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Pr3+ and Tm3+ containing transparent glass ceramics in the GeO2-PbO-PbF2-LnF3 system

Identifieur interne : 000A07 ( Pascal/Corpus ); précédent : 000A06; suivant : 000A08

Pr3+ and Tm3+ containing transparent glass ceramics in the GeO2-PbO-PbF2-LnF3 system

Auteurs : B. Klimesz ; G. Dominiak-Dzik ; P. Solarz ; M. Zelechower ; W. Ryba-Romanowski

Source :

RBID : Pascal:04-0601458

Descripteurs français

English descriptors

Abstract

Oxyfluoride glasses with composition 50GeO2-(50-x)PbO-xPbF2 (x ≤ 15 mol%) containing praseodymium or thulium were melted from commercial raw materials in normal atmosphere. Based on the results of differential thermal analysis (DTA), glass transition temperatures and oxide glass crystallisation temperatures have been derived. Then the glass samples were thermally treated in order to achieve controlled precipitation of PbF2. Process of formation of glass ceramics has been monitored with the aid of the DTA and X-ray measurements. The control acoustic emission (AE) measurements confirm the DTA results. It has been found that after heat treatment the crystallisation temperatures of investigated materials have been changed due to the PbF2 content and kind of doped ions. The influence of the kind of doped ions on the glass stability was observed. The effect of thermal treatment on the absorption spectra and kinetics of the fluorescent levels of Pr3+ and Tm3+ was studied. In the case of Tm3+ doped systems it was found that this effect on the relaxation of the 1G4 level was weak, whereas the decay of the 3H4 level was slower by a factor of 3 roughly with respect to that recorded with as-melted glass. Relaxation rates of the 3P0 and 1D2 levels of Pr3+ showed marked dependence on both the PbF2 and Pr3- content in as-melted glass and in glass ceramics.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0925-8388
A03   1    @0 J. alloys compd.
A05       @2 382
A08 01  1  ENG  @1 Pr3+ and Tm3+ containing transparent glass ceramics in the GeO2-PbO-PbF2-LnF3 system
A09 01  1  ENG  @1 Proceedings of the European Materials Research Society Fall Meeting, Symposium B, September 15-19, 2003, Warsaw, Poland
A11 01  1    @1 KLIMESZ (B.)
A11 02  1    @1 DOMINIAK-DZIK (G.)
A11 03  1    @1 SOLARZ (P.)
A11 04  1    @1 ZELECHOWER (M.)
A11 05  1    @1 RYBA-ROMANOWSKI (W.)
A12 01  1    @1 PASZKOWICZ (W.) @9 ed.
A12 02  1    @1 PELKA (J. B.) @9 ed.
A14 01      @1 Physical Laboratory, Opole Technical University, ul. Ozimska 75 @2 Opole 45-370 @3 POL @Z 1 aut.
A14 02      @1 Institute of Low Temperature and Structure Research, Polish Academy of Sciences, ul. Okólna 2 @2 50-395 Wroclaw @3 POL @Z 2 aut. @Z 3 aut. @Z 5 aut.
A14 03      @1 Department of Material Science, Silesian University of Technology, ul. Krasiñskiego 8 @2 Katowice 40-019 @3 POL @Z 4 aut.
A15 01      @1 Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46 @2 02-668 Warsaw @3 POL @Z 1 aut. @Z 2 aut.
A18 01  1    @1 European Materials Research Society (E-MRS) @2 67037 Strasbourg @3 FRA @9 patr.
A20       @1 292-299
A21       @1 2004
A23 01      @0 ENG
A43 01      @1 INIST @2 1151 @5 354000122631830470
A44       @0 0000 @1 © 2004 INIST-CNRS. All rights reserved.
A45       @0 8 ref.
A47 01  1    @0 04-0601458
A60       @1 P @2 C
A61       @0 A
A64 01  1    @0 Journal of alloys and compounds
A66 01      @0 CHE
C01 01    ENG  @0 Oxyfluoride glasses with composition 50GeO2-(50-x)PbO-xPbF2 (x ≤ 15 mol%) containing praseodymium or thulium were melted from commercial raw materials in normal atmosphere. Based on the results of differential thermal analysis (DTA), glass transition temperatures and oxide glass crystallisation temperatures have been derived. Then the glass samples were thermally treated in order to achieve controlled precipitation of PbF2. Process of formation of glass ceramics has been monitored with the aid of the DTA and X-ray measurements. The control acoustic emission (AE) measurements confirm the DTA results. It has been found that after heat treatment the crystallisation temperatures of investigated materials have been changed due to the PbF2 content and kind of doped ions. The influence of the kind of doped ions on the glass stability was observed. The effect of thermal treatment on the absorption spectra and kinetics of the fluorescent levels of Pr3+ and Tm3+ was studied. In the case of Tm3+ doped systems it was found that this effect on the relaxation of the 1G4 level was weak, whereas the decay of the 3H4 level was slower by a factor of 3 roughly with respect to that recorded with as-melted glass. Relaxation rates of the 3P0 and 1D2 levels of Pr3+ showed marked dependence on both the PbF2 and Pr3- content in as-melted glass and in glass ceramics.
C02 01  3    @0 001B60D70P
C02 02  3    @0 001B70H55Q
C03 01  3  FRE  @0 Analyse thermique différentielle @5 02
C03 01  3  ENG  @0 Differential thermal analysis @5 02
C03 02  3  FRE  @0 Transition vitreuse @5 03
C03 02  3  ENG  @0 Glass transition @5 03
C03 03  3  FRE  @0 Cristallisation @5 04
C03 03  3  ENG  @0 Crystallization @5 04
C03 04  3  FRE  @0 Traitement thermique @5 05
C03 04  3  ENG  @0 Heat treatments @5 05
C03 05  3  FRE  @0 Précipitation @5 06
C03 05  3  ENG  @0 Precipitation @5 06
C03 06  3  FRE  @0 Formation verre @5 07
C03 06  3  ENG  @0 Glass formation @5 07
C03 07  3  FRE  @0 Mesure acoustique @5 08
C03 07  3  ENG  @0 Acoustic measurement @5 08
C03 08  3  FRE  @0 Essai émission acoustique @5 09
C03 08  3  ENG  @0 Acoustic emission testing @5 09
C03 09  3  FRE  @0 Fluorescence @5 10
C03 09  3  ENG  @0 Fluorescence @5 10
C03 10  3  FRE  @0 Spectre absorption @5 11
C03 10  3  ENG  @0 Absorption spectra @5 11
C03 11  3  FRE  @0 Propriété optique @5 12
C03 11  3  ENG  @0 Optical properties @5 12
C03 12  3  FRE  @0 Composition chimique @5 13
C03 12  3  ENG  @0 Chemical composition @5 13
C03 13  X  FRE  @0 Matériau transparent @5 15
C03 13  X  ENG  @0 Transparent material @5 15
C03 13  X  SPA  @0 Material transparente @5 15
C03 14  3  FRE  @0 Vitrocéramique @5 16
C03 14  3  ENG  @0 Glass ceramics @5 16
C03 15  3  FRE  @0 Oxyfluorure @2 NA @5 17
C03 15  3  ENG  @0 Oxyfluorides @2 NA @5 17
C03 16  3  FRE  @0 Verre @5 18
C03 16  3  ENG  @0 Glass @5 18
C03 17  3  FRE  @0 Pr @4 INC @5 52
C03 18  3  FRE  @0 Tm @4 INC @5 53
C03 19  3  FRE  @0 6470P @4 INC @5 56
C03 20  3  FRE  @0 7855Q @4 INC @5 57
C07 01  3  FRE  @0 Lanthanide @2 NC @5 48
C07 01  3  ENG  @0 Rare earths @2 NC @5 48
C07 02  3  FRE  @0 Actinide @2 NC @5 49
C07 02  3  ENG  @0 Actinides @2 NC @5 49
N21       @1 348
N44 01      @1 PSI
N82       @1 PSI
pR  
A30 01  1  ENG  @1 European Materials Research Society Fall Meeting. Symposium B @3 Warsaw POL @4 2003-09-15

Format Inist (serveur)

NO : PASCAL 04-0601458 INIST
ET : Pr3+ and Tm3+ containing transparent glass ceramics in the GeO2-PbO-PbF2-LnF3 system
AU : KLIMESZ (B.); DOMINIAK-DZIK (G.); SOLARZ (P.); ZELECHOWER (M.); RYBA-ROMANOWSKI (W.); PASZKOWICZ (W.); PELKA (J. B.)
AF : Physical Laboratory, Opole Technical University, ul. Ozimska 75/Opole 45-370/Pologne (1 aut.); Institute of Low Temperature and Structure Research, Polish Academy of Sciences, ul. Okólna 2/50-395 Wroclaw/Pologne (2 aut., 3 aut., 5 aut.); Department of Material Science, Silesian University of Technology, ul. Krasiñskiego 8/Katowice 40-019/Pologne (4 aut.); Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46/02-668 Warsaw/Pologne (1 aut., 2 aut.)
DT : Publication en série; Congrès; Niveau analytique
SO : Journal of alloys and compounds; ISSN 0925-8388; Suisse; Da. 2004; Vol. 382; Pp. 292-299; Bibl. 8 ref.
LA : Anglais
EA : Oxyfluoride glasses with composition 50GeO2-(50-x)PbO-xPbF2 (x ≤ 15 mol%) containing praseodymium or thulium were melted from commercial raw materials in normal atmosphere. Based on the results of differential thermal analysis (DTA), glass transition temperatures and oxide glass crystallisation temperatures have been derived. Then the glass samples were thermally treated in order to achieve controlled precipitation of PbF2. Process of formation of glass ceramics has been monitored with the aid of the DTA and X-ray measurements. The control acoustic emission (AE) measurements confirm the DTA results. It has been found that after heat treatment the crystallisation temperatures of investigated materials have been changed due to the PbF2 content and kind of doped ions. The influence of the kind of doped ions on the glass stability was observed. The effect of thermal treatment on the absorption spectra and kinetics of the fluorescent levels of Pr3+ and Tm3+ was studied. In the case of Tm3+ doped systems it was found that this effect on the relaxation of the 1G4 level was weak, whereas the decay of the 3H4 level was slower by a factor of 3 roughly with respect to that recorded with as-melted glass. Relaxation rates of the 3P0 and 1D2 levels of Pr3+ showed marked dependence on both the PbF2 and Pr3- content in as-melted glass and in glass ceramics.
CC : 001B60D70P; 001B70H55Q
FD : Analyse thermique différentielle; Transition vitreuse; Cristallisation; Traitement thermique; Précipitation; Formation verre; Mesure acoustique; Essai émission acoustique; Fluorescence; Spectre absorption; Propriété optique; Composition chimique; Matériau transparent; Vitrocéramique; Oxyfluorure; Verre; Pr; Tm; 6470P; 7855Q
FG : Lanthanide; Actinide
ED : Differential thermal analysis; Glass transition; Crystallization; Heat treatments; Precipitation; Glass formation; Acoustic measurement; Acoustic emission testing; Fluorescence; Absorption spectra; Optical properties; Chemical composition; Transparent material; Glass ceramics; Oxyfluorides; Glass
EG : Rare earths; Actinides
SD : Material transparente
LO : INIST-1151.354000122631830470
ID : 04-0601458

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Pascal:04-0601458

Le document en format XML

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<title xml:lang="en" level="a">Pr
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and Tm
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containing transparent glass ceramics in the GeO
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-PbO-PbF
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-LnF
<sub>3</sub>
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<sZ>4 aut.</sZ>
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</author>
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<term>Chemical composition</term>
<term>Crystallization</term>
<term>Differential thermal analysis</term>
<term>Fluorescence</term>
<term>Glass</term>
<term>Glass ceramics</term>
<term>Glass formation</term>
<term>Glass transition</term>
<term>Heat treatments</term>
<term>Optical properties</term>
<term>Oxyfluorides</term>
<term>Precipitation</term>
<term>Transparent material</term>
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<term>Analyse thermique différentielle</term>
<term>Transition vitreuse</term>
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<term>Précipitation</term>
<term>Formation verre</term>
<term>Mesure acoustique</term>
<term>Essai émission acoustique</term>
<term>Fluorescence</term>
<term>Spectre absorption</term>
<term>Propriété optique</term>
<term>Composition chimique</term>
<term>Matériau transparent</term>
<term>Vitrocéramique</term>
<term>Oxyfluorure</term>
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<div type="abstract" xml:lang="en">Oxyfluoride glasses with composition 50GeO
<sub>2</sub>
-(50-x)PbO-xPbF
<sub>2</sub>
(x ≤ 15 mol%) containing praseodymium or thulium were melted from commercial raw materials in normal atmosphere. Based on the results of differential thermal analysis (DTA), glass transition temperatures and oxide glass crystallisation temperatures have been derived. Then the glass samples were thermally treated in order to achieve controlled precipitation of PbF
<sub>2</sub>
. Process of formation of glass ceramics has been monitored with the aid of the DTA and X-ray measurements. The control acoustic emission (AE) measurements confirm the DTA results. It has been found that after heat treatment the crystallisation temperatures of investigated materials have been changed due to the PbF
<sub>2</sub>
content and kind of doped ions. The influence of the kind of doped ions on the glass stability was observed. The effect of thermal treatment on the absorption spectra and kinetics of the fluorescent levels of Pr
<sup>3+</sup>
and Tm
<sup>3+</sup>
was studied. In the case of Tm
<sup>3+</sup>
doped systems it was found that this effect on the relaxation of the
<sup>1</sup>
G
<sub>4</sub>
level was weak, whereas the decay of the
<sup>3</sup>
H
<sub>4</sub>
level was slower by a factor of 3 roughly with respect to that recorded with as-melted glass. Relaxation rates of the
<sup>3</sup>
P
<sub>0</sub>
and
<sup>1</sup>
D
<sub>2</sub>
levels of Pr
<sup>3+</sup>
showed marked dependence on both the PbF
<sub>2</sub>
and Pr
<sup>3-</sup>
content in as-melted glass and in glass ceramics.</div>
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<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
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<fA14 i1="03">
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<sZ>4 aut.</sZ>
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<s1>European Materials Research Society (E-MRS)</s1>
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</fA43>
<fA44>
<s0>0000</s0>
<s1>© 2004 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45>
<s0>8 ref.</s0>
</fA45>
<fA47 i1="01" i2="1">
<s0>04-0601458</s0>
</fA47>
<fA60>
<s1>P</s1>
<s2>C</s2>
</fA60>
<fA61>
<s0>A</s0>
</fA61>
<fA64 i1="01" i2="1">
<s0>Journal of alloys and compounds</s0>
</fA64>
<fA66 i1="01">
<s0>CHE</s0>
</fA66>
<fC01 i1="01" l="ENG">
<s0>Oxyfluoride glasses with composition 50GeO
<sub>2</sub>
-(50-x)PbO-xPbF
<sub>2</sub>
(x ≤ 15 mol%) containing praseodymium or thulium were melted from commercial raw materials in normal atmosphere. Based on the results of differential thermal analysis (DTA), glass transition temperatures and oxide glass crystallisation temperatures have been derived. Then the glass samples were thermally treated in order to achieve controlled precipitation of PbF
<sub>2</sub>
. Process of formation of glass ceramics has been monitored with the aid of the DTA and X-ray measurements. The control acoustic emission (AE) measurements confirm the DTA results. It has been found that after heat treatment the crystallisation temperatures of investigated materials have been changed due to the PbF
<sub>2</sub>
content and kind of doped ions. The influence of the kind of doped ions on the glass stability was observed. The effect of thermal treatment on the absorption spectra and kinetics of the fluorescent levels of Pr
<sup>3+</sup>
and Tm
<sup>3+</sup>
was studied. In the case of Tm
<sup>3+</sup>
doped systems it was found that this effect on the relaxation of the
<sup>1</sup>
G
<sub>4</sub>
level was weak, whereas the decay of the
<sup>3</sup>
H
<sub>4</sub>
level was slower by a factor of 3 roughly with respect to that recorded with as-melted glass. Relaxation rates of the
<sup>3</sup>
P
<sub>0</sub>
and
<sup>1</sup>
D
<sub>2</sub>
levels of Pr
<sup>3+</sup>
showed marked dependence on both the PbF
<sub>2</sub>
and Pr
<sup>3-</sup>
content in as-melted glass and in glass ceramics.</s0>
</fC01>
<fC02 i1="01" i2="3">
<s0>001B60D70P</s0>
</fC02>
<fC02 i1="02" i2="3">
<s0>001B70H55Q</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE">
<s0>Analyse thermique différentielle</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG">
<s0>Differential thermal analysis</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE">
<s0>Transition vitreuse</s0>
<s5>03</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG">
<s0>Glass transition</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE">
<s0>Cristallisation</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG">
<s0>Crystallization</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE">
<s0>Traitement thermique</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG">
<s0>Heat treatments</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE">
<s0>Précipitation</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG">
<s0>Precipitation</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE">
<s0>Formation verre</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG">
<s0>Glass formation</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE">
<s0>Mesure acoustique</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG">
<s0>Acoustic measurement</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE">
<s0>Essai émission acoustique</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG">
<s0>Acoustic emission testing</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE">
<s0>Fluorescence</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG">
<s0>Fluorescence</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE">
<s0>Spectre absorption</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG">
<s0>Absorption spectra</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>Propriété optique</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG">
<s0>Optical properties</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE">
<s0>Composition chimique</s0>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG">
<s0>Chemical composition</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Matériau transparent</s0>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Transparent material</s0>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA">
<s0>Material transparente</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE">
<s0>Vitrocéramique</s0>
<s5>16</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG">
<s0>Glass ceramics</s0>
<s5>16</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE">
<s0>Oxyfluorure</s0>
<s2>NA</s2>
<s5>17</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG">
<s0>Oxyfluorides</s0>
<s2>NA</s2>
<s5>17</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE">
<s0>Verre</s0>
<s5>18</s5>
</fC03>
<fC03 i1="16" i2="3" l="ENG">
<s0>Glass</s0>
<s5>18</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE">
<s0>Pr</s0>
<s4>INC</s4>
<s5>52</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE">
<s0>Tm</s0>
<s4>INC</s4>
<s5>53</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE">
<s0>6470P</s0>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE">
<s0>7855Q</s0>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE">
<s0>Lanthanide</s0>
<s2>NC</s2>
<s5>48</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG">
<s0>Rare earths</s0>
<s2>NC</s2>
<s5>48</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE">
<s0>Actinide</s0>
<s2>NC</s2>
<s5>49</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG">
<s0>Actinides</s0>
<s2>NC</s2>
<s5>49</s5>
</fC07>
<fN21>
<s1>348</s1>
</fN21>
<fN44 i1="01">
<s1>PSI</s1>
</fN44>
<fN82>
<s1>PSI</s1>
</fN82>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>European Materials Research Society Fall Meeting. Symposium B</s1>
<s3>Warsaw POL</s3>
<s4>2003-09-15</s4>
</fA30>
</pR>
</standard>
<server>
<NO>PASCAL 04-0601458 INIST</NO>
<ET>Pr
<sup>3+</sup>
and Tm
<sup>3+</sup>
containing transparent glass ceramics in the GeO
<sub>2</sub>
-PbO-PbF
<sub>2</sub>
-LnF
<sub>3</sub>
system</ET>
<AU>KLIMESZ (B.); DOMINIAK-DZIK (G.); SOLARZ (P.); ZELECHOWER (M.); RYBA-ROMANOWSKI (W.); PASZKOWICZ (W.); PELKA (J. B.)</AU>
<AF>Physical Laboratory, Opole Technical University, ul. Ozimska 75/Opole 45-370/Pologne (1 aut.); Institute of Low Temperature and Structure Research, Polish Academy of Sciences, ul. Okólna 2/50-395 Wroclaw/Pologne (2 aut., 3 aut., 5 aut.); Department of Material Science, Silesian University of Technology, ul. Krasiñskiego 8/Katowice 40-019/Pologne (4 aut.); Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46/02-668 Warsaw/Pologne (1 aut., 2 aut.)</AF>
<DT>Publication en série; Congrès; Niveau analytique</DT>
<SO>Journal of alloys and compounds; ISSN 0925-8388; Suisse; Da. 2004; Vol. 382; Pp. 292-299; Bibl. 8 ref.</SO>
<LA>Anglais</LA>
<EA>Oxyfluoride glasses with composition 50GeO
<sub>2</sub>
-(50-x)PbO-xPbF
<sub>2</sub>
(x ≤ 15 mol%) containing praseodymium or thulium were melted from commercial raw materials in normal atmosphere. Based on the results of differential thermal analysis (DTA), glass transition temperatures and oxide glass crystallisation temperatures have been derived. Then the glass samples were thermally treated in order to achieve controlled precipitation of PbF
<sub>2</sub>
. Process of formation of glass ceramics has been monitored with the aid of the DTA and X-ray measurements. The control acoustic emission (AE) measurements confirm the DTA results. It has been found that after heat treatment the crystallisation temperatures of investigated materials have been changed due to the PbF
<sub>2</sub>
content and kind of doped ions. The influence of the kind of doped ions on the glass stability was observed. The effect of thermal treatment on the absorption spectra and kinetics of the fluorescent levels of Pr
<sup>3+</sup>
and Tm
<sup>3+</sup>
was studied. In the case of Tm
<sup>3+</sup>
doped systems it was found that this effect on the relaxation of the
<sup>1</sup>
G
<sub>4</sub>
level was weak, whereas the decay of the
<sup>3</sup>
H
<sub>4</sub>
level was slower by a factor of 3 roughly with respect to that recorded with as-melted glass. Relaxation rates of the
<sup>3</sup>
P
<sub>0</sub>
and
<sup>1</sup>
D
<sub>2</sub>
levels of Pr
<sup>3+</sup>
showed marked dependence on both the PbF
<sub>2</sub>
and Pr
<sup>3-</sup>
content in as-melted glass and in glass ceramics.</EA>
<CC>001B60D70P; 001B70H55Q</CC>
<FD>Analyse thermique différentielle; Transition vitreuse; Cristallisation; Traitement thermique; Précipitation; Formation verre; Mesure acoustique; Essai émission acoustique; Fluorescence; Spectre absorption; Propriété optique; Composition chimique; Matériau transparent; Vitrocéramique; Oxyfluorure; Verre; Pr; Tm; 6470P; 7855Q</FD>
<FG>Lanthanide; Actinide</FG>
<ED>Differential thermal analysis; Glass transition; Crystallization; Heat treatments; Precipitation; Glass formation; Acoustic measurement; Acoustic emission testing; Fluorescence; Absorption spectra; Optical properties; Chemical composition; Transparent material; Glass ceramics; Oxyfluorides; Glass</ED>
<EG>Rare earths; Actinides</EG>
<SD>Material transparente</SD>
<LO>INIST-1151.354000122631830470</LO>
<ID>04-0601458</ID>
</server>
</inist>
</record>

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