Lithium Alkoxide {Li4O4} Cubanes Bridged by Rhodium–Quinonoid Organometalloligands
Identifieur interne : 001C31 ( Istex/Corpus ); précédent : 001C30; suivant : 001C32Lithium Alkoxide {Li4O4} Cubanes Bridged by Rhodium–Quinonoid Organometalloligands
Auteurs : Seung Uk Son ; Jeffrey A. Reingold ; Sang Bok Kim ; Gene B. Carpenter ; Dwight A. SweigartSource :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2005-12-02.
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Abstract
Joining the cubes: The linking of lithium {Li4O4} cubanes by the bifunctional organometalloligand [(η4‐quinone)Rh(cod)]− (cod=cyclooctadiene) results in an unprecedented doubly bridged motif. The dimeric assembly features cubane units that are connected by a transition‐metal complex and that incorporate a quinone oxygen atom at one of the corners.
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DOI: 10.1002/anie.200503050
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ISTEX:B8E70E81738378C00E09C9CD4161801E84732753Le document en format XML
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The dimeric assembly features cubane units that are connected by a transition‐metal complex and that incorporate a quinone oxygen atom at one of the corners.</div></front></TEI><istex><corpusName>wiley</corpusName><author><json:item><name>Seung Uk Son Prof.</name><affiliations><json:string>Department of Chemistry, Sungkyunkwan University, Suwon 440‐746, Korea</json:string></affiliations></json:item><json:item><name>Jeffrey A. Reingold</name><affiliations><json:string>Department of Chemistry, Brown University, Providence, RI 02912, USA, Fax: (+1) 401‐863‐9046</json:string></affiliations></json:item><json:item><name>Sang Bok Kim</name><affiliations><json:string>Department of Chemistry, Brown University, Providence, RI 02912, USA, Fax: (+1) 401‐863‐9046</json:string></affiliations></json:item><json:item><name>Gene B. Carpenter Prof.</name><affiliations><json:string>Department of Chemistry, Brown University, Providence, RI 02912, USA, Fax: (+1) 401‐863‐9046</json:string></affiliations></json:item><json:item><name>Dwight A. Sweigart Prof.</name><affiliations><json:string>Department of Chemistry, Brown University, Providence, RI 02912, USA, Fax: (+1) 401‐863‐9046</json:string><json:string>E-mail: dwight_sweigart@brown.edu</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>cubanes</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>lithium</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>organometalloligands</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>quinones</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>rhodium</value></json:item></subject><articleId><json:string>ANIE200503050</json:string></articleId><language><json:string>eng</json:string></language><abstract>Joining the cubes: The linking of lithium {Li4O4} cubanes by the bifunctional organometalloligand [(η4‐quinone)Rh(cod)]− (cod=cyclooctadiene) results in an unprecedented doubly bridged motif. The dimeric assembly features cubane units that are connected by a transition‐metal complex and that incorporate a quinone oxygen atom at one of the corners.</abstract><qualityIndicators><score>3.966</score><pdfVersion>1.3</pdfVersion><pdfPageSize>595 x 842 pts (A4)</pdfPageSize><refBibsNative>true</refBibsNative><keywordCount>5</keywordCount><abstractCharCount>349</abstractCharCount><pdfWordCount>3402</pdfWordCount><pdfCharCount>19438</pdfCharCount><pdfPageCount>6</pdfPageCount><abstractWordCount>47</abstractWordCount></qualityIndicators><title>Lithium Alkoxide {Li4O4} Cubanes Bridged by Rhodium–Quinonoid Organometalloligands</title><genre.original><json:string>shortCommunication</json:string></genre.original><genre><json:string>brief-communication</json:string></genre><host><volume>44</volume><publisherId><json:string>ANIE</json:string></publisherId><pages><total>6</total><last>7715</last><first>7710</first></pages><issn><json:string>1433-7851</json:string></issn><issue>47</issue><subject><json:item><value>Communication</value></json:item></subject><genre><json:string>journal</json:string></genre><language><json:string>unknown</json:string></language><eissn><json:string>1521-3773</json:string></eissn><title>Angewandte Chemie International Edition</title><doi><json:string>10.1002/(ISSN)1521-3773</json:string></doi></host><publicationDate>2005</publicationDate><copyrightDate>2005</copyrightDate><doi><json:string>10.1002/anie.200503050</json:string></doi><id>B8E70E81738378C00E09C9CD4161801E84732753</id><score>1</score><fulltext><json:item><original>true</original><mimetype>application/pdf</mimetype><extension>pdf</extension><uri>https://api.istex.fr/document/B8E70E81738378C00E09C9CD4161801E84732753/fulltext/pdf</uri></json:item><json:item><original>false</original><mimetype>application/zip</mimetype><extension>zip</extension><uri>https://api.istex.fr/document/B8E70E81738378C00E09C9CD4161801E84732753/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/B8E70E81738378C00E09C9CD4161801E84732753/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">Lithium Alkoxide {Li4O4} Cubanes Bridged by Rhodium–Quinonoid Organometalloligands</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><availability><p>WILEY</p></availability><date>2005</date></publicationStmt><notesStmt><note type="content">*We are grateful to the donors to the Petroleum Research Fund (administered by the American Chemical Society) and to the National Science Foundation (CHE‐0308640) for support of this research. We are also most grateful to Professor Ronald Lawler for insightful discussions and assistance with the NMR simulations.</note></notesStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a" type="main" xml:lang="en">Lithium Alkoxide {Li4O4} Cubanes Bridged by Rhodium–Quinonoid Organometalloligands</title><author><persName><forename type="first">Seung Uk</forename><surname>Son</surname></persName><roleName type="degree">Prof.</roleName><affiliation>Department of Chemistry, Sungkyunkwan University, Suwon 440‐746, Korea</affiliation></author><author><persName><forename type="first">Jeffrey A.</forename><surname>Reingold</surname></persName><affiliation>Department of Chemistry, Brown University, Providence, RI 02912, USA, Fax: (+1) 401‐863‐9046</affiliation></author><author><persName><forename type="first">Sang Bok</forename><surname>Kim</surname></persName><affiliation>Department of Chemistry, Brown University, Providence, RI 02912, USA, Fax: (+1) 401‐863‐9046</affiliation></author><author><persName><forename type="first">Gene B.</forename><surname>Carpenter</surname></persName><roleName type="degree">Prof.</roleName><affiliation>Department of Chemistry, Brown University, Providence, RI 02912, USA, Fax: (+1) 401‐863‐9046</affiliation></author><author><persName><forename type="first">Dwight A.</forename><surname>Sweigart</surname></persName><roleName type="degree">Prof.</roleName><email>dwight_sweigart@brown.edu</email><affiliation>Department of Chemistry, Brown University, Providence, RI 02912, USA, Fax: (+1) 401‐863‐9046</affiliation></author></analytic><monogr><title level="j">Angewandte Chemie International Edition</title><title level="j" type="abbrev">Angewandte Chemie International Edition</title><idno type="pISSN">1433-7851</idno><idno type="eISSN">1521-3773</idno><idno type="DOI">10.1002/(ISSN)1521-3773</idno><imprint><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2005-12-02"></date><biblScope unit="volume">44</biblScope><biblScope unit="issue">47</biblScope><biblScope unit="page" from="7710">7710</biblScope><biblScope unit="page" to="7715">7715</biblScope></imprint></monogr><idno type="istex">B8E70E81738378C00E09C9CD4161801E84732753</idno><idno type="DOI">10.1002/anie.200503050</idno><idno type="ArticleID">ANIE200503050</idno></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>2005</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en" style="graphical"><p>Joining the cubes: The linking of lithium {Li4O4} cubanes by the bifunctional organometalloligand [(η4‐quinone)Rh(cod)]− (cod=cyclooctadiene) results in an unprecedented doubly bridged motif. 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KGaA, Weinheim</copyright><eventGroup><event type="manuscriptReceived" date="2005-08-26"></event><event type="firstOnline" date="2005-11-08"></event><event type="publishedOnlineFinalForm" date="2005-11-28"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.6 mode:FullText source:FullText result:FullText mathml2tex" date="2010-04-20"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-01-03"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-14"></event></eventGroup><numberingGroup><numbering type="pageFirst">7710</numbering><numbering type="pageLast">7715</numbering></numberingGroup><objectNameGroup><objectName elementName="figure">Scheme</objectName></objectNameGroup><linkGroup><link type="toTypesetVersion" href="file:ANIE.ANIE7710.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="9"></count><count type="tableTotal" number="0"></count><count type="referenceTotal" number="47"></count></countGroup><titleGroup><title type="main" xml:lang="en">Lithium Alkoxide {Li<sub>4</sub>O<sub>4</sub>} Cubanes Bridged by Rhodium–Quinonoid Organometalloligands<link href="#nss"></link></title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#ab"><personName><givenNames>Seung Uk</givenNames><familyName>Son</familyName><degrees>Prof.</degrees></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Jeffrey A.</givenNames><familyName>Reingold</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Sang Bok</givenNames><familyName>Kim</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Gene B.</givenNames><familyName>Carpenter</familyName><degrees>Prof.</degrees></personName></creator><creator xml:id="au5" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Dwight A.</givenNames><familyName>Sweigart</familyName><degrees>Prof.</degrees></personName><contactDetails><email>dwight_sweigart@brown.edu</email></contactDetails></creator></creators><affiliationGroup><affiliation xml:id="aa" countryCode="US" type="organization"><unparsedAffiliation>Department of Chemistry, Brown University, Providence, RI 02912, USA, Fax: (+1) 401‐863‐9046</unparsedAffiliation></affiliation><affiliation xml:id="ab" countryCode="KR" type="organization"><unparsedAffiliation>Department of Chemistry, Sungkyunkwan University, Suwon 440‐746, Korea</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">cubanes</keyword><keyword xml:id="kwd2">lithium</keyword><keyword xml:id="kwd3">organometalloligands</keyword><keyword xml:id="kwd4">quinones</keyword><keyword xml:id="kwd5">rhodium</keyword></keywordGroup><supportingInformation><p>Supporting information for this article is available on the WWW under <url href="http://www.wiley-vch.de/contents/jc_2002/2005/z503050_s.pdf">http://www.wiley‐vch.de/contents/jc_2002/2005/z503050_s.pdf</url> or from the author.</p></supportingInformation><abstractGroup><abstract type="graphical" xml:lang="en"><p><b>Joining the cubes</b>: The linking of lithium {Li<sub>4</sub>O<sub>4</sub>} cubanes by the bifunctional organometalloligand [(η<sup>4</sup>‐quinone)Rh(cod)]<sup>−</sup> (cod=cyclooctadiene) results in an unprecedented doubly bridged motif. 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The dimeric assembly features cubane units that are connected by a transition‐metal complex and that incorporate a quinone oxygen atom at one of the corners.</abstract><note type="content">*We are grateful to the donors to the Petroleum Research Fund (administered by the American Chemical Society) and to the National Science Foundation (CHE‐0308640) for support of this research. We are also most grateful to Professor Ronald Lawler for insightful discussions and assistance with the NMR simulations.</note><subject lang="en"><genre>keywords</genre><topic>cubanes</topic><topic>lithium</topic><topic>organometalloligands</topic><topic>quinones</topic><topic>rhodium</topic></subject><relatedItem type="host"><titleInfo><title>Angewandte Chemie International Edition</title></titleInfo><titleInfo type="abbreviated"><title>Angewandte Chemie International Edition</title></titleInfo><genre type="journal">journal</genre><note type="content"> Supporting information for this article is available on the WWW under http://www.wiley‐vch.de/contents/jc_2002/2005/z503050_s.pdf or from the author.</note><subject><genre>article-category</genre><topic>Communication</topic></subject><identifier type="ISSN">1433-7851</identifier><identifier type="eISSN">1521-3773</identifier><identifier type="DOI">10.1002/(ISSN)1521-3773</identifier><identifier type="PublisherID">ANIE</identifier><part><date>2005</date><detail type="volume"><caption>vol.</caption><number>44</number></detail><detail type="issue"><caption>no.</caption><number>47</number></detail><extent unit="pages"><start>7710</start><end>7715</end><total>6</total></extent></part></relatedItem><identifier type="istex">B8E70E81738378C00E09C9CD4161801E84732753</identifier><identifier type="DOI">10.1002/anie.200503050</identifier><identifier type="ArticleID">ANIE200503050</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2005 WILEY‐VCH Verlag GmbH & Co. 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{{Explor lien
|wiki= Ticri/CIDE
|area= HapticV1
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|texte= Lithium Alkoxide {Li4O4} Cubanes Bridged by Rhodium–Quinonoid Organometalloligands
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