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Spectroscopic investigation of Tm3+:TeO2-WO3 glass

Identifieur interne : 000621 ( Pascal/Curation ); précédent : 000620; suivant : 000622

Spectroscopic investigation of Tm3+:TeO2-WO3 glass

Auteurs : Hamit Kalaycioglu [Turquie] ; Huseyin Cankaya [Turquie] ; M. Natali Cizmeciyan [Turquie] ; Alphan Sennaroglu [Turquie] ; Gonul Ozen [Turquie]

Source :

RBID : Pascal:08-0383061

Descripteurs français

English descriptors

Abstract

We studied the spectroscopic characteristics of telluride glass with the host composition (0.85)Te02-(0.15)W03, containing 0.25 and 1.0mol% thulium oxide (Tm2O3). By analyzing the absorption spectra with the Judd-Ofelt theory, the average radiative lifetimes of 305±7.5 μs and 1.95±0.02ms were determined for the 3F4 and 3H4 levels, respectively. Measured fluorescence lifetime of the 3F4 level decreased from 218 to 51 μs for the 0.25 and 1.0 mol% Tm2O3 doped samples, respectively, indicating the effect of boosted non-radiative decay at higher doping concentrations. A similar trend was observed for the 3H4 level, where the fluorescence lifetime decreased from 1.86ms to 350 μs at these concentrations. The quenching of the 1460nm (3F43H4) emission in favor of the 1800nm (3H43H6) emission due to cross relaxation was further evident in the fluorescence spectra of the samples. The calculated stimulated emission cross sections (3.73±0.1 x 10-21cm2 at 1460nm and 6.57±0.07 x 10-21cm2 at 1808nm) reveal the potential importance of the Tm3+:(0.85)TeO2-(0.15)WO3 glass for applications in fiber-optic amplifiers and fiber lasers.
pA  
A01 01  1    @0 0022-2313
A02 01      @0 JLUMA8
A03   1    @0 J. lumin.
A05       @2 128
A06       @2 9
A08 01  1  ENG  @1 Spectroscopic investigation of Tm3+:TeO2-WO3 glass
A11 01  1    @1 KALAYCIOGLU (Hamit)
A11 02  1    @1 CANKAYA (Huseyin)
A11 03  1    @1 CIZMECIYAN (M. Natali)
A11 04  1    @1 SENNAROGLU (Alphan)
A11 05  1    @1 OZEN (Gonul)
A14 01      @1 Laser Research Laboratory, Department of Physics, Koç University, Rumelifeneri Yolu @2 Sariyer, 34450 Istanbul @3 TUR @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 4 aut.
A14 02      @1 Department of Physics, Istanbul Technical University @2 Maslak, 34469 Istanbul @3 TUR @Z 5 aut.
A20       @1 1501-1506
A21       @1 2008
A23 01      @0 ENG
A43 01      @1 INIST @2 14666 @5 354000196028620200
A44       @0 0000 @1 © 2008 INIST-CNRS. All rights reserved.
A45       @0 25 ref.
A47 01  1    @0 08-0383061
A60       @1 P
A61       @0 A
A64 01  1    @0 Journal of luminescence
A66 01      @0 NLD
C01 01    ENG  @0 We studied the spectroscopic characteristics of telluride glass with the host composition (0.85)Te02-(0.15)W03, containing 0.25 and 1.0mol% thulium oxide (Tm2O3). By analyzing the absorption spectra with the Judd-Ofelt theory, the average radiative lifetimes of 305±7.5 μs and 1.95±0.02ms were determined for the 3F4 and 3H4 levels, respectively. Measured fluorescence lifetime of the 3F4 level decreased from 218 to 51 μs for the 0.25 and 1.0 mol% Tm2O3 doped samples, respectively, indicating the effect of boosted non-radiative decay at higher doping concentrations. A similar trend was observed for the 3H4 level, where the fluorescence lifetime decreased from 1.86ms to 350 μs at these concentrations. The quenching of the 1460nm (3F43H4) emission in favor of the 1800nm (3H43H6) emission due to cross relaxation was further evident in the fluorescence spectra of the samples. The calculated stimulated emission cross sections (3.73±0.1 x 10-21cm2 at 1460nm and 6.57±0.07 x 10-21cm2 at 1808nm) reveal the potential importance of the Tm3+:(0.85)TeO2-(0.15)WO3 glass for applications in fiber-optic amplifiers and fiber lasers.
C02 01  3    @0 001B70H55Q
C03 01  3  FRE  @0 Spectre absorption @5 02
C03 01  3  ENG  @0 Absorption spectra @5 02
C03 02  3  FRE  @0 Théorie Judd Ofelt @5 03
C03 02  3  ENG  @0 Judd-Ofelt theory @5 03
C03 03  3  FRE  @0 Durée vie radiative @5 04
C03 03  3  ENG  @0 Radiative lifetimes @5 04
C03 04  3  FRE  @0 Fluorescence @5 05
C03 04  3  ENG  @0 Fluorescence @5 05
C03 05  3  FRE  @0 Addition thulium @5 06
C03 05  3  ENG  @0 Thulium additions @5 06
C03 06  X  FRE  @0 Dopage @5 07
C03 06  X  ENG  @0 Doping @5 07
C03 06  X  SPA  @0 Doping @5 07
C03 07  X  FRE  @0 Concentration impureté @5 08
C03 07  X  ENG  @0 Impurity density @5 08
C03 07  X  SPA  @0 Concentración impureza @5 08
C03 08  3  FRE  @0 Transition niveau énergie @5 09
C03 08  3  ENG  @0 Energy-level transitions @5 09
C03 09  X  FRE  @0 Relaxation croisée @5 10
C03 09  X  ENG  @0 Cross relaxation @5 10
C03 09  X  SPA  @0 Relajación cruzada @5 10
C03 10  3  FRE  @0 Emission stimulée @5 11
C03 10  3  ENG  @0 Stimulated emission @5 11
C03 11  3  FRE  @0 Tungstate @2 NA @5 15
C03 11  3  ENG  @0 Tungstates @2 NA @5 15
C03 12  3  FRE  @0 Système binaire @5 16
C03 12  3  ENG  @0 Binary systems @5 16
C03 13  3  FRE  @0 Verre chalcogénure @5 17
C03 13  3  ENG  @0 Chalcogenide glasses @5 17
C03 14  3  FRE  @0 Verre de tellurite @4 INC @5 63
N21       @1 245

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Pascal:08-0383061

Le document en format XML

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<title xml:lang="en" level="a">Spectroscopic investigation of Tm
<sup>3+</sup>
:TeO
<sub>2</sub>
-WO
<sub>3</sub>
glass</title>
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<name sortKey="Kalaycioglu, Hamit" sort="Kalaycioglu, Hamit" uniqKey="Kalaycioglu H" first="Hamit" last="Kalaycioglu">Hamit Kalaycioglu</name>
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<title xml:lang="en" level="a">Spectroscopic investigation of Tm
<sup>3+</sup>
:TeO
<sub>2</sub>
-WO
<sub>3</sub>
glass</title>
<author>
<name sortKey="Kalaycioglu, Hamit" sort="Kalaycioglu, Hamit" uniqKey="Kalaycioglu H" first="Hamit" last="Kalaycioglu">Hamit Kalaycioglu</name>
<affiliation wicri:level="1">
<inist:fA14 i1="01">
<s1>Laser Research Laboratory, Department of Physics, Koç University, Rumelifeneri Yolu</s1>
<s2>Sariyer, 34450 Istanbul</s2>
<s3>TUR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
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<author>
<name sortKey="Cankaya, Huseyin" sort="Cankaya, Huseyin" uniqKey="Cankaya H" first="Huseyin" last="Cankaya">Huseyin Cankaya</name>
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<s1>Laser Research Laboratory, Department of Physics, Koç University, Rumelifeneri Yolu</s1>
<s2>Sariyer, 34450 Istanbul</s2>
<s3>TUR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
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<country>Turquie</country>
</affiliation>
</author>
<author>
<name sortKey="Cizmeciyan, M Natali" sort="Cizmeciyan, M Natali" uniqKey="Cizmeciyan M" first="M. Natali" last="Cizmeciyan">M. Natali Cizmeciyan</name>
<affiliation wicri:level="1">
<inist:fA14 i1="01">
<s1>Laser Research Laboratory, Department of Physics, Koç University, Rumelifeneri Yolu</s1>
<s2>Sariyer, 34450 Istanbul</s2>
<s3>TUR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Turquie</country>
</affiliation>
</author>
<author>
<name sortKey="Sennaroglu, Alphan" sort="Sennaroglu, Alphan" uniqKey="Sennaroglu A" first="Alphan" last="Sennaroglu">Alphan Sennaroglu</name>
<affiliation wicri:level="1">
<inist:fA14 i1="01">
<s1>Laser Research Laboratory, Department of Physics, Koç University, Rumelifeneri Yolu</s1>
<s2>Sariyer, 34450 Istanbul</s2>
<s3>TUR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Turquie</country>
</affiliation>
</author>
<author>
<name sortKey="Ozen, Gonul" sort="Ozen, Gonul" uniqKey="Ozen G" first="Gonul" last="Ozen">Gonul Ozen</name>
<affiliation wicri:level="1">
<inist:fA14 i1="02">
<s1>Department of Physics, Istanbul Technical University</s1>
<s2>Maslak, 34469 Istanbul</s2>
<s3>TUR</s3>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Turquie</country>
</affiliation>
</author>
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<series>
<title level="j" type="main">Journal of luminescence</title>
<title level="j" type="abbreviated">J. lumin.</title>
<idno type="ISSN">0022-2313</idno>
<imprint>
<date when="2008">2008</date>
</imprint>
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<title level="j" type="main">Journal of luminescence</title>
<title level="j" type="abbreviated">J. lumin.</title>
<idno type="ISSN">0022-2313</idno>
</seriesStmt>
</fileDesc>
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<keywords scheme="KwdEn" xml:lang="en">
<term>Absorption spectra</term>
<term>Binary systems</term>
<term>Chalcogenide glasses</term>
<term>Cross relaxation</term>
<term>Doping</term>
<term>Energy-level transitions</term>
<term>Fluorescence</term>
<term>Impurity density</term>
<term>Judd-Ofelt theory</term>
<term>Radiative lifetimes</term>
<term>Stimulated emission</term>
<term>Thulium additions</term>
<term>Tungstates</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Spectre absorption</term>
<term>Théorie Judd Ofelt</term>
<term>Durée vie radiative</term>
<term>Fluorescence</term>
<term>Addition thulium</term>
<term>Dopage</term>
<term>Concentration impureté</term>
<term>Transition niveau énergie</term>
<term>Relaxation croisée</term>
<term>Emission stimulée</term>
<term>Tungstate</term>
<term>Système binaire</term>
<term>Verre chalcogénure</term>
<term>Verre de tellurite</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr">
<term>Dopage</term>
</keywords>
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<front>
<div type="abstract" xml:lang="en">We studied the spectroscopic characteristics of telluride glass with the host composition (0.85)Te02-(0.15)W03, containing 0.25 and 1.0mol% thulium oxide (Tm
<sub>2</sub>
O
<sub>3</sub>
). By analyzing the absorption spectra with the Judd-Ofelt theory, the average radiative lifetimes of 305±7.5 μs and 1.95±0.02ms were determined for the
<sup>3</sup>
F
<sub>4</sub>
and
<sup>3</sup>
H
<sub>4</sub>
levels, respectively. Measured fluorescence lifetime of the
<sup>3</sup>
F
<sub>4</sub>
level decreased from 218 to 51 μs for the 0.25 and 1.0 mol% Tm
<sub>2</sub>
O
<sub>3</sub>
doped samples, respectively, indicating the effect of boosted non-radiative decay at higher doping concentrations. A similar trend was observed for the
<sup>3</sup>
H
<sub>4</sub>
level, where the fluorescence lifetime decreased from 1.86ms to 350 μs at these concentrations. The quenching of the 1460nm (
<sup>3</sup>
F
<sub>4</sub>
<sup>3</sup>
H
<sub>4</sub>
) emission in favor of the 1800nm (
<sup>3</sup>
H
<sub>4</sub>
<sup>3</sup>
H
<sub>6</sub>
) emission due to cross relaxation was further evident in the fluorescence spectra of the samples. The calculated stimulated emission cross sections (3.73±0.1 x 10
<sup>-21</sup>
cm
<sup>2</sup>
at 1460nm and 6.57±0.07 x 10
<sup>-21</sup>
cm
<sup>2</sup>
at 1808nm) reveal the potential importance of the Tm
<sup>3+</sup>
:(0.85)TeO
<sub>2</sub>
-(0.15)WO
<sub>3</sub>
glass for applications in fiber-optic amplifiers and fiber lasers.</div>
</front>
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<fA05>
<s2>128</s2>
</fA05>
<fA06>
<s2>9</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG">
<s1>Spectroscopic investigation of Tm
<sup>3+</sup>
:TeO
<sub>2</sub>
-WO
<sub>3</sub>
glass</s1>
</fA08>
<fA11 i1="01" i2="1">
<s1>KALAYCIOGLU (Hamit)</s1>
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<s1>CANKAYA (Huseyin)</s1>
</fA11>
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<s1>CIZMECIYAN (M. Natali)</s1>
</fA11>
<fA11 i1="04" i2="1">
<s1>SENNAROGLU (Alphan)</s1>
</fA11>
<fA11 i1="05" i2="1">
<s1>OZEN (Gonul)</s1>
</fA11>
<fA14 i1="01">
<s1>Laser Research Laboratory, Department of Physics, Koç University, Rumelifeneri Yolu</s1>
<s2>Sariyer, 34450 Istanbul</s2>
<s3>TUR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="02">
<s1>Department of Physics, Istanbul Technical University</s1>
<s2>Maslak, 34469 Istanbul</s2>
<s3>TUR</s3>
<sZ>5 aut.</sZ>
</fA14>
<fA20>
<s1>1501-1506</s1>
</fA20>
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<s1>2008</s1>
</fA21>
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<fA44>
<s0>0000</s0>
<s1>© 2008 INIST-CNRS. All rights reserved.</s1>
</fA44>
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<s0>25 ref.</s0>
</fA45>
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</fA64>
<fA66 i1="01">
<s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG">
<s0>We studied the spectroscopic characteristics of telluride glass with the host composition (0.85)Te02-(0.15)W03, containing 0.25 and 1.0mol% thulium oxide (Tm
<sub>2</sub>
O
<sub>3</sub>
). By analyzing the absorption spectra with the Judd-Ofelt theory, the average radiative lifetimes of 305±7.5 μs and 1.95±0.02ms were determined for the
<sup>3</sup>
F
<sub>4</sub>
and
<sup>3</sup>
H
<sub>4</sub>
levels, respectively. Measured fluorescence lifetime of the
<sup>3</sup>
F
<sub>4</sub>
level decreased from 218 to 51 μs for the 0.25 and 1.0 mol% Tm
<sub>2</sub>
O
<sub>3</sub>
doped samples, respectively, indicating the effect of boosted non-radiative decay at higher doping concentrations. A similar trend was observed for the
<sup>3</sup>
H
<sub>4</sub>
level, where the fluorescence lifetime decreased from 1.86ms to 350 μs at these concentrations. The quenching of the 1460nm (
<sup>3</sup>
F
<sub>4</sub>
<sup>3</sup>
H
<sub>4</sub>
) emission in favor of the 1800nm (
<sup>3</sup>
H
<sub>4</sub>
<sup>3</sup>
H
<sub>6</sub>
) emission due to cross relaxation was further evident in the fluorescence spectra of the samples. The calculated stimulated emission cross sections (3.73±0.1 x 10
<sup>-21</sup>
cm
<sup>2</sup>
at 1460nm and 6.57±0.07 x 10
<sup>-21</sup>
cm
<sup>2</sup>
at 1808nm) reveal the potential importance of the Tm
<sup>3+</sup>
:(0.85)TeO
<sub>2</sub>
-(0.15)WO
<sub>3</sub>
glass for applications in fiber-optic amplifiers and fiber lasers.</s0>
</fC01>
<fC02 i1="01" i2="3">
<s0>001B70H55Q</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE">
<s0>Spectre absorption</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG">
<s0>Absorption spectra</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE">
<s0>Théorie Judd Ofelt</s0>
<s5>03</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG">
<s0>Judd-Ofelt theory</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE">
<s0>Durée vie radiative</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG">
<s0>Radiative lifetimes</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE">
<s0>Fluorescence</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG">
<s0>Fluorescence</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE">
<s0>Addition thulium</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG">
<s0>Thulium additions</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Dopage</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Doping</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Doping</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Concentration impureté</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Impurity density</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Concentración impureza</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE">
<s0>Transition niveau énergie</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG">
<s0>Energy-level transitions</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Relaxation croisée</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>Cross relaxation</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Relajación cruzada</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE">
<s0>Emission stimulée</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG">
<s0>Stimulated emission</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>Tungstate</s0>
<s2>NA</s2>
<s5>15</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG">
<s0>Tungstates</s0>
<s2>NA</s2>
<s5>15</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE">
<s0>Système binaire</s0>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG">
<s0>Binary systems</s0>
<s5>16</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>Verre chalcogénure</s0>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG">
<s0>Chalcogenide glasses</s0>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE">
<s0>Verre de tellurite</s0>
<s4>INC</s4>
<s5>63</s5>
</fC03>
<fN21>
<s1>245</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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   |texte=   Spectroscopic investigation of Tm3+:TeO2-WO3 glass
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