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Poly[diaqua-penta-kis(μ(4)-benzene-1,2-dicarboxyl-ato)(μ(3)-benzene-1,2-dicarboxyl-ato)tetra-thulium(III)].

Identifieur interne : 000601 ( PubMed/Corpus ); précédent : 000600; suivant : 000602

Poly[diaqua-penta-kis(μ(4)-benzene-1,2-dicarboxyl-ato)(μ(3)-benzene-1,2-dicarboxyl-ato)tetra-thulium(III)].

Auteurs : Guo-Ming Wang ; Chun-Sheng Duan ; Hui-Luan Liu ; Hui Li

Source :

RBID : pubmed:21201858

Abstract

The title compound, [Tm(4)(C(8)H(4)O(4))(6)(H(2)O)(2)](n), has been synthesized hydro-thermally. The asymmetric unit has four unique Tm(III) ions that are six-, seven-, eight- and nine-coordinate. The cations are inter-connected by bridging benzene-1,2-dicarboxyl-ate (BDC) anions to form an infinite two-dimensional framework, in which the BDC ligands adopt three different coordination modes. Adjacent sheets are further packed to form a three-dimensional supra-molecular framework through O-H⋯O hydrogen bonds.

DOI: 10.1107/S1600536808003620
PubMed: 21201858

Links to Exploration step

pubmed:21201858

Le document en format XML

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<RefSource>Angew Chem Int Ed Engl. 2005 Feb 18;44(9):1385-8</RefSource>
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<RefSource>Chem Commun (Camb). 2003 Jun 21;(12):1346-7</RefSource>
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<RefSource>J Inorg Biochem. 1992 May 15;46(3):193-205</RefSource>
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<RefSource>Acta Crystallogr C. 2007 Nov;63(Pt 11):m531-3</RefSource>
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<RefSource>Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22</RefSource>
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<RefSource>Inorg Chem. 2003 Feb 10;42(3):821-6</RefSource>
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