Tunable long lasting phosphorescence due to the selective energy transfer from defects to luminescent centres via tunnelling in Mn(2+) and Tm(3+) co-doped zinc pyrophosphate.
Identifieur interne : 000177 ( PubMed/Corpus ); précédent : 000176; suivant : 000178Tunable long lasting phosphorescence due to the selective energy transfer from defects to luminescent centres via tunnelling in Mn(2+) and Tm(3+) co-doped zinc pyrophosphate.
Auteurs : Ran Pang ; Yonglei Jia ; Ran Zhao ; Haifeng Li ; Jipeng Fu ; Wenzhi Sun ; Lihong Jiang ; Su Zhang ; Chengyu Li ; Qiang SuSource :
- Dalton transactions (Cambridge, England : 2003) [ 1477-9234 ] ; 2014.
English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Diphosphates, Luminescent Agents, Manganese, Thulium, Zinc Compounds.
- Energy Transfer, Luminescent Measurements, Spectroscopy, Near-Infrared.
Abstract
A series of new phosphors Zn2(0.97-x)P2O7:0.06Tm(3+),2xMn(2+) (0 ≤ x ≤ 0.05) were synthesized and their luminescence properties were investigated. The results showed that the defects in all the phosphors were related to Tm(3+), and Mn(2+) merely served as the emission centres. Tm(3+) also acted as an emission centre and yielded blue phosphorescence corresponding to its characteristic f-f emissions in the phosphors where the Mn(2+) concentration was low (x ≤ 0.001), while in the phosphors with high concentrations of Mn(2+) it mainly served as a defect by forming Tm. The electrons thermally released from defects selectively transferred to Mn(2+) centres mainly through thermally-assisted tunnelling and this resulted in their red to near-infrared phosphorescence. By adjusting the ratio of Mn(2+) to Tm(3+) to control the spectral distribution, tunable long lasting phosphorescence from blue to near-infrared was achieved.
DOI: 10.1039/c4dt00223g
PubMed: 24837685
Links to Exploration step
pubmed:24837685Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Tunable long lasting phosphorescence due to the selective energy transfer from defects to luminescent centres via tunnelling in Mn(2+) and Tm(3+) co-doped zinc pyrophosphate.</title>
<author><name sortKey="Pang, Ran" sort="Pang, Ran" uniqKey="Pang R" first="Ran" last="Pang">Ran Pang</name>
<affiliation><nlm:affiliation>State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China. cyli@ciac.ac.cn.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Jia, Yonglei" sort="Jia, Yonglei" uniqKey="Jia Y" first="Yonglei" last="Jia">Yonglei Jia</name>
</author>
<author><name sortKey="Zhao, Ran" sort="Zhao, Ran" uniqKey="Zhao R" first="Ran" last="Zhao">Ran Zhao</name>
</author>
<author><name sortKey="Li, Haifeng" sort="Li, Haifeng" uniqKey="Li H" first="Haifeng" last="Li">Haifeng Li</name>
</author>
<author><name sortKey="Fu, Jipeng" sort="Fu, Jipeng" uniqKey="Fu J" first="Jipeng" last="Fu">Jipeng Fu</name>
</author>
<author><name sortKey="Sun, Wenzhi" sort="Sun, Wenzhi" uniqKey="Sun W" first="Wenzhi" last="Sun">Wenzhi Sun</name>
</author>
<author><name sortKey="Jiang, Lihong" sort="Jiang, Lihong" uniqKey="Jiang L" first="Lihong" last="Jiang">Lihong Jiang</name>
</author>
<author><name sortKey="Zhang, Su" sort="Zhang, Su" uniqKey="Zhang S" first="Su" last="Zhang">Su Zhang</name>
</author>
<author><name sortKey="Li, Chengyu" sort="Li, Chengyu" uniqKey="Li C" first="Chengyu" last="Li">Chengyu Li</name>
</author>
<author><name sortKey="Su, Qiang" sort="Su, Qiang" uniqKey="Su Q" first="Qiang" last="Su">Qiang Su</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PubMed</idno>
<date when="2014">2014</date>
<idno type="doi">10.1039/c4dt00223g</idno>
<idno type="RBID">pubmed:24837685</idno>
<idno type="pmid">24837685</idno>
<idno type="wicri:Area/PubMed/Corpus">000177</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000177</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">Tunable long lasting phosphorescence due to the selective energy transfer from defects to luminescent centres via tunnelling in Mn(2+) and Tm(3+) co-doped zinc pyrophosphate.</title>
<author><name sortKey="Pang, Ran" sort="Pang, Ran" uniqKey="Pang R" first="Ran" last="Pang">Ran Pang</name>
<affiliation><nlm:affiliation>State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China. cyli@ciac.ac.cn.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Jia, Yonglei" sort="Jia, Yonglei" uniqKey="Jia Y" first="Yonglei" last="Jia">Yonglei Jia</name>
</author>
<author><name sortKey="Zhao, Ran" sort="Zhao, Ran" uniqKey="Zhao R" first="Ran" last="Zhao">Ran Zhao</name>
</author>
<author><name sortKey="Li, Haifeng" sort="Li, Haifeng" uniqKey="Li H" first="Haifeng" last="Li">Haifeng Li</name>
</author>
<author><name sortKey="Fu, Jipeng" sort="Fu, Jipeng" uniqKey="Fu J" first="Jipeng" last="Fu">Jipeng Fu</name>
</author>
<author><name sortKey="Sun, Wenzhi" sort="Sun, Wenzhi" uniqKey="Sun W" first="Wenzhi" last="Sun">Wenzhi Sun</name>
</author>
<author><name sortKey="Jiang, Lihong" sort="Jiang, Lihong" uniqKey="Jiang L" first="Lihong" last="Jiang">Lihong Jiang</name>
</author>
<author><name sortKey="Zhang, Su" sort="Zhang, Su" uniqKey="Zhang S" first="Su" last="Zhang">Su Zhang</name>
</author>
<author><name sortKey="Li, Chengyu" sort="Li, Chengyu" uniqKey="Li C" first="Chengyu" last="Li">Chengyu Li</name>
</author>
<author><name sortKey="Su, Qiang" sort="Su, Qiang" uniqKey="Su Q" first="Qiang" last="Su">Qiang Su</name>
</author>
</analytic>
<series><title level="j">Dalton transactions (Cambridge, England : 2003)</title>
<idno type="eISSN">1477-9234</idno>
<imprint><date when="2014" type="published">2014</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Diphosphates (chemistry)</term>
<term>Energy Transfer</term>
<term>Luminescent Agents (chemistry)</term>
<term>Luminescent Measurements</term>
<term>Manganese (chemistry)</term>
<term>Spectroscopy, Near-Infrared</term>
<term>Thulium (chemistry)</term>
<term>Zinc Compounds (chemistry)</term>
</keywords>
<keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Diphosphates</term>
<term>Luminescent Agents</term>
<term>Manganese</term>
<term>Thulium</term>
<term>Zinc Compounds</term>
</keywords>
<keywords scheme="MESH" xml:lang="en"><term>Energy Transfer</term>
<term>Luminescent Measurements</term>
<term>Spectroscopy, Near-Infrared</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">A series of new phosphors Zn2(0.97-x)P2O7:0.06Tm(3+),2xMn(2+) (0 ≤ x ≤ 0.05) were synthesized and their luminescence properties were investigated. The results showed that the defects in all the phosphors were related to Tm(3+), and Mn(2+) merely served as the emission centres. Tm(3+) also acted as an emission centre and yielded blue phosphorescence corresponding to its characteristic f-f emissions in the phosphors where the Mn(2+) concentration was low (x ≤ 0.001), while in the phosphors with high concentrations of Mn(2+) it mainly served as a defect by forming Tm. The electrons thermally released from defects selectively transferred to Mn(2+) centres mainly through thermally-assisted tunnelling and this resulted in their red to near-infrared phosphorescence. By adjusting the ratio of Mn(2+) to Tm(3+) to control the spectral distribution, tunable long lasting phosphorescence from blue to near-infrared was achieved.</div>
</front>
</TEI>
<pubmed><MedlineCitation Owner="NLM" Status="MEDLINE"><PMID Version="1">24837685</PMID>
<DateCreated><Year>2014</Year>
<Month>06</Month>
<Day>04</Day>
</DateCreated>
<DateCompleted><Year>2015</Year>
<Month>04</Month>
<Day>21</Day>
</DateCompleted>
<Article PubModel="Print"><Journal><ISSN IssnType="Electronic">1477-9234</ISSN>
<JournalIssue CitedMedium="Internet"><Volume>43</Volume>
<Issue>25</Issue>
<PubDate><Year>2014</Year>
<Month>Jul</Month>
<Day>7</Day>
</PubDate>
</JournalIssue>
<Title>Dalton transactions (Cambridge, England : 2003)</Title>
<ISOAbbreviation>Dalton Trans</ISOAbbreviation>
</Journal>
<ArticleTitle>Tunable long lasting phosphorescence due to the selective energy transfer from defects to luminescent centres via tunnelling in Mn(2+) and Tm(3+) co-doped zinc pyrophosphate.</ArticleTitle>
<Pagination><MedlinePgn>9661-8</MedlinePgn>
</Pagination>
<ELocationID EIdType="doi" ValidYN="Y">10.1039/c4dt00223g</ELocationID>
<Abstract><AbstractText>A series of new phosphors Zn2(0.97-x)P2O7:0.06Tm(3+),2xMn(2+) (0 ≤ x ≤ 0.05) were synthesized and their luminescence properties were investigated. The results showed that the defects in all the phosphors were related to Tm(3+), and Mn(2+) merely served as the emission centres. Tm(3+) also acted as an emission centre and yielded blue phosphorescence corresponding to its characteristic f-f emissions in the phosphors where the Mn(2+) concentration was low (x ≤ 0.001), while in the phosphors with high concentrations of Mn(2+) it mainly served as a defect by forming Tm. The electrons thermally released from defects selectively transferred to Mn(2+) centres mainly through thermally-assisted tunnelling and this resulted in their red to near-infrared phosphorescence. By adjusting the ratio of Mn(2+) to Tm(3+) to control the spectral distribution, tunable long lasting phosphorescence from blue to near-infrared was achieved.</AbstractText>
</Abstract>
<AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Pang</LastName>
<ForeName>Ran</ForeName>
<Initials>R</Initials>
<AffiliationInfo><Affiliation>State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China. cyli@ciac.ac.cn.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Jia</LastName>
<ForeName>Yonglei</ForeName>
<Initials>Y</Initials>
</Author>
<Author ValidYN="Y"><LastName>Zhao</LastName>
<ForeName>Ran</ForeName>
<Initials>R</Initials>
</Author>
<Author ValidYN="Y"><LastName>Li</LastName>
<ForeName>Haifeng</ForeName>
<Initials>H</Initials>
</Author>
<Author ValidYN="Y"><LastName>Fu</LastName>
<ForeName>Jipeng</ForeName>
<Initials>J</Initials>
</Author>
<Author ValidYN="Y"><LastName>Sun</LastName>
<ForeName>Wenzhi</ForeName>
<Initials>W</Initials>
</Author>
<Author ValidYN="Y"><LastName>Jiang</LastName>
<ForeName>Lihong</ForeName>
<Initials>L</Initials>
</Author>
<Author ValidYN="Y"><LastName>Zhang</LastName>
<ForeName>Su</ForeName>
<Initials>S</Initials>
</Author>
<Author ValidYN="Y"><LastName>Li</LastName>
<ForeName>Chengyu</ForeName>
<Initials>C</Initials>
</Author>
<Author ValidYN="Y"><LastName>Su</LastName>
<ForeName>Qiang</ForeName>
<Initials>Q</Initials>
</Author>
</AuthorList>
<Language>eng</Language>
<PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType>
<PublicationType UI="D013485">Research Support, Non-U.S. Gov't</PublicationType>
</PublicationTypeList>
</Article>
<MedlineJournalInfo><Country>England</Country>
<MedlineTA>Dalton Trans</MedlineTA>
<NlmUniqueID>101176026</NlmUniqueID>
<ISSNLinking>1477-9226</ISSNLinking>
</MedlineJournalInfo>
<ChemicalList><Chemical><RegistryNumber>0</RegistryNumber>
<NameOfSubstance UI="D011756">Diphosphates</NameOfSubstance>
</Chemical>
<Chemical><RegistryNumber>0</RegistryNumber>
<NameOfSubstance UI="D049408">Luminescent Agents</NameOfSubstance>
</Chemical>
<Chemical><RegistryNumber>0</RegistryNumber>
<NameOfSubstance UI="D017967">Zinc Compounds</NameOfSubstance>
</Chemical>
<Chemical><RegistryNumber>42Z2K6ZL8P</RegistryNumber>
<NameOfSubstance UI="D008345">Manganese</NameOfSubstance>
</Chemical>
<Chemical><RegistryNumber>8RKC5ATI4P</RegistryNumber>
<NameOfSubstance UI="D013932">Thulium</NameOfSubstance>
</Chemical>
</ChemicalList>
<CitationSubset>IM</CitationSubset>
<MeshHeadingList><MeshHeading><DescriptorName MajorTopicYN="N" UI="D011756">Diphosphates</DescriptorName>
<QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName>
</MeshHeading>
<MeshHeading><DescriptorName MajorTopicYN="N" UI="D004735">Energy Transfer</DescriptorName>
</MeshHeading>
<MeshHeading><DescriptorName MajorTopicYN="N" UI="D049408">Luminescent Agents</DescriptorName>
<QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName>
</MeshHeading>
<MeshHeading><DescriptorName MajorTopicYN="N" UI="D008163">Luminescent Measurements</DescriptorName>
</MeshHeading>
<MeshHeading><DescriptorName MajorTopicYN="N" UI="D008345">Manganese</DescriptorName>
<QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName>
</MeshHeading>
<MeshHeading><DescriptorName MajorTopicYN="N" UI="D019265">Spectroscopy, Near-Infrared</DescriptorName>
</MeshHeading>
<MeshHeading><DescriptorName MajorTopicYN="N" UI="D013932">Thulium</DescriptorName>
<QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName>
</MeshHeading>
<MeshHeading><DescriptorName MajorTopicYN="N" UI="D017967">Zinc Compounds</DescriptorName>
<QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName>
</MeshHeading>
</MeshHeadingList>
</MedlineCitation>
<PubmedData><History><PubMedPubDate PubStatus="entrez"><Year>2014</Year>
<Month>5</Month>
<Day>20</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="pubmed"><Year>2014</Year>
<Month>5</Month>
<Day>20</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="medline"><Year>2015</Year>
<Month>4</Month>
<Day>22</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
</History>
<PublicationStatus>ppublish</PublicationStatus>
<ArticleIdList><ArticleId IdType="doi">10.1039/c4dt00223g</ArticleId>
<ArticleId IdType="pubmed">24837685</ArticleId>
</ArticleIdList>
</PubmedData>
</pubmed>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/ThuliumV1/Data/PubMed/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000177 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/PubMed/Corpus/biblio.hfd -nk 000177 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Wicri/Terre |area= ThuliumV1 |flux= PubMed |étape= Corpus |type= RBID |clé= pubmed:24837685 |texte= Tunable long lasting phosphorescence due to the selective energy transfer from defects to luminescent centres via tunnelling in Mn(2+) and Tm(3+) co-doped zinc pyrophosphate. }}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/PubMed/Corpus/RBID.i -Sk "pubmed:24837685" \ | HfdSelect -Kh $EXPLOR_AREA/Data/PubMed/Corpus/biblio.hfd \ | NlmPubMed2Wicri -a ThuliumV1
![]() | This area was generated with Dilib version V0.6.21. | ![]() |