffraction of a Methanol Synthesis Catalyst at Industrially Relevant Pressure

In Situ Study of Catalytic Processes: Neutron Diffraction of a Methanol Synthesis Catalyst at Industrially Relevant Pressure

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