Lithium Alkoxide {Li4O4} Cubanes Bridged by Rhodium–Quinonoid Organometalloligands
Identifieur interne : 006752 ( Main/Merge ); précédent : 006751; suivant : 006753Lithium Alkoxide {Li4O4} Cubanes Bridged by Rhodium–Quinonoid Organometalloligands
Auteurs : Seung Uk Son [Corée du Sud] ; Jeffrey A. Reingold ; Sang Bok Kim ; Gene B. Carpenter ; Dwight A. Sweigart [États-Unis]Source :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2005-12-02.
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Abstract
Joining the cubes: The linking of lithium {Li4O4} cubanes by the bifunctional organometalloligand [(η4‐quinone)Rh(cod)]− (cod=cyclooctadiene) results in an unprecedented doubly bridged motif. The dimeric assembly features cubane units that are connected by a transition‐metal complex and that incorporate a quinone oxygen atom at one of the corners.
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DOI: 10.1002/anie.200503050
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ISTEX:B8E70E81738378C00E09C9CD4161801E84732753Le document en format XML
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