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Crystal structure of Tm2Ni12P7

Identifieur interne : 000F54 ( Pascal/Curation ); précédent : 000F53; suivant : 000F55

Crystal structure of Tm2Ni12P7

Auteurs : T. P. Braun [États-Unis] ; F. J. Disalvo [États-Unis]

Source :

RBID : Pascal:00-0371576

Descripteurs français

English descriptors

Abstract

The crystal structure of Tm2Ni12P7 has been determined by single crystal X-ray diffraction. Tm2Ni12P7 crystallizes in the Zr2Fe12P7 structure type with a=9.0577(13) Å and c=3.6641(7) Å. The sample was prepared by melting the elements in a tin flux. All crystals show racemic twinning. The long standing dispute over the the correct space group symmetry (P6 or P63/m) could be solved: Tm2Ni12P7 crystallizes in the non-centrosymmetric space group P6.
pA  
A01 01  1    @0 0925-8388
A03   1    @0 J. alloys compd.
A05       @2 307
A06       @2 1-2
A08 01  1  ENG  @1 Crystal structure of Tm2Ni12P7
A11 01  1    @1 BRAUN (T. P.)
A11 02  1    @1 DISALVO (F. J.)
A14 01      @1 Department of Chemistry and Chemical Biology, Cornell University @2 Ithaca, NY 14853-1301 @3 USA @Z 1 aut. @Z 2 aut.
A20       @1 111-113
A21       @1 2000
A23 01      @0 ENG
A43 01      @1 INIST @2 1151 @5 354000090758630160
A44       @0 0000 @1 © 2000 INIST-CNRS. All rights reserved.
A45       @0 14 ref.
A47 01  1    @0 00-0371576
A60       @1 P
A61       @0 A
A64 01  1    @0 Journal of alloys and compounds
A66 01      @0 CHE
C01 01    ENG  @0 The crystal structure of Tm2Ni12P7 has been determined by single crystal X-ray diffraction. Tm2Ni12P7 crystallizes in the Zr2Fe12P7 structure type with a=9.0577(13) Å and c=3.6641(7) Å. The sample was prepared by melting the elements in a tin flux. All crystals show racemic twinning. The long standing dispute over the the correct space group symmetry (P6 or P63/m) could be solved: Tm2Ni12P7 crystallizes in the non-centrosymmetric space group P6.
C02 01  3    @0 001B60A66D
C02 02  X    @0 240
C03 01  3  FRE  @0 Structure cristalline @5 01
C03 01  3  ENG  @0 Crystal structure @5 01
C03 02  3  FRE  @0 Diffraction RX @5 02
C03 02  3  ENG  @0 XRD @5 02
C03 03  3  FRE  @0 Paramètre cristallin @5 03
C03 03  3  ENG  @0 Lattice parameters @5 03
C03 04  3  FRE  @0 Maclage @5 04
C03 04  3  ENG  @0 Twinning @5 04
C03 05  3  FRE  @0 Groupe espace @5 05
C03 05  3  ENG  @0 Space groups @5 05
C03 06  X  FRE  @0 Polyèdre coordination @5 06
C03 06  X  ENG  @0 Coordination polyhedron @5 06
C03 06  X  SPA  @0 Poliedro coordinación @5 06
C03 07  3  FRE  @0 Monocristal @5 07
C03 07  3  ENG  @0 Monocrystals @5 07
C03 08  X  FRE  @0 Cristal non centrosymétrique @5 08
C03 08  X  ENG  @0 Non centrosymmetric crystals @5 08
C03 08  X  SPA  @0 Cristal sin centro simetría @5 08
C03 09  3  FRE  @0 Composé intermétallique @5 09
C03 09  3  ENG  @0 Intermetallic compounds @5 09
C03 10  3  FRE  @0 Alliage base nickel @2 NK @5 10
C03 10  3  ENG  @0 Nickel base alloys @2 NK @5 10
C03 11  3  FRE  @0 Thulium alliage @5 11
C03 11  3  ENG  @0 Thulium alloys @5 11
C03 12  3  FRE  @0 Phosphore alliage @5 12
C03 12  3  ENG  @0 Phosphorus alloys @5 12
C03 13  3  FRE  @0 Alliage ternaire @5 13
C03 13  3  ENG  @0 Ternary alloys @5 13
C03 14  3  FRE  @0 Etude expérimentale @5 14
C03 14  3  ENG  @0 Experimental study @5 14
C03 15  3  FRE  @0 6166D @2 PAC @4 INC @5 56
C03 16  3  FRE  @0 Alliage Ni56Tm27P17 @2 NK @4 INC @5 92
C03 17  3  FRE  @0 Ni P Tm @4 INC @5 93
C07 01  3  FRE  @0 Métal transition alliage @5 16
C07 01  3  ENG  @0 Transition element alloys @5 16
N21       @1 255

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Pascal:00-0371576

Le document en format XML

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<title xml:lang="en" level="a">Crystal structure of Tm
<sub>2</sub>
Ni
<sub>12</sub>
P
<sub>7</sub>
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<term>Nickel base alloys</term>
<term>Non centrosymmetric crystals</term>
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<div type="abstract" xml:lang="en">The crystal structure of Tm
<sub>2</sub>
Ni
<sub>12</sub>
P
<sub>7</sub>
has been determined by single crystal X-ray diffraction. Tm
<sub>2</sub>
Ni
<sub>12</sub>
P
<sub>7</sub>
crystallizes in the Zr
<sub>2</sub>
Fe
<sub>12</sub>
P
<sub>7</sub>
structure type with a=9.0577(13) Å and c=3.6641(7) Å. The sample was prepared by melting the elements in a tin flux. All crystals show racemic twinning. The long standing dispute over the the correct space group symmetry (P6 or P6
<sub>3</sub>
/m) could be solved: Tm
<sub>2</sub>
Ni
<sub>12</sub>
P
<sub>7</sub>
crystallizes in the non-centrosymmetric space group P6.</div>
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P
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<s0>CHE</s0>
</fA66>
<fC01 i1="01" l="ENG">
<s0>The crystal structure of Tm
<sub>2</sub>
Ni
<sub>12</sub>
P
<sub>7</sub>
has been determined by single crystal X-ray diffraction. Tm
<sub>2</sub>
Ni
<sub>12</sub>
P
<sub>7</sub>
crystallizes in the Zr
<sub>2</sub>
Fe
<sub>12</sub>
P
<sub>7</sub>
structure type with a=9.0577(13) Å and c=3.6641(7) Å. The sample was prepared by melting the elements in a tin flux. All crystals show racemic twinning. The long standing dispute over the the correct space group symmetry (P6 or P6
<sub>3</sub>
/m) could be solved: Tm
<sub>2</sub>
Ni
<sub>12</sub>
P
<sub>7</sub>
crystallizes in the non-centrosymmetric space group P6.</s0>
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<s0>Polyèdre coordination</s0>
<s5>06</s5>
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<s0>Coordination polyhedron</s0>
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<s0>Monocristal</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG">
<s0>Monocrystals</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
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<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Non centrosymmetric crystals</s0>
<s5>08</s5>
</fC03>
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<s5>08</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE">
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<s5>09</s5>
</fC03>
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<s0>Intermetallic compounds</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE">
<s0>Alliage base nickel</s0>
<s2>NK</s2>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG">
<s0>Nickel base alloys</s0>
<s2>NK</s2>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>Thulium alliage</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG">
<s0>Thulium alloys</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE">
<s0>Phosphore alliage</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG">
<s0>Phosphorus alloys</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>Alliage ternaire</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG">
<s0>Ternary alloys</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE">
<s0>Etude expérimentale</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG">
<s0>Experimental study</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE">
<s0>6166D</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE">
<s0>Alliage Ni56Tm27P17</s0>
<s2>NK</s2>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE">
<s0>Ni P Tm</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE">
<s0>Métal transition alliage</s0>
<s5>16</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG">
<s0>Transition element alloys</s0>
<s5>16</s5>
</fC07>
<fN21>
<s1>255</s1>
</fN21>
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