Interplay of spin-allowed and spin-forbidden 5d-4f luminescence from rare earth ions
Identifieur interne :
000659 ( Pascal/Curation );
précédent :
000658;
suivant :
000660
Interplay of spin-allowed and spin-forbidden 5d-4f luminescence from rare earth ions
Auteurs : V. N. Makhov [
Estonie,
Russie] ;
T. Adamberg [
Estonie] ;
M. Kirm [
Estonie] ;
S. Vielhauer [
Estonie] ;
G. Stryganyuk [
Allemagne]
Source :
-
Journal of luminescence [ 0022-2313 ] ; 2008.
RBID : Pascal:08-0285216
Descripteurs français
- Pascal (Inist)
- Photoluminescence,
Transition interdite,
Rayonnement UV extrême,
Trempe,
Transition permise,
Transition niveau énergie,
Dopage,
Addition thulium,
Fluorure de lithium,
Fluorure d'yttrium,
LiYF4.
- Wicri :
English descriptors
Abstract
The conditions for co-existence of emissions from spin-allowed and spin-forbidden 5d-4f transitions in rare earth ions and for thermal quenching of these emissions have been analyzed by taking Tm3+ 5d-4f luminescence in LiYF4:Tm3+ and Lu3+ 5d-4f luminescence in LuF3 as examples. It is shown that temperature behavior of 5d-4f luminescence agrees with the common trends in decreasing energy splitting between the lowest high-spin and low-spin 5d levels as well as decreasing energy gap between the lowest 5d level and the bottom of the conduction band of the host crystal towards heavier rare earth ions (from Er3+ to Lu3+).
pA |
A01 | 01 | 1 | | @0 0022-2313 |
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A02 | 01 | | | @0 JLUMA8 |
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A03 | | 1 | | @0 J. lumin. |
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A05 | | | | @2 128 |
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A06 | | | | @2 5-6 |
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A08 | 01 | 1 | ENG | @1 Interplay of spin-allowed and spin-forbidden 5d-4f luminescence from rare earth ions |
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A09 | 01 | 1 | ENG | @1 Proceesings of th 16th International Conference on Dynamical processes in Excited States of Solids |
---|
A11 | 01 | 1 | | @1 MAKHOV (V. N.) |
---|
A11 | 02 | 1 | | @1 ADAMBERG (T.) |
---|
A11 | 03 | 1 | | @1 KIRM (M.) |
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A11 | 04 | 1 | | @1 VIELHAUER (S.) |
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A11 | 05 | 1 | | @1 STRYGANYUK (G.) |
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A12 | 01 | 1 | | @1 GARCIA-SOLE (José) @9 ed. |
---|
A12 | 02 | 1 | | @1 DE ANDRES (Alicia) @9 ed. |
---|
A12 | 03 | 1 | | @1 BAUSA (Luisa) @9 ed. |
---|
A14 | 01 | | | @1 Institute of Physics, University of Tartu, Riia 142 @2 51014 Tartu @3 EST @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 4 aut. |
---|
A14 | 02 | | | @1 P.N. Lebedev Physical Institute, Leninskii Prospect 53 @2 119991 Moscow @3 RUS @Z 1 aut. |
---|
A14 | 03 | | | @1 HASYLAB at DESY, Notkestra<ss>e 85 @2 22607 Hamburg @3 DEU @Z 5 aut. |
---|
A15 | 01 | | | @1 Departamento de Física de Materiales, Universidad Autónoma de Madrid @2 28049 Madrid @3 ESP @Z 1 aut. @Z 2 aut. |
---|
A15 | 02 | | | @1 Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Cientificas @2 28049 Madrid @3 ESP @Z 3 aut. |
---|
A20 | | | | @1 725-727 |
---|
A21 | | | | @1 2008 |
---|
A23 | 01 | | | @0 ENG |
---|
A43 | 01 | | | @1 INIST @2 14666 @5 354000172659770080 |
---|
A44 | | | | @0 0000 @1 © 2008 INIST-CNRS. All rights reserved. |
---|
A45 | | | | @0 10 ref. |
---|
A47 | 01 | 1 | | @0 08-0285216 |
---|
A60 | | | | @1 P @2 C |
---|
A61 | | | | @0 A |
---|
A64 | 01 | 1 | | @0 Journal of luminescence |
---|
A66 | 01 | | | @0 NLD |
---|
C01 | 01 | | ENG | @0 The conditions for co-existence of emissions from spin-allowed and spin-forbidden 5d-4f transitions in rare earth ions and for thermal quenching of these emissions have been analyzed by taking Tm3+ 5d-4f luminescence in LiYF4:Tm3+ and Lu3+ 5d-4f luminescence in LuF3 as examples. It is shown that temperature behavior of 5d-4f luminescence agrees with the common trends in decreasing energy splitting between the lowest high-spin and low-spin 5d levels as well as decreasing energy gap between the lowest 5d level and the bottom of the conduction band of the host crystal towards heavier rare earth ions (from Er3+ to Lu3+). |
---|
C02 | 01 | 3 | | @0 001B70H55H |
---|
C03 | 01 | 3 | FRE | @0 Photoluminescence @5 02 |
---|
C03 | 01 | 3 | ENG | @0 Photoluminescence @5 02 |
---|
C03 | 02 | 3 | FRE | @0 Transition interdite @5 03 |
---|
C03 | 02 | 3 | ENG | @0 Forbidden transitions @5 03 |
---|
C03 | 03 | 3 | FRE | @0 Rayonnement UV extrême @5 04 |
---|
C03 | 03 | 3 | ENG | @0 Extreme ultraviolet radiation @5 04 |
---|
C03 | 04 | 3 | FRE | @0 Trempe @5 05 |
---|
C03 | 04 | 3 | ENG | @0 Quenching @5 05 |
---|
C03 | 05 | X | FRE | @0 Transition permise @5 06 |
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C03 | 05 | X | ENG | @0 Allowed transition @5 06 |
---|
C03 | 05 | X | SPA | @0 Transición permitida @5 06 |
---|
C03 | 06 | 3 | FRE | @0 Transition niveau énergie @5 07 |
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C03 | 06 | 3 | ENG | @0 Energy-level transitions @5 07 |
---|
C03 | 07 | X | FRE | @0 Dopage @5 08 |
---|
C03 | 07 | X | ENG | @0 Doping @5 08 |
---|
C03 | 07 | X | SPA | @0 Doping @5 08 |
---|
C03 | 08 | 3 | FRE | @0 Addition thulium @5 09 |
---|
C03 | 08 | 3 | ENG | @0 Thulium additions @5 09 |
---|
C03 | 09 | X | FRE | @0 Fluorure de lithium @5 16 |
---|
C03 | 09 | X | ENG | @0 Lithium fluoride @5 16 |
---|
C03 | 09 | X | SPA | @0 Litio fluoruro @5 16 |
---|
C03 | 10 | X | FRE | @0 Fluorure d'yttrium @5 17 |
---|
C03 | 10 | X | ENG | @0 Yttrium fluoride @5 17 |
---|
C03 | 10 | X | SPA | @0 Ytrio fluoruro @5 17 |
---|
C03 | 11 | 3 | FRE | @0 LiYF4 @4 INC @5 52 |
---|
N21 | | | | @1 182 |
---|
|
pR |
A30 | 01 | 1 | ENG | @1 International Conference on Dynamical processes in Excited States of Solids, DPC 07 @2 16 @3 Segovia ESP @4 2007-06-17 |
---|
|
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Le document en format XML
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<series><title level="j" type="main">Journal of luminescence</title>
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<imprint><date when="2008">2008</date>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Allowed transition</term>
<term>Doping</term>
<term>Energy-level transitions</term>
<term>Extreme ultraviolet radiation</term>
<term>Forbidden transitions</term>
<term>Lithium fluoride</term>
<term>Photoluminescence</term>
<term>Quenching</term>
<term>Thulium additions</term>
<term>Yttrium fluoride</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Photoluminescence</term>
<term>Transition interdite</term>
<term>Rayonnement UV extrême</term>
<term>Trempe</term>
<term>Transition permise</term>
<term>Transition niveau énergie</term>
<term>Dopage</term>
<term>Addition thulium</term>
<term>Fluorure de lithium</term>
<term>Fluorure d'yttrium</term>
<term>LiYF4</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Dopage</term>
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<front><div type="abstract" xml:lang="en">The conditions for co-existence of emissions from spin-allowed and spin-forbidden 5d-4f transitions in rare earth ions and for thermal quenching of these emissions have been analyzed by taking Tm<sup>3+</sup>
5d-4f luminescence in LiYF<sub>4</sub>
:Tm<sup>3+</sup>
and Lu<sup>3+</sup>
5d-4f luminescence in LuF<sub>3</sub>
as examples. It is shown that temperature behavior of 5d-4f luminescence agrees with the common trends in decreasing energy splitting between the lowest high-spin and low-spin 5d levels as well as decreasing energy gap between the lowest 5d level and the bottom of the conduction band of the host crystal towards heavier rare earth ions (from Er<sup>3+</sup>
to Lu<sup>3+</sup>
).</div>
</front>
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<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0022-2313</s0>
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<fA03 i2="1"><s0>J. lumin.</s0>
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<fA11 i1="03" i2="1"><s1>KIRM (M.)</s1>
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<fA11 i1="04" i2="1"><s1>VIELHAUER (S.)</s1>
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<fA11 i1="05" i2="1"><s1>STRYGANYUK (G.)</s1>
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<fA12 i1="01" i2="1"><s1>GARCIA-SOLE (José)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="02" i2="1"><s1>DE ANDRES (Alicia)</s1>
<s9>ed.</s9>
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<fA12 i1="03" i2="1"><s1>BAUSA (Luisa)</s1>
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<fA14 i1="01"><s1>Institute of Physics, University of Tartu, Riia 142</s1>
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<sZ>4 aut.</sZ>
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<fA14 i1="02"><s1>P.N. Lebedev Physical Institute, Leninskii Prospect 53</s1>
<s2>119991 Moscow</s2>
<s3>RUS</s3>
<sZ>1 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>HASYLAB at DESY, Notkestrae 85</s1>
<s2>22607 Hamburg</s2>
<s3>DEU</s3>
<sZ>5 aut.</sZ>
</fA14>
<fA15 i1="01"><s1>Departamento de Física de Materiales, Universidad Autónoma de Madrid</s1>
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<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<fA15 i1="02"><s1>Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Cientificas</s1>
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<fA20><s1>725-727</s1>
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<fA21><s1>2008</s1>
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<s5>354000172659770080</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2008 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>10 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>08-0285216</s0>
</fA47>
<fA60><s1>P</s1>
<s2>C</s2>
</fA60>
<fA64 i1="01" i2="1"><s0>Journal of luminescence</s0>
</fA64>
<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>The conditions for co-existence of emissions from spin-allowed and spin-forbidden 5d-4f transitions in rare earth ions and for thermal quenching of these emissions have been analyzed by taking Tm<sup>3+</sup>
5d-4f luminescence in LiYF<sub>4</sub>
:Tm<sup>3+</sup>
and Lu<sup>3+</sup>
5d-4f luminescence in LuF<sub>3</sub>
as examples. It is shown that temperature behavior of 5d-4f luminescence agrees with the common trends in decreasing energy splitting between the lowest high-spin and low-spin 5d levels as well as decreasing energy gap between the lowest 5d level and the bottom of the conduction band of the host crystal towards heavier rare earth ions (from Er<sup>3+</sup>
to Lu<sup>3+</sup>
).</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B70H55H</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Photoluminescence</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Photoluminescence</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Transition interdite</s0>
<s5>03</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Forbidden transitions</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Rayonnement UV extrême</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Extreme ultraviolet radiation</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Trempe</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Quenching</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Transition permise</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Allowed transition</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Transición permitida</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Transition niveau énergie</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Energy-level transitions</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Dopage</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Doping</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Doping</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Addition thulium</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Thulium additions</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Fluorure de lithium</s0>
<s5>16</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Lithium fluoride</s0>
<s5>16</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Litio fluoruro</s0>
<s5>16</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Fluorure d'yttrium</s0>
<s5>17</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Yttrium fluoride</s0>
<s5>17</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Ytrio fluoruro</s0>
<s5>17</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>LiYF4</s0>
<s4>INC</s4>
<s5>52</s5>
</fC03>
<fN21><s1>182</s1>
</fN21>
</pA>
<pR><fA30 i1="01" i2="1" l="ENG"><s1>International Conference on Dynamical processes in Excited States of Solids, DPC 07</s1>
<s2>16</s2>
<s3>Segovia ESP</s3>
<s4>2007-06-17</s4>
</fA30>
</pR>
</standard>
</inist>
</record>
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