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Crystal growth and spectroscopic analysis of codoped (Ho,Tm):KGd(WO4)2

Identifieur interne : 000787 ( Pascal/Corpus ); précédent : 000786; suivant : 000788

Crystal growth and spectroscopic analysis of codoped (Ho,Tm):KGd(WO4)2

Auteurs : O. Silvestre ; M. C. Pujol ; F. Güell ; M. Aguilo ; F. Diaz ; A. Brenier ; G. Boulon

Source :

RBID : Pascal:07-0193319

Descripteurs français

English descriptors

Abstract

We present the crystal growth of monoclinic KGd(WO4)2 codoped with holmium and thulium by a top-seeded solution growth and slow cooling method. Macrodefect-free crystals with sizes about 8.5 x 5 x 12 (a* x b x c, dimensions in mm) were obtained. A complete study of the spectroscopic parameters of the holmium emission 5I75I8, around 2 microns, sensitized by the thulium ion, was made. Polarized absorption measurements were performed to characterize the optimum pumping wavelength in the system. The maximum value of the cross section is 8.0x102 cm2 with E//Np direction at a wavelength value of 794 nm. The emission cross section of the 2-micron holmium transition has been calculated by the reciprocity method. The experimental lifetime of the 5I7 level has been measured in relation to holmium and thulium concentrations.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0946-2171
A03   1    @0 Appl. phys., B Lasers opt. : (Print)
A05       @2 87
A06       @2 1
A08 01  1  ENG  @1 Crystal growth and spectroscopic analysis of codoped (Ho,Tm):KGd(WO4)2
A11 01  1    @1 SILVESTRE (O.)
A11 02  1    @1 PUJOL (M. C.)
A11 03  1    @1 GÜELL (F.)
A11 04  1    @1 AGUILO (M.)
A11 05  1    @1 DIAZ (F.)
A11 06  1    @1 BRENIER (A.)
A11 07  1    @1 BOULON (G.)
A14 01      @1 Física i Cristal-lografia de Materials (FiCMA), Universitat Rovira i Virgili, Campus Sescelades c/Marcel. lí Domingo, s/n @2 43007 Tarragona @3 ESP @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 4 aut. @Z 5 aut.
A14 02      @1 Physico Chimie des Matériaux Luminescents, Université Claude Bernard Lyon 1, UMR 5620 CNRS, Bât. A. Kastler, 10 rue Ampère @2 69622 Villeurbanne @3 FRA @Z 6 aut. @Z 7 aut.
A20       @1 111-117
A21       @1 2007
A23 01      @0 ENG
A43 01      @1 INIST @2 16194B @5 354000145692230200
A44       @0 0000 @1 © 2007 INIST-CNRS. All rights reserved.
A45       @0 49 ref.
A47 01  1    @0 07-0193319
A60       @1 P
A61       @0 A
A64 01  1    @0 Applied physics. B, Lasers and optics : (Print)
A66 01      @0 DEU
C01 01    ENG  @0 We present the crystal growth of monoclinic KGd(WO4)2 codoped with holmium and thulium by a top-seeded solution growth and slow cooling method. Macrodefect-free crystals with sizes about 8.5 x 5 x 12 (a* x b x c, dimensions in mm) were obtained. A complete study of the spectroscopic parameters of the holmium emission 5I75I8, around 2 microns, sensitized by the thulium ion, was made. Polarized absorption measurements were performed to characterize the optimum pumping wavelength in the system. The maximum value of the cross section is 8.0x102 cm2 with E//Np direction at a wavelength value of 794 nm. The emission cross section of the 2-micron holmium transition has been calculated by the reciprocity method. The experimental lifetime of the 5I7 level has been measured in relation to holmium and thulium concentrations.
C02 01  3    @0 001B80A10D
C02 02  3    @0 001B40B70H
C03 01  3  FRE  @0 Croissance cristalline en solution @5 31
C03 01  3  ENG  @0 Crystal growth from solutions @5 31
C03 02  3  FRE  @0 Durée vie @5 41
C03 02  3  ENG  @0 Lifetime @5 41
C03 03  3  FRE  @0 Spectre émission @5 42
C03 03  3  ENG  @0 Emission spectra @5 42
C03 04  X  FRE  @0 Spectre fluorescence @5 43
C03 04  X  ENG  @0 Fluorescence spectrum @5 43
C03 04  X  SPA  @0 Espectro fluorescencia @5 43
C03 05  3  FRE  @0 Matériau dopé @5 50
C03 05  3  ENG  @0 Doped materials @5 50
C03 06  3  FRE  @0 Addition thulium @5 51
C03 06  3  ENG  @0 Thulium additions @5 51
C03 07  3  FRE  @0 Potassium tungstate @2 NK @5 52
C03 07  3  ENG  @0 Potassium tungstates @2 NK @5 52
C03 08  3  FRE  @0 Gadolinium tungstate @2 NK @5 53
C03 08  3  ENG  @0 Gadolinium tungstates @2 NK @5 53
C03 09  3  FRE  @0 Composé quaternaire @5 54
C03 09  3  ENG  @0 Quaternary compounds @5 54
C03 10  3  FRE  @0 Matériau optique @5 55
C03 10  3  ENG  @0 Optical materials @5 55
C03 11  X  FRE  @0 Codopage @5 57
C03 11  X  ENG  @0 Codoping @5 57
C03 11  X  SPA  @0 Codrogado @5 57
C03 12  3  FRE  @0 Matériau laser @5 58
C03 12  3  ENG  @0 Laser materials @5 58
C03 13  3  FRE  @0 Holmium @2 NC @5 61
C03 13  3  ENG  @0 Holmium @2 NC @5 61
C03 14  3  FRE  @0 Thulium ion @2 NC @5 62
C03 14  3  ENG  @0 Thulium ions @2 NC @5 62
C03 15  3  FRE  @0 Addition holmium @5 63
C03 15  3  ENG  @0 Holmium additions @5 63
C03 16  X  FRE  @0 Cristal monoclinique @5 64
C03 16  X  ENG  @0 Monoclinic crystals @5 64
C03 16  X  SPA  @0 Cristal monoclínico @5 64
C03 17  3  FRE  @0 Tm:KGd(WO4)2 @4 INC @5 71
C03 18  3  FRE  @0 KGd(WO4)2 @4 INC @5 72
C03 19  3  FRE  @0 Gd K O W @4 INC @5 75
C03 20  3  FRE  @0 8110D @4 INC @5 83
C03 21  3  FRE  @0 4270H @4 INC @5 84
N21       @1 128

Format Inist (serveur)

NO : PASCAL 07-0193319 INIST
ET : Crystal growth and spectroscopic analysis of codoped (Ho,Tm):KGd(WO4)2
AU : SILVESTRE (O.); PUJOL (M. C.); GÜELL (F.); AGUILO (M.); DIAZ (F.); BRENIER (A.); BOULON (G.)
AF : Física i Cristal-lografia de Materials (FiCMA), Universitat Rovira i Virgili, Campus Sescelades c/Marcel. lí Domingo, s/n/43007 Tarragona/Espagne (1 aut., 2 aut., 3 aut., 4 aut., 5 aut.); Physico Chimie des Matériaux Luminescents, Université Claude Bernard Lyon 1, UMR 5620 CNRS, Bât. A. Kastler, 10 rue Ampère/69622 Villeurbanne/France (6 aut., 7 aut.)
DT : Publication en série; Niveau analytique
SO : Applied physics. B, Lasers and optics : (Print); ISSN 0946-2171; Allemagne; Da. 2007; Vol. 87; No. 1; Pp. 111-117; Bibl. 49 ref.
LA : Anglais
EA : We present the crystal growth of monoclinic KGd(WO4)2 codoped with holmium and thulium by a top-seeded solution growth and slow cooling method. Macrodefect-free crystals with sizes about 8.5 x 5 x 12 (a* x b x c, dimensions in mm) were obtained. A complete study of the spectroscopic parameters of the holmium emission 5I75I8, around 2 microns, sensitized by the thulium ion, was made. Polarized absorption measurements were performed to characterize the optimum pumping wavelength in the system. The maximum value of the cross section is 8.0x102 cm2 with E//Np direction at a wavelength value of 794 nm. The emission cross section of the 2-micron holmium transition has been calculated by the reciprocity method. The experimental lifetime of the 5I7 level has been measured in relation to holmium and thulium concentrations.
CC : 001B80A10D; 001B40B70H
FD : Croissance cristalline en solution; Durée vie; Spectre émission; Spectre fluorescence; Matériau dopé; Addition thulium; Potassium tungstate; Gadolinium tungstate; Composé quaternaire; Matériau optique; Codopage; Matériau laser; Holmium; Thulium ion; Addition holmium; Cristal monoclinique; Tm:KGd(WO4)2; KGd(WO4)2; Gd K O W; 8110D; 4270H
ED : Crystal growth from solutions; Lifetime; Emission spectra; Fluorescence spectrum; Doped materials; Thulium additions; Potassium tungstates; Gadolinium tungstates; Quaternary compounds; Optical materials; Codoping; Laser materials; Holmium; Thulium ions; Holmium additions; Monoclinic crystals
SD : Espectro fluorescencia; Codrogado; Cristal monoclínico
LO : INIST-16194B.354000145692230200
ID : 07-0193319

Links to Exploration step

Pascal:07-0193319

Le document en format XML

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<term>Codoping</term>
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<term>Doped materials</term>
<term>Emission spectra</term>
<term>Fluorescence spectrum</term>
<term>Gadolinium tungstates</term>
<term>Holmium</term>
<term>Holmium additions</term>
<term>Laser materials</term>
<term>Lifetime</term>
<term>Monoclinic crystals</term>
<term>Optical materials</term>
<term>Potassium tungstates</term>
<term>Quaternary compounds</term>
<term>Thulium additions</term>
<term>Thulium ions</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Croissance cristalline en solution</term>
<term>Durée vie</term>
<term>Spectre émission</term>
<term>Spectre fluorescence</term>
<term>Matériau dopé</term>
<term>Addition thulium</term>
<term>Potassium tungstate</term>
<term>Gadolinium tungstate</term>
<term>Composé quaternaire</term>
<term>Matériau optique</term>
<term>Codopage</term>
<term>Matériau laser</term>
<term>Holmium</term>
<term>Thulium ion</term>
<term>Addition holmium</term>
<term>Cristal monoclinique</term>
<term>Tm:KGd(WO4)2</term>
<term>KGd(WO4)2</term>
<term>Gd K O W</term>
<term>8110D</term>
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<front>
<div type="abstract" xml:lang="en">We present the crystal growth of monoclinic KGd(WO
<sub>4</sub>
)
<sub>2</sub>
codoped with holmium and thulium by a top-seeded solution growth and slow cooling method. Macrodefect-free crystals with sizes about 8.5 x 5 x 12 (a* x b x c, dimensions in mm) were obtained. A complete study of the spectroscopic parameters of the holmium emission
<sup>5</sup>
I
<sub>7</sub>
<sup>5</sup>
I
<sub>8,</sub>
around 2 microns, sensitized by the thulium ion, was made. Polarized absorption measurements were performed to characterize the optimum pumping wavelength in the system. The maximum value of the cross section is 8.0x10
<sup>2</sup>
cm
<sup>2</sup>
with E//Np direction at a wavelength value of 794 nm. The emission cross section of the 2-micron holmium transition has been calculated by the reciprocity method. The experimental lifetime of the
<sup>5</sup>
I
<sub>7</sub>
level has been measured in relation to holmium and thulium concentrations.</div>
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<s3>ESP</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
</fA14>
<fA14 i1="02">
<s1>Physico Chimie des Matériaux Luminescents, Université Claude Bernard Lyon 1, UMR 5620 CNRS, Bât. A. Kastler, 10 rue Ampère</s1>
<s2>69622 Villeurbanne</s2>
<s3>FRA</s3>
<sZ>6 aut.</sZ>
<sZ>7 aut.</sZ>
</fA14>
<fA20>
<s1>111-117</s1>
</fA20>
<fA21>
<s1>2007</s1>
</fA21>
<fA23 i1="01">
<s0>ENG</s0>
</fA23>
<fA43 i1="01">
<s1>INIST</s1>
<s2>16194B</s2>
<s5>354000145692230200</s5>
</fA43>
<fA44>
<s0>0000</s0>
<s1>© 2007 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45>
<s0>49 ref.</s0>
</fA45>
<fA47 i1="01" i2="1">
<s0>07-0193319</s0>
</fA47>
<fA60>
<s1>P</s1>
</fA60>
<fA61>
<s0>A</s0>
</fA61>
<fA64 i1="01" i2="1">
<s0>Applied physics. B, Lasers and optics : (Print)</s0>
</fA64>
<fA66 i1="01">
<s0>DEU</s0>
</fA66>
<fC01 i1="01" l="ENG">
<s0>We present the crystal growth of monoclinic KGd(WO
<sub>4</sub>
)
<sub>2</sub>
codoped with holmium and thulium by a top-seeded solution growth and slow cooling method. Macrodefect-free crystals with sizes about 8.5 x 5 x 12 (a* x b x c, dimensions in mm) were obtained. A complete study of the spectroscopic parameters of the holmium emission
<sup>5</sup>
I
<sub>7</sub>
<sup>5</sup>
I
<sub>8,</sub>
around 2 microns, sensitized by the thulium ion, was made. Polarized absorption measurements were performed to characterize the optimum pumping wavelength in the system. The maximum value of the cross section is 8.0x10
<sup>2</sup>
cm
<sup>2</sup>
with E//Np direction at a wavelength value of 794 nm. The emission cross section of the 2-micron holmium transition has been calculated by the reciprocity method. The experimental lifetime of the
<sup>5</sup>
I
<sub>7</sub>
level has been measured in relation to holmium and thulium concentrations.</s0>
</fC01>
<fC02 i1="01" i2="3">
<s0>001B80A10D</s0>
</fC02>
<fC02 i1="02" i2="3">
<s0>001B40B70H</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE">
<s0>Croissance cristalline en solution</s0>
<s5>31</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG">
<s0>Crystal growth from solutions</s0>
<s5>31</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE">
<s0>Durée vie</s0>
<s5>41</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG">
<s0>Lifetime</s0>
<s5>41</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE">
<s0>Spectre émission</s0>
<s5>42</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG">
<s0>Emission spectra</s0>
<s5>42</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE">
<s0>Spectre fluorescence</s0>
<s5>43</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG">
<s0>Fluorescence spectrum</s0>
<s5>43</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA">
<s0>Espectro fluorescencia</s0>
<s5>43</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE">
<s0>Matériau dopé</s0>
<s5>50</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG">
<s0>Doped materials</s0>
<s5>50</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE">
<s0>Addition thulium</s0>
<s5>51</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG">
<s0>Thulium additions</s0>
<s5>51</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE">
<s0>Potassium tungstate</s0>
<s2>NK</s2>
<s5>52</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG">
<s0>Potassium tungstates</s0>
<s2>NK</s2>
<s5>52</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE">
<s0>Gadolinium tungstate</s0>
<s2>NK</s2>
<s5>53</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG">
<s0>Gadolinium tungstates</s0>
<s2>NK</s2>
<s5>53</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE">
<s0>Composé quaternaire</s0>
<s5>54</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG">
<s0>Quaternary compounds</s0>
<s5>54</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE">
<s0>Matériau optique</s0>
<s5>55</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG">
<s0>Optical materials</s0>
<s5>55</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Codopage</s0>
<s5>57</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Codoping</s0>
<s5>57</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Codrogado</s0>
<s5>57</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE">
<s0>Matériau laser</s0>
<s5>58</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG">
<s0>Laser materials</s0>
<s5>58</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>Holmium</s0>
<s2>NC</s2>
<s5>61</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG">
<s0>Holmium</s0>
<s2>NC</s2>
<s5>61</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE">
<s0>Thulium ion</s0>
<s2>NC</s2>
<s5>62</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG">
<s0>Thulium ions</s0>
<s2>NC</s2>
<s5>62</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE">
<s0>Addition holmium</s0>
<s5>63</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG">
<s0>Holmium additions</s0>
<s5>63</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Cristal monoclinique</s0>
<s5>64</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG">
<s0>Monoclinic crystals</s0>
<s5>64</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA">
<s0>Cristal monoclínico</s0>
<s5>64</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE">
<s0>Tm:KGd(WO4)2</s0>
<s4>INC</s4>
<s5>71</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE">
<s0>KGd(WO4)2</s0>
<s4>INC</s4>
<s5>72</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE">
<s0>Gd K O W</s0>
<s4>INC</s4>
<s5>75</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE">
<s0>8110D</s0>
<s4>INC</s4>
<s5>83</s5>
</fC03>
<fC03 i1="21" i2="3" l="FRE">
<s0>4270H</s0>
<s4>INC</s4>
<s5>84</s5>
</fC03>
<fN21>
<s1>128</s1>
</fN21>
</pA>
</standard>
<server>
<NO>PASCAL 07-0193319 INIST</NO>
<ET>Crystal growth and spectroscopic analysis of codoped (Ho,Tm):KGd(WO
<sub>4</sub>
)
<sub>2</sub>
</ET>
<AU>SILVESTRE (O.); PUJOL (M. C.); GÜELL (F.); AGUILO (M.); DIAZ (F.); BRENIER (A.); BOULON (G.)</AU>
<AF>Física i Cristal-lografia de Materials (FiCMA), Universitat Rovira i Virgili, Campus Sescelades c/Marcel. lí Domingo, s/n/43007 Tarragona/Espagne (1 aut., 2 aut., 3 aut., 4 aut., 5 aut.); Physico Chimie des Matériaux Luminescents, Université Claude Bernard Lyon 1, UMR 5620 CNRS, Bât. A. Kastler, 10 rue Ampère/69622 Villeurbanne/France (6 aut., 7 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Applied physics. B, Lasers and optics : (Print); ISSN 0946-2171; Allemagne; Da. 2007; Vol. 87; No. 1; Pp. 111-117; Bibl. 49 ref.</SO>
<LA>Anglais</LA>
<EA>We present the crystal growth of monoclinic KGd(WO
<sub>4</sub>
)
<sub>2</sub>
codoped with holmium and thulium by a top-seeded solution growth and slow cooling method. Macrodefect-free crystals with sizes about 8.5 x 5 x 12 (a* x b x c, dimensions in mm) were obtained. A complete study of the spectroscopic parameters of the holmium emission
<sup>5</sup>
I
<sub>7</sub>
<sup>5</sup>
I
<sub>8,</sub>
around 2 microns, sensitized by the thulium ion, was made. Polarized absorption measurements were performed to characterize the optimum pumping wavelength in the system. The maximum value of the cross section is 8.0x10
<sup>2</sup>
cm
<sup>2</sup>
with E//Np direction at a wavelength value of 794 nm. The emission cross section of the 2-micron holmium transition has been calculated by the reciprocity method. The experimental lifetime of the
<sup>5</sup>
I
<sub>7</sub>
level has been measured in relation to holmium and thulium concentrations.</EA>
<CC>001B80A10D; 001B40B70H</CC>
<FD>Croissance cristalline en solution; Durée vie; Spectre émission; Spectre fluorescence; Matériau dopé; Addition thulium; Potassium tungstate; Gadolinium tungstate; Composé quaternaire; Matériau optique; Codopage; Matériau laser; Holmium; Thulium ion; Addition holmium; Cristal monoclinique; Tm:KGd(WO4)2; KGd(WO4)2; Gd K O W; 8110D; 4270H</FD>
<ED>Crystal growth from solutions; Lifetime; Emission spectra; Fluorescence spectrum; Doped materials; Thulium additions; Potassium tungstates; Gadolinium tungstates; Quaternary compounds; Optical materials; Codoping; Laser materials; Holmium; Thulium ions; Holmium additions; Monoclinic crystals</ED>
<SD>Espectro fluorescencia; Codrogado; Cristal monoclínico</SD>
<LO>INIST-16194B.354000145692230200</LO>
<ID>07-0193319</ID>
</server>
</inist>
</record>

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