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Up-conversion in nanostructured Yb3+-Tm3+co-doped sol-gel derived SiO2-LaF3 transparent glass-ceramics

Identifieur interne : 000683 ( Pascal/Corpus ); précédent : 000682; suivant : 000684

Up-conversion in nanostructured Yb3+-Tm3+co-doped sol-gel derived SiO2-LaF3 transparent glass-ceramics

Auteurs : J. Mendez-Ramos ; J. J. Velazquez ; A. C. Yanes ; J. Del-Castillo ; V. D. Rodriguez

Source :

RBID : Pascal:08-0144517

Descripteurs français

English descriptors

Abstract

Nanostructured transparent glass-ceramics with composition of 95SiO2-5LaF3 doped with 0.1 mol% of Tm3+ or co-doped with 0.1 mol% of Tm3+ and 0.3 mol% of Yb3+ were synthesized by thermal treatment of precursor sol-gel denved glasses. A comparative luminescence analysis in terms of different temperatures of thermal treatments has been carried out. Segregation of LaF3 nanocrystals in matrix was confirmed by X-ray diffraction. Blue and red efficient up-conversion emissions were observed under 980 nm excitation at room temperature. These resuits indicate partition of a significant fraction of co-dopants into the precipitated LaF3 nanocrystals. The mechanisms involved in the up-conversion emissions have been analyzed and can be ascribed to processes with two, three and four photons.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 1862-6300
A03   1    @0 Phys. status solidi, A Appl. mater. sci. : (Print)
A05       @2 205
A06       @2 2
A08 01  1  ENG  @1 Up-conversion in nanostructured Yb3+-Tm3+co-doped sol-gel derived SiO2-LaF3 transparent glass-ceramics
A11 01  1    @1 MENDEZ-RAMOS (J.)
A11 02  1    @1 VELAZQUEZ (J. J.)
A11 03  1    @1 YANES (A. C.)
A11 04  1    @1 DEL-CASTILLO (J.)
A11 05  1    @1 RODRIGUEZ (V. D.)
A14 01      @1 Departamento de Física Fundamental y Experimental, Electrónica y Sistemas, Universidad de La Laguna @2 38206 La Laguna, Tenerife @3 ESP @Z 1 aut. @Z 2 aut. @Z 5 aut.
A14 02      @1 Departamento de Física Bâsica, Universidad de La Laguna @2 38206 La Laguna, Tenerife @3 ESP @Z 3 aut. @Z 4 aut.
A20       @1 330-334
A21       @1 2008
A23 01      @0 ENG
A43 01      @1 INIST @2 10183A @5 354000175038490190
A44       @0 0000 @1 © 2008 INIST-CNRS. All rights reserved.
A45       @0 20 ref.
A47 01  1    @0 08-0144517
A60       @1 P
A61       @0 A
A64 01  1    @0 Physica status solidi. A, Applications and materials science : (Print)
A66 01      @0 DEU
C01 01    ENG  @0 Nanostructured transparent glass-ceramics with composition of 95SiO2-5LaF3 doped with 0.1 mol% of Tm3+ or co-doped with 0.1 mol% of Tm3+ and 0.3 mol% of Yb3+ were synthesized by thermal treatment of precursor sol-gel denved glasses. A comparative luminescence analysis in terms of different temperatures of thermal treatments has been carried out. Segregation of LaF3 nanocrystals in matrix was confirmed by X-ray diffraction. Blue and red efficient up-conversion emissions were observed under 980 nm excitation at room temperature. These resuits indicate partition of a significant fraction of co-dopants into the precipitated LaF3 nanocrystals. The mechanisms involved in the up-conversion emissions have been analyzed and can be ascribed to processes with two, three and four photons.
C02 01  3    @0 001B70H55Q
C03 01  X  FRE  @0 Conversion fréquence @5 02
C03 01  X  ENG  @0 Frequency conversion @5 02
C03 01  X  SPA  @0 Conversión frecuencia @5 02
C03 02  3  FRE  @0 Photoluminescence @5 03
C03 02  3  ENG  @0 Photoluminescence @5 03
C03 03  3  FRE  @0 Procédé sol gel @5 04
C03 03  3  ENG  @0 Sol-gel process @5 04
C03 04  3  FRE  @0 Addition thulium @5 05
C03 04  3  ENG  @0 Thulium additions @5 05
C03 05  3  FRE  @0 Traitement thermique @5 06
C03 05  3  ENG  @0 Heat treatments @5 06
C03 06  3  FRE  @0 Addition ytterbium @5 07
C03 06  3  ENG  @0 Ytterbium additions @5 07
C03 07  3  FRE  @0 Ségrégation @5 08
C03 07  3  ENG  @0 Segregation @5 08
C03 08  3  FRE  @0 Diffraction RX @5 09
C03 08  3  ENG  @0 XRD @5 09
C03 09  X  FRE  @0 Codopage @5 10
C03 09  X  ENG  @0 Codoping @5 10
C03 09  X  SPA  @0 Codrogado @5 10
C03 10  3  FRE  @0 Précipitation @5 11
C03 10  3  ENG  @0 Precipitation @5 11
C03 11  3  FRE  @0 Nanostructure @5 15
C03 11  3  ENG  @0 Nanostructures @5 15
C03 12  3  FRE  @0 Silice @2 NK @5 16
C03 12  3  ENG  @0 Silica @2 NK @5 16
C03 13  X  FRE  @0 Fluorure de lanthane @5 17
C03 13  X  ENG  @0 Lanthanum fluoride @5 17
C03 13  X  SPA  @0 Lantano fluoruro @5 17
C03 14  3  FRE  @0 Vitrocéramique @5 18
C03 14  3  ENG  @0 Glass ceramics @5 18
C03 15  3  FRE  @0 Verre @5 19
C03 15  3  ENG  @0 Glass @5 19
C03 16  X  FRE  @0 Nanocristal @5 20
C03 16  X  ENG  @0 Nanocrystal @5 20
C03 16  X  SPA  @0 Nanocristal @5 20
C03 17  3  FRE  @0 Système binaire @5 21
C03 17  3  ENG  @0 Binary systems @5 21
C03 18  3  FRE  @0 Composé minéral @5 48
C03 18  3  ENG  @0 Inorganic compounds @5 48
C03 19  3  FRE  @0 Système SiO2 LaF3 @4 INC @5 63
N21       @1 084

Format Inist (serveur)

NO : PASCAL 08-0144517 INIST
ET : Up-conversion in nanostructured Yb3+-Tm3+co-doped sol-gel derived SiO2-LaF3 transparent glass-ceramics
AU : MENDEZ-RAMOS (J.); VELAZQUEZ (J. J.); YANES (A. C.); DEL-CASTILLO (J.); RODRIGUEZ (V. D.)
AF : Departamento de Física Fundamental y Experimental, Electrónica y Sistemas, Universidad de La Laguna/38206 La Laguna, Tenerife/Espagne (1 aut., 2 aut., 5 aut.); Departamento de Física Bâsica, Universidad de La Laguna/38206 La Laguna, Tenerife/Espagne (3 aut., 4 aut.)
DT : Publication en série; Niveau analytique
SO : Physica status solidi. A, Applications and materials science : (Print); ISSN 1862-6300; Allemagne; Da. 2008; Vol. 205; No. 2; Pp. 330-334; Bibl. 20 ref.
LA : Anglais
EA : Nanostructured transparent glass-ceramics with composition of 95SiO2-5LaF3 doped with 0.1 mol% of Tm3+ or co-doped with 0.1 mol% of Tm3+ and 0.3 mol% of Yb3+ were synthesized by thermal treatment of precursor sol-gel denved glasses. A comparative luminescence analysis in terms of different temperatures of thermal treatments has been carried out. Segregation of LaF3 nanocrystals in matrix was confirmed by X-ray diffraction. Blue and red efficient up-conversion emissions were observed under 980 nm excitation at room temperature. These resuits indicate partition of a significant fraction of co-dopants into the precipitated LaF3 nanocrystals. The mechanisms involved in the up-conversion emissions have been analyzed and can be ascribed to processes with two, three and four photons.
CC : 001B70H55Q
FD : Conversion fréquence; Photoluminescence; Procédé sol gel; Addition thulium; Traitement thermique; Addition ytterbium; Ségrégation; Diffraction RX; Codopage; Précipitation; Nanostructure; Silice; Fluorure de lanthane; Vitrocéramique; Verre; Nanocristal; Système binaire; Composé minéral; Système SiO2 LaF3
ED : Frequency conversion; Photoluminescence; Sol-gel process; Thulium additions; Heat treatments; Ytterbium additions; Segregation; XRD; Codoping; Precipitation; Nanostructures; Silica; Lanthanum fluoride; Glass ceramics; Glass; Nanocrystal; Binary systems; Inorganic compounds
SD : Conversión frecuencia; Codrogado; Lantano fluoruro; Nanocristal
LO : INIST-10183A.354000175038490190
ID : 08-0144517

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Pascal:08-0144517

Le document en format XML

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transparent glass-ceramics</title>
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co-doped sol-gel derived SiO
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<term>Heat treatments</term>
<term>Inorganic compounds</term>
<term>Lanthanum fluoride</term>
<term>Nanocrystal</term>
<term>Nanostructures</term>
<term>Photoluminescence</term>
<term>Precipitation</term>
<term>Segregation</term>
<term>Silica</term>
<term>Sol-gel process</term>
<term>Thulium additions</term>
<term>XRD</term>
<term>Ytterbium additions</term>
</keywords>
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<term>Conversion fréquence</term>
<term>Photoluminescence</term>
<term>Procédé sol gel</term>
<term>Addition thulium</term>
<term>Traitement thermique</term>
<term>Addition ytterbium</term>
<term>Ségrégation</term>
<term>Diffraction RX</term>
<term>Codopage</term>
<term>Précipitation</term>
<term>Nanostructure</term>
<term>Silice</term>
<term>Fluorure de lanthane</term>
<term>Vitrocéramique</term>
<term>Verre</term>
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<front>
<div type="abstract" xml:lang="en">Nanostructured transparent glass-ceramics with composition of 95SiO
<sub>2</sub>
-5LaF
<sub>3</sub>
doped with 0.1 mol% of Tm
<sup>3+</sup>
or co-doped with 0.1 mol% of Tm
<sup>3+</sup>
and 0.3 mol% of Yb
<sup>3+</sup>
were synthesized by thermal treatment of precursor sol-gel denved glasses. A comparative luminescence analysis in terms of different temperatures of thermal treatments has been carried out. Segregation of LaF
<sub>3</sub>
nanocrystals in matrix was confirmed by X-ray diffraction. Blue and red efficient up-conversion emissions were observed under 980 nm excitation at room temperature. These resuits indicate partition of a significant fraction of co-dopants into the precipitated LaF
<sub>3</sub>
nanocrystals. The mechanisms involved in the up-conversion emissions have been analyzed and can be ascribed to processes with two, three and four photons.</div>
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<s1>Up-conversion in nanostructured Yb
<sup>3+</sup>
-Tm
<sup>3+</sup>
co-doped sol-gel derived SiO
<sub>2</sub>
-LaF
<sub>3</sub>
transparent glass-ceramics</s1>
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<s0>DEU</s0>
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<fC01 i1="01" l="ENG">
<s0>Nanostructured transparent glass-ceramics with composition of 95SiO
<sub>2</sub>
-5LaF
<sub>3</sub>
doped with 0.1 mol% of Tm
<sup>3+</sup>
or co-doped with 0.1 mol% of Tm
<sup>3+</sup>
and 0.3 mol% of Yb
<sup>3+</sup>
were synthesized by thermal treatment of precursor sol-gel denved glasses. A comparative luminescence analysis in terms of different temperatures of thermal treatments has been carried out. Segregation of LaF
<sub>3</sub>
nanocrystals in matrix was confirmed by X-ray diffraction. Blue and red efficient up-conversion emissions were observed under 980 nm excitation at room temperature. These resuits indicate partition of a significant fraction of co-dopants into the precipitated LaF
<sub>3</sub>
nanocrystals. The mechanisms involved in the up-conversion emissions have been analyzed and can be ascribed to processes with two, three and four photons.</s0>
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<s0>001B70H55Q</s0>
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<s0>Conversion fréquence</s0>
<s5>02</s5>
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<fC03 i1="01" i2="X" l="ENG">
<s0>Frequency conversion</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA">
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<s5>02</s5>
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<fC03 i1="02" i2="3" l="FRE">
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<s5>03</s5>
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<s5>03</s5>
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<s0>Procédé sol gel</s0>
<s5>04</s5>
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<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE">
<s0>Addition thulium</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG">
<s0>Thulium additions</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE">
<s0>Traitement thermique</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG">
<s0>Heat treatments</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE">
<s0>Addition ytterbium</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG">
<s0>Ytterbium additions</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE">
<s0>Ségrégation</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG">
<s0>Segregation</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE">
<s0>Diffraction RX</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG">
<s0>XRD</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Codopage</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>Codoping</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Codrogado</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE">
<s0>Précipitation</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG">
<s0>Precipitation</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>Nanostructure</s0>
<s5>15</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG">
<s0>Nanostructures</s0>
<s5>15</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE">
<s0>Silice</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG">
<s0>Silica</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Fluorure de lanthane</s0>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Lanthanum fluoride</s0>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA">
<s0>Lantano fluoruro</s0>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE">
<s0>Vitrocéramique</s0>
<s5>18</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG">
<s0>Glass ceramics</s0>
<s5>18</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE">
<s0>Verre</s0>
<s5>19</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG">
<s0>Glass</s0>
<s5>19</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Nanocristal</s0>
<s5>20</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG">
<s0>Nanocrystal</s0>
<s5>20</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA">
<s0>Nanocristal</s0>
<s5>20</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE">
<s0>Système binaire</s0>
<s5>21</s5>
</fC03>
<fC03 i1="17" i2="3" l="ENG">
<s0>Binary systems</s0>
<s5>21</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE">
<s0>Composé minéral</s0>
<s5>48</s5>
</fC03>
<fC03 i1="18" i2="3" l="ENG">
<s0>Inorganic compounds</s0>
<s5>48</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE">
<s0>Système SiO2 LaF3</s0>
<s4>INC</s4>
<s5>63</s5>
</fC03>
<fN21>
<s1>084</s1>
</fN21>
</pA>
</standard>
<server>
<NO>PASCAL 08-0144517 INIST</NO>
<ET>Up-conversion in nanostructured Yb
<sup>3+</sup>
-Tm
<sup>3+</sup>
co-doped sol-gel derived SiO
<sub>2</sub>
-LaF
<sub>3</sub>
transparent glass-ceramics</ET>
<AU>MENDEZ-RAMOS (J.); VELAZQUEZ (J. J.); YANES (A. C.); DEL-CASTILLO (J.); RODRIGUEZ (V. D.)</AU>
<AF>Departamento de Física Fundamental y Experimental, Electrónica y Sistemas, Universidad de La Laguna/38206 La Laguna, Tenerife/Espagne (1 aut., 2 aut., 5 aut.); Departamento de Física Bâsica, Universidad de La Laguna/38206 La Laguna, Tenerife/Espagne (3 aut., 4 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Physica status solidi. A, Applications and materials science : (Print); ISSN 1862-6300; Allemagne; Da. 2008; Vol. 205; No. 2; Pp. 330-334; Bibl. 20 ref.</SO>
<LA>Anglais</LA>
<EA>Nanostructured transparent glass-ceramics with composition of 95SiO
<sub>2</sub>
-5LaF
<sub>3</sub>
doped with 0.1 mol% of Tm
<sup>3+</sup>
or co-doped with 0.1 mol% of Tm
<sup>3+</sup>
and 0.3 mol% of Yb
<sup>3+</sup>
were synthesized by thermal treatment of precursor sol-gel denved glasses. A comparative luminescence analysis in terms of different temperatures of thermal treatments has been carried out. Segregation of LaF
<sub>3</sub>
nanocrystals in matrix was confirmed by X-ray diffraction. Blue and red efficient up-conversion emissions were observed under 980 nm excitation at room temperature. These resuits indicate partition of a significant fraction of co-dopants into the precipitated LaF
<sub>3</sub>
nanocrystals. The mechanisms involved in the up-conversion emissions have been analyzed and can be ascribed to processes with two, three and four photons.</EA>
<CC>001B70H55Q</CC>
<FD>Conversion fréquence; Photoluminescence; Procédé sol gel; Addition thulium; Traitement thermique; Addition ytterbium; Ségrégation; Diffraction RX; Codopage; Précipitation; Nanostructure; Silice; Fluorure de lanthane; Vitrocéramique; Verre; Nanocristal; Système binaire; Composé minéral; Système SiO2 LaF3</FD>
<ED>Frequency conversion; Photoluminescence; Sol-gel process; Thulium additions; Heat treatments; Ytterbium additions; Segregation; XRD; Codoping; Precipitation; Nanostructures; Silica; Lanthanum fluoride; Glass ceramics; Glass; Nanocrystal; Binary systems; Inorganic compounds</ED>
<SD>Conversión frecuencia; Codrogado; Lantano fluoruro; Nanocristal</SD>
<LO>INIST-10183A.354000175038490190</LO>
<ID>08-0144517</ID>
</server>
</inist>
</record>

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