Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation.
Identifieur interne : 000414 ( PubMed/Curation ); précédent : 000413; suivant : 000415Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation.
Auteurs : Aurélien Momin [France] ; Fanny Bonnet ; Marc Visseaux ; Laurent Maron ; Josef Takats ; Michael J. Ferguson ; Xavier-Frédéric Le Goff ; François NiefSource :
- Chemical communications (Cambridge, England) [ 1364-548X ] ; 2011.
Abstract
The new divalent thulium compound [Tm(BH(4))(2)(DME)(2)] could be prepared by reduction of [Tm(BH(4))(3)(THF)(3)] or from TmI(2) and KBH(4). It was used as a precursor to the divalent [(Tp(tBu,Me))Tm(BH(4))(THF)] by reaction with potassium tris(2-tBu-4-Me)pyrazolylborate (KTp(tBu,Me)). Both Tm(II) compounds were found active as ε-caprolactone polymerisation catalysts.
DOI: 10.1039/c1cc15294g
PubMed: 21987051
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Ferguson</name></author><author><name sortKey="Le Goff, Xavier Frederic" sort="Le Goff, Xavier Frederic" uniqKey="Le Goff X" first="Xavier-Frédéric" last="Le Goff">Xavier-Frédéric Le Goff</name></author><author><name sortKey="Nief, Francois" sort="Nief, Francois" uniqKey="Nief F" first="François" last="Nief">François Nief</name></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2011">2011</date><idno type="doi">10.1039/c1cc15294g</idno><idno type="RBID">pubmed:21987051</idno><idno type="pmid">21987051</idno><idno type="wicri:Area/PubMed/Corpus">000414</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000414</idno><idno type="wicri:Area/PubMed/Curation">000414</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000414</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation.</title><author><name sortKey="Momin, Aurelien" sort="Momin, Aurelien" uniqKey="Momin A" first="Aurélien" last="Momin">Aurélien Momin</name><affiliation wicri:level="1"><nlm:affiliation>Ecole Polytechnique, CNRS, Laboratoire Hétéroéléments et Coordination, Palaiseau, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Ecole Polytechnique, CNRS, Laboratoire Hétéroéléments et Coordination, Palaiseau</wicri:regionArea></affiliation></author><author><name sortKey="Bonnet, Fanny" sort="Bonnet, Fanny" uniqKey="Bonnet F" first="Fanny" last="Bonnet">Fanny Bonnet</name></author><author><name sortKey="Visseaux, Marc" sort="Visseaux, Marc" uniqKey="Visseaux M" first="Marc" last="Visseaux">Marc Visseaux</name></author><author><name sortKey="Maron, Laurent" sort="Maron, Laurent" uniqKey="Maron L" first="Laurent" last="Maron">Laurent Maron</name></author><author><name sortKey="Takats, Josef" sort="Takats, Josef" uniqKey="Takats J" first="Josef" last="Takats">Josef Takats</name></author><author><name sortKey="Ferguson, Michael J" sort="Ferguson, Michael J" uniqKey="Ferguson M" first="Michael J" last="Ferguson">Michael J. Ferguson</name></author><author><name sortKey="Le Goff, Xavier Frederic" sort="Le Goff, Xavier Frederic" uniqKey="Le Goff X" first="Xavier-Frédéric" last="Le Goff">Xavier-Frédéric Le Goff</name></author><author><name sortKey="Nief, Francois" sort="Nief, Francois" uniqKey="Nief F" first="François" last="Nief">François Nief</name></author></analytic><series><title level="j">Chemical communications (Cambridge, England)</title><idno type="eISSN">1364-548X</idno><imprint><date when="2011" type="published">2011</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The new divalent thulium compound [Tm(BH(4))(2)(DME)(2)] could be prepared by reduction of [Tm(BH(4))(3)(THF)(3)] or from TmI(2) and KBH(4). It was used as a precursor to the divalent [(Tp(tBu,Me))Tm(BH(4))(THF)] by reaction with potassium tris(2-tBu-4-Me)pyrazolylborate (KTp(tBu,Me)). Both Tm(II) compounds were found active as ε-caprolactone polymerisation catalysts.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">21987051</PMID><DateCreated><Year>2011</Year><Month>11</Month><Day>01</Day></DateCreated><DateCompleted><Year>2012</Year><Month>02</Month><Day>27</Day></DateCompleted><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1364-548X</ISSN><JournalIssue CitedMedium="Internet"><Volume>47</Volume><Issue>44</Issue><PubDate><Year>2011</Year><Month>Nov</Month><Day>28</Day></PubDate></JournalIssue><Title>Chemical communications (Cambridge, England)</Title><ISOAbbreviation>Chem. Commun. (Camb.)</ISOAbbreviation></Journal><ArticleTitle>Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation.</ArticleTitle><Pagination><MedlinePgn>12203-5</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1039/c1cc15294g</ELocationID><Abstract><AbstractText>The new divalent thulium compound [Tm(BH(4))(2)(DME)(2)] could be prepared by reduction of [Tm(BH(4))(3)(THF)(3)] or from TmI(2) and KBH(4). It was used as a precursor to the divalent [(Tp(tBu,Me))Tm(BH(4))(THF)] by reaction with potassium tris(2-tBu-4-Me)pyrazolylborate (KTp(tBu,Me)). 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