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Interplay of spin-allowed and spin-forbidden 5d-4f luminescence from rare earth ions

Identifieur interne : 000659 ( Pascal/Corpus ); précédent : 000658; suivant : 000660

Interplay of spin-allowed and spin-forbidden 5d-4f luminescence from rare earth ions

Auteurs : V. N. Makhov ; T. Adamberg ; M. Kirm ; S. Vielhauer ; G. Stryganyuk

Source :

RBID : Pascal:08-0285216

Descripteurs français

English descriptors

Abstract

The conditions for co-existence of emissions from spin-allowed and spin-forbidden 5d-4f transitions in rare earth ions and for thermal quenching of these emissions have been analyzed by taking Tm3+ 5d-4f luminescence in LiYF4:Tm3+ and Lu3+ 5d-4f luminescence in LuF3 as examples. It is shown that temperature behavior of 5d-4f luminescence agrees with the common trends in decreasing energy splitting between the lowest high-spin and low-spin 5d levels as well as decreasing energy gap between the lowest 5d level and the bottom of the conduction band of the host crystal towards heavier rare earth ions (from Er3+ to Lu3+).

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0022-2313
A02 01      @0 JLUMA8
A03   1    @0 J. lumin.
A05       @2 128
A06       @2 5-6
A08 01  1  ENG  @1 Interplay of spin-allowed and spin-forbidden 5d-4f luminescence from rare earth ions
A09 01  1  ENG  @1 Proceesings of th 16th International Conference on Dynamical processes in Excited States of Solids
A11 01  1    @1 MAKHOV (V. N.)
A11 02  1    @1 ADAMBERG (T.)
A11 03  1    @1 KIRM (M.)
A11 04  1    @1 VIELHAUER (S.)
A11 05  1    @1 STRYGANYUK (G.)
A12 01  1    @1 GARCIA-SOLE (José) @9 ed.
A12 02  1    @1 DE ANDRES (Alicia) @9 ed.
A12 03  1    @1 BAUSA (Luisa) @9 ed.
A14 01      @1 Institute of Physics, University of Tartu, Riia 142 @2 51014 Tartu @3 EST @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 4 aut.
A14 02      @1 P.N. Lebedev Physical Institute, Leninskii Prospect 53 @2 119991 Moscow @3 RUS @Z 1 aut.
A14 03      @1 HASYLAB at DESY, Notkestra<ss>e 85 @2 22607 Hamburg @3 DEU @Z 5 aut.
A15 01      @1 Departamento de Física de Materiales, Universidad Autónoma de Madrid @2 28049 Madrid @3 ESP @Z 1 aut. @Z 2 aut.
A15 02      @1 Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Cientificas @2 28049 Madrid @3 ESP @Z 3 aut.
A20       @1 725-727
A21       @1 2008
A23 01      @0 ENG
A43 01      @1 INIST @2 14666 @5 354000172659770080
A44       @0 0000 @1 © 2008 INIST-CNRS. All rights reserved.
A45       @0 10 ref.
A47 01  1    @0 08-0285216
A60       @1 P @2 C
A61       @0 A
A64 01  1    @0 Journal of luminescence
A66 01      @0 NLD
C01 01    ENG  @0 The conditions for co-existence of emissions from spin-allowed and spin-forbidden 5d-4f transitions in rare earth ions and for thermal quenching of these emissions have been analyzed by taking Tm3+ 5d-4f luminescence in LiYF4:Tm3+ and Lu3+ 5d-4f luminescence in LuF3 as examples. It is shown that temperature behavior of 5d-4f luminescence agrees with the common trends in decreasing energy splitting between the lowest high-spin and low-spin 5d levels as well as decreasing energy gap between the lowest 5d level and the bottom of the conduction band of the host crystal towards heavier rare earth ions (from Er3+ to Lu3+).
C02 01  3    @0 001B70H55H
C03 01  3  FRE  @0 Photoluminescence @5 02
C03 01  3  ENG  @0 Photoluminescence @5 02
C03 02  3  FRE  @0 Transition interdite @5 03
C03 02  3  ENG  @0 Forbidden transitions @5 03
C03 03  3  FRE  @0 Rayonnement UV extrême @5 04
C03 03  3  ENG  @0 Extreme ultraviolet radiation @5 04
C03 04  3  FRE  @0 Trempe @5 05
C03 04  3  ENG  @0 Quenching @5 05
C03 05  X  FRE  @0 Transition permise @5 06
C03 05  X  ENG  @0 Allowed transition @5 06
C03 05  X  SPA  @0 Transición permitida @5 06
C03 06  3  FRE  @0 Transition niveau énergie @5 07
C03 06  3  ENG  @0 Energy-level transitions @5 07
C03 07  X  FRE  @0 Dopage @5 08
C03 07  X  ENG  @0 Doping @5 08
C03 07  X  SPA  @0 Doping @5 08
C03 08  3  FRE  @0 Addition thulium @5 09
C03 08  3  ENG  @0 Thulium additions @5 09
C03 09  X  FRE  @0 Fluorure de lithium @5 16
C03 09  X  ENG  @0 Lithium fluoride @5 16
C03 09  X  SPA  @0 Litio fluoruro @5 16
C03 10  X  FRE  @0 Fluorure d'yttrium @5 17
C03 10  X  ENG  @0 Yttrium fluoride @5 17
C03 10  X  SPA  @0 Ytrio fluoruro @5 17
C03 11  3  FRE  @0 LiYF4 @4 INC @5 52
N21       @1 182
pR  
A30 01  1  ENG  @1 International Conference on Dynamical processes in Excited States of Solids, DPC 07 @2 16 @3 Segovia ESP @4 2007-06-17

Format Inist (serveur)

NO : PASCAL 08-0285216 INIST
ET : Interplay of spin-allowed and spin-forbidden 5d-4f luminescence from rare earth ions
AU : MAKHOV (V. N.); ADAMBERG (T.); KIRM (M.); VIELHAUER (S.); STRYGANYUK (G.); GARCIA-SOLE (José); DE ANDRES (Alicia); BAUSA (Luisa)
AF : Institute of Physics, University of Tartu, Riia 142/51014 Tartu/Estonie (1 aut., 2 aut., 3 aut., 4 aut.); P.N. Lebedev Physical Institute, Leninskii Prospect 53/119991 Moscow/Russie (1 aut.); HASYLAB at DESY, Notkestra<ss>e 85/22607 Hamburg/Allemagne (5 aut.); Departamento de Física de Materiales, Universidad Autónoma de Madrid/28049 Madrid/Espagne (1 aut., 2 aut.); Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Cientificas/28049 Madrid/Espagne (3 aut.)
DT : Publication en série; Congrès; Niveau analytique
SO : Journal of luminescence; ISSN 0022-2313; Coden JLUMA8; Pays-Bas; Da. 2008; Vol. 128; No. 5-6; Pp. 725-727; Bibl. 10 ref.
LA : Anglais
EA : The conditions for co-existence of emissions from spin-allowed and spin-forbidden 5d-4f transitions in rare earth ions and for thermal quenching of these emissions have been analyzed by taking Tm3+ 5d-4f luminescence in LiYF4:Tm3+ and Lu3+ 5d-4f luminescence in LuF3 as examples. It is shown that temperature behavior of 5d-4f luminescence agrees with the common trends in decreasing energy splitting between the lowest high-spin and low-spin 5d levels as well as decreasing energy gap between the lowest 5d level and the bottom of the conduction band of the host crystal towards heavier rare earth ions (from Er3+ to Lu3+).
CC : 001B70H55H
FD : Photoluminescence; Transition interdite; Rayonnement UV extrême; Trempe; Transition permise; Transition niveau énergie; Dopage; Addition thulium; Fluorure de lithium; Fluorure d'yttrium; LiYF4
ED : Photoluminescence; Forbidden transitions; Extreme ultraviolet radiation; Quenching; Allowed transition; Energy-level transitions; Doping; Thulium additions; Lithium fluoride; Yttrium fluoride
SD : Transición permitida; Doping; Litio fluoruro; Ytrio fluoruro
LO : INIST-14666.354000172659770080
ID : 08-0285216

Links to Exploration step

Pascal:08-0285216

Le document en format XML

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<div type="abstract" xml:lang="en">The conditions for co-existence of emissions from spin-allowed and spin-forbidden 5d-4f transitions in rare earth ions and for thermal quenching of these emissions have been analyzed by taking Tm
<sup>3+</sup>
5d-4f luminescence in LiYF
<sub>4</sub>
:Tm
<sup>3+</sup>
and Lu
<sup>3+</sup>
5d-4f luminescence in LuF
<sub>3</sub>
as examples. It is shown that temperature behavior of 5d-4f luminescence agrees with the common trends in decreasing energy splitting between the lowest high-spin and low-spin 5d levels as well as decreasing energy gap between the lowest 5d level and the bottom of the conduction band of the host crystal towards heavier rare earth ions (from Er
<sup>3+</sup>
to Lu
<sup>3+</sup>
).</div>
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<fC01 i1="01" l="ENG">
<s0>The conditions for co-existence of emissions from spin-allowed and spin-forbidden 5d-4f transitions in rare earth ions and for thermal quenching of these emissions have been analyzed by taking Tm
<sup>3+</sup>
5d-4f luminescence in LiYF
<sub>4</sub>
:Tm
<sup>3+</sup>
and Lu
<sup>3+</sup>
5d-4f luminescence in LuF
<sub>3</sub>
as examples. It is shown that temperature behavior of 5d-4f luminescence agrees with the common trends in decreasing energy splitting between the lowest high-spin and low-spin 5d levels as well as decreasing energy gap between the lowest 5d level and the bottom of the conduction band of the host crystal towards heavier rare earth ions (from Er
<sup>3+</sup>
to Lu
<sup>3+</sup>
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<s5>03</s5>
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<s5>06</s5>
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<s5>07</s5>
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<fC03 i1="06" i2="3" l="ENG">
<s0>Energy-level transitions</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Dopage</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Doping</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Doping</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE">
<s0>Addition thulium</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG">
<s0>Thulium additions</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Fluorure de lithium</s0>
<s5>16</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>Lithium fluoride</s0>
<s5>16</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Litio fluoruro</s0>
<s5>16</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Fluorure d'yttrium</s0>
<s5>17</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Yttrium fluoride</s0>
<s5>17</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Ytrio fluoruro</s0>
<s5>17</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>LiYF4</s0>
<s4>INC</s4>
<s5>52</s5>
</fC03>
<fN21>
<s1>182</s1>
</fN21>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>International Conference on Dynamical processes in Excited States of Solids, DPC 07</s1>
<s2>16</s2>
<s3>Segovia ESP</s3>
<s4>2007-06-17</s4>
</fA30>
</pR>
</standard>
<server>
<NO>PASCAL 08-0285216 INIST</NO>
<ET>Interplay of spin-allowed and spin-forbidden 5d-4f luminescence from rare earth ions</ET>
<AU>MAKHOV (V. N.); ADAMBERG (T.); KIRM (M.); VIELHAUER (S.); STRYGANYUK (G.); GARCIA-SOLE (José); DE ANDRES (Alicia); BAUSA (Luisa)</AU>
<AF>Institute of Physics, University of Tartu, Riia 142/51014 Tartu/Estonie (1 aut., 2 aut., 3 aut., 4 aut.); P.N. Lebedev Physical Institute, Leninskii Prospect 53/119991 Moscow/Russie (1 aut.); HASYLAB at DESY, Notkestrae 85/22607 Hamburg/Allemagne (5 aut.); Departamento de Física de Materiales, Universidad Autónoma de Madrid/28049 Madrid/Espagne (1 aut., 2 aut.); Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Cientificas/28049 Madrid/Espagne (3 aut.)</AF>
<DT>Publication en série; Congrès; Niveau analytique</DT>
<SO>Journal of luminescence; ISSN 0022-2313; Coden JLUMA8; Pays-Bas; Da. 2008; Vol. 128; No. 5-6; Pp. 725-727; Bibl. 10 ref.</SO>
<LA>Anglais</LA>
<EA>The conditions for co-existence of emissions from spin-allowed and spin-forbidden 5d-4f transitions in rare earth ions and for thermal quenching of these emissions have been analyzed by taking Tm
<sup>3+</sup>
5d-4f luminescence in LiYF
<sub>4</sub>
:Tm
<sup>3+</sup>
and Lu
<sup>3+</sup>
5d-4f luminescence in LuF
<sub>3</sub>
as examples. It is shown that temperature behavior of 5d-4f luminescence agrees with the common trends in decreasing energy splitting between the lowest high-spin and low-spin 5d levels as well as decreasing energy gap between the lowest 5d level and the bottom of the conduction band of the host crystal towards heavier rare earth ions (from Er
<sup>3+</sup>
to Lu
<sup>3+</sup>
).</EA>
<CC>001B70H55H</CC>
<FD>Photoluminescence; Transition interdite; Rayonnement UV extrême; Trempe; Transition permise; Transition niveau énergie; Dopage; Addition thulium; Fluorure de lithium; Fluorure d'yttrium; LiYF4</FD>
<ED>Photoluminescence; Forbidden transitions; Extreme ultraviolet radiation; Quenching; Allowed transition; Energy-level transitions; Doping; Thulium additions; Lithium fluoride; Yttrium fluoride</ED>
<SD>Transición permitida; Doping; Litio fluoruro; Ytrio fluoruro</SD>
<LO>INIST-14666.354000172659770080</LO>
<ID>08-0285216</ID>
</server>
</inist>
</record>

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