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Spectroscopic investigations of OH-influence on near-infrared fluorescence quenching of Yb3+/Tm3+ co-doped sodium-metaphosphate glasses

Identifieur interne : 000660 ( Pascal/Corpus ); précédent : 000659; suivant : 000661

Spectroscopic investigations of OH-influence on near-infrared fluorescence quenching of Yb3+/Tm3+ co-doped sodium-metaphosphate glasses

Auteurs : I. A. A. Terra ; A. S. S. De Camargo ; M. C. Terrile ; L. A. O. Nunes

Source :

RBID : Pascal:08-0285205

Descripteurs français

English descriptors

Abstract

Energy transfer processes were studied in two sets of Yb3+ and Tm3+ co-doped sodium-metaphosphate glasses, prepared in air and nitrogen atmospheres. Using Förster, Dexter, and Miyakawa theoretical models, the energy transfer parameters were calculated. The main ion-ion energy transfer processes analyzed were energy migration among Yb3+ ions, cross-relaxations between Yb3+ and Tm3+ ions, and interactions with OH- radicals. The results indicated that Yb→Tm energy transfer favors 1.8 μm emissions, and there is no evidence of concentration quenching up to 2% Tm2O3 doping. As expected, samples prepared in nitrogen atmosphere present higher fluorescence quantum efficiency than those prepared in air, and this feature is specially noted in the near-infrared region, where the interaction with the OH- radicals is more pronounced.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0022-2313
A02 01      @0 JLUMA8
A03   1    @0 J. lumin.
A05       @2 128
A06       @2 5-6
A08 01  1  ENG  @1 Spectroscopic investigations of OH-influence on near-infrared fluorescence quenching of Yb3+/Tm3+ co-doped sodium-metaphosphate glasses
A09 01  1  ENG  @1 Proceesings of th 16th International Conference on Dynamical processes in Excited States of Solids
A11 01  1    @1 TERRA (I. A. A.)
A11 02  1    @1 DE CAMARGO (A. S. S.)
A11 03  1    @1 TERRILE (M. C.)
A11 04  1    @1 NUNES (L. A. O.)
A12 01  1    @1 GARCIA-SOLE (José) @9 ed.
A12 02  1    @1 DE ANDRES (Alicia) @9 ed.
A12 03  1    @1 BAUSA (Luisa) @9 ed.
A14 01      @1 Instituto de Fisica de São Carlos, Universidade de São Paulo, Av. Trabalhador Sãocarlense 400 @2 CEP 13566-590, USP-São Carlos, SP @3 BRA @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 4 aut.
A15 01      @1 Departamento de Física de Materiales, Universidad Autónoma de Madrid @2 28049 Madrid @3 ESP @Z 1 aut. @Z 2 aut.
A15 02      @1 Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Cientificas @2 28049 Madrid @3 ESP @Z 3 aut.
A20       @1 891-893
A21       @1 2008
A23 01      @0 ENG
A43 01      @1 INIST @2 14666 @5 354000172659770580
A44       @0 0000 @1 © 2008 INIST-CNRS. All rights reserved.
A45       @0 6 ref.
A47 01  1    @0 08-0285205
A60       @1 P @2 C
A61       @0 A
A64 01  1    @0 Journal of luminescence
A66 01      @0 NLD
C01 01    ENG  @0 Energy transfer processes were studied in two sets of Yb3+ and Tm3+ co-doped sodium-metaphosphate glasses, prepared in air and nitrogen atmospheres. Using Förster, Dexter, and Miyakawa theoretical models, the energy transfer parameters were calculated. The main ion-ion energy transfer processes analyzed were energy migration among Yb3+ ions, cross-relaxations between Yb3+ and Tm3+ ions, and interactions with OH- radicals. The results indicated that Yb→Tm energy transfer favors 1.8 μm emissions, and there is no evidence of concentration quenching up to 2% Tm2O3 doping. As expected, samples prepared in nitrogen atmosphere present higher fluorescence quantum efficiency than those prepared in air, and this feature is specially noted in the near-infrared region, where the interaction with the OH- radicals is more pronounced.
C02 01  3    @0 001B70H55Q
C03 01  3  FRE  @0 Rayonnement IR proche @5 02
C03 01  3  ENG  @0 Near infrared radiation @5 02
C03 02  X  FRE  @0 Extinction luminescence @5 03
C03 02  X  ENG  @0 Luminescence quenching @5 03
C03 02  X  SPA  @0 Extinción luminiscencia @5 03
C03 03  X  FRE  @0 Codopage @5 04
C03 03  X  ENG  @0 Codoping @5 04
C03 03  X  SPA  @0 Codrogado @5 04
C03 04  3  FRE  @0 Transfert énergie @5 05
C03 04  3  ENG  @0 Energy transfer @5 05
C03 05  3  FRE  @0 Addition ytterbium @5 06
C03 05  3  ENG  @0 Ytterbium additions @5 06
C03 06  X  FRE  @0 Relaxation croisée @5 07
C03 06  X  ENG  @0 Cross relaxation @5 07
C03 06  X  SPA  @0 Relajación cruzada @5 07
C03 07  3  FRE  @0 Addition thulium @5 08
C03 07  3  ENG  @0 Thulium additions @5 08
C03 08  3  FRE  @0 Fluorescence @5 10
C03 08  3  ENG  @0 Fluorescence @5 10
C03 09  3  FRE  @0 Rendement quantique @5 11
C03 09  3  ENG  @0 Quantum yield @5 11
C03 10  3  FRE  @0 Verre phosphate @5 16
C03 10  3  ENG  @0 Phosphate glass @5 16
N21       @1 182
pR  
A30 01  1  ENG  @1 International Conference on Dynamical processes in Excited States of Solids, DPC 07 @2 16 @3 Segovia ESP @4 2007-06-17

Format Inist (serveur)

NO : PASCAL 08-0285205 INIST
ET : Spectroscopic investigations of OH-influence on near-infrared fluorescence quenching of Yb3+/Tm3+ co-doped sodium-metaphosphate glasses
AU : TERRA (I. A. A.); DE CAMARGO (A. S. S.); TERRILE (M. C.); NUNES (L. A. O.); GARCIA-SOLE (José); DE ANDRES (Alicia); BAUSA (Luisa)
AF : Instituto de Fisica de São Carlos, Universidade de São Paulo, Av. Trabalhador Sãocarlense 400/CEP 13566-590, USP-São Carlos, SP/Brésil (1 aut., 2 aut., 3 aut., 4 aut.); Departamento de Física de Materiales, Universidad Autónoma de Madrid/28049 Madrid/Espagne (1 aut., 2 aut.); Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Cientificas/28049 Madrid/Espagne (3 aut.)
DT : Publication en série; Congrès; Niveau analytique
SO : Journal of luminescence; ISSN 0022-2313; Coden JLUMA8; Pays-Bas; Da. 2008; Vol. 128; No. 5-6; Pp. 891-893; Bibl. 6 ref.
LA : Anglais
EA : Energy transfer processes were studied in two sets of Yb3+ and Tm3+ co-doped sodium-metaphosphate glasses, prepared in air and nitrogen atmospheres. Using Förster, Dexter, and Miyakawa theoretical models, the energy transfer parameters were calculated. The main ion-ion energy transfer processes analyzed were energy migration among Yb3+ ions, cross-relaxations between Yb3+ and Tm3+ ions, and interactions with OH- radicals. The results indicated that Yb→Tm energy transfer favors 1.8 μm emissions, and there is no evidence of concentration quenching up to 2% Tm2O3 doping. As expected, samples prepared in nitrogen atmosphere present higher fluorescence quantum efficiency than those prepared in air, and this feature is specially noted in the near-infrared region, where the interaction with the OH- radicals is more pronounced.
CC : 001B70H55Q
FD : Rayonnement IR proche; Extinction luminescence; Codopage; Transfert énergie; Addition ytterbium; Relaxation croisée; Addition thulium; Fluorescence; Rendement quantique; Verre phosphate
ED : Near infrared radiation; Luminescence quenching; Codoping; Energy transfer; Ytterbium additions; Cross relaxation; Thulium additions; Fluorescence; Quantum yield; Phosphate glass
SD : Extinción luminiscencia; Codrogado; Relajación cruzada
LO : INIST-14666.354000172659770580
ID : 08-0285205

Links to Exploration step

Pascal:08-0285205

Le document en format XML

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<title xml:lang="en" level="a">Spectroscopic investigations of OH
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co-doped sodium-metaphosphate glasses</title>
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co-doped sodium-metaphosphate glasses</title>
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<term>Near infrared radiation</term>
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<term>Quantum yield</term>
<term>Thulium additions</term>
<term>Ytterbium additions</term>
</keywords>
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<term>Rayonnement IR proche</term>
<term>Extinction luminescence</term>
<term>Codopage</term>
<term>Transfert énergie</term>
<term>Addition ytterbium</term>
<term>Relaxation croisée</term>
<term>Addition thulium</term>
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<div type="abstract" xml:lang="en">Energy transfer processes were studied in two sets of Yb
<sup>3+</sup>
and Tm
<sup>3+</sup>
co-doped sodium-metaphosphate glasses, prepared in air and nitrogen atmospheres. Using Förster, Dexter, and Miyakawa theoretical models, the energy transfer parameters were calculated. The main ion-ion energy transfer processes analyzed were energy migration among Yb
<sup>3+</sup>
ions, cross-relaxations between Yb
<sup>3+</sup>
and Tm
<sup>3+</sup>
ions, and interactions with OH
<sup>-</sup>
radicals. The results indicated that Yb→Tm energy transfer favors 1.8 μm emissions, and there is no evidence of concentration quenching up to 2% Tm
<sub>2</sub>
O
<sub>3</sub>
doping. As expected, samples prepared in nitrogen atmosphere present higher fluorescence quantum efficiency than those prepared in air, and this feature is specially noted in the near-infrared region, where the interaction with the OH
<sup>-</sup>
radicals is more pronounced.</div>
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<s1>Spectroscopic investigations of OH
<sup>-</sup>
influence on near-infrared fluorescence quenching of Yb
<sup>3+</sup>
/Tm
<sup>3+</sup>
co-doped sodium-metaphosphate glasses</s1>
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<s0>08-0285205</s0>
</fA47>
<fA60>
<s1>P</s1>
<s2>C</s2>
</fA60>
<fA61>
<s0>A</s0>
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<s0>Journal of luminescence</s0>
</fA64>
<fA66 i1="01">
<s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG">
<s0>Energy transfer processes were studied in two sets of Yb
<sup>3+</sup>
and Tm
<sup>3+</sup>
co-doped sodium-metaphosphate glasses, prepared in air and nitrogen atmospheres. Using Förster, Dexter, and Miyakawa theoretical models, the energy transfer parameters were calculated. The main ion-ion energy transfer processes analyzed were energy migration among Yb
<sup>3+</sup>
ions, cross-relaxations between Yb
<sup>3+</sup>
and Tm
<sup>3+</sup>
ions, and interactions with OH
<sup>-</sup>
radicals. The results indicated that Yb→Tm energy transfer favors 1.8 μm emissions, and there is no evidence of concentration quenching up to 2% Tm
<sub>2</sub>
O
<sub>3</sub>
doping. As expected, samples prepared in nitrogen atmosphere present higher fluorescence quantum efficiency than those prepared in air, and this feature is specially noted in the near-infrared region, where the interaction with the OH
<sup>-</sup>
radicals is more pronounced.</s0>
</fC01>
<fC02 i1="01" i2="3">
<s0>001B70H55Q</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE">
<s0>Rayonnement IR proche</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG">
<s0>Near infrared radiation</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE">
<s0>Extinction luminescence</s0>
<s5>03</s5>
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<fC03 i1="02" i2="X" l="ENG">
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<s5>03</s5>
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<fC03 i1="02" i2="X" l="SPA">
<s0>Extinción luminiscencia</s0>
<s5>03</s5>
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<fC03 i1="03" i2="X" l="FRE">
<s0>Codopage</s0>
<s5>04</s5>
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<fC03 i1="03" i2="X" l="ENG">
<s0>Codoping</s0>
<s5>04</s5>
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<fC03 i1="03" i2="X" l="SPA">
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<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE">
<s0>Transfert énergie</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG">
<s0>Energy transfer</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE">
<s0>Addition ytterbium</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG">
<s0>Ytterbium additions</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Relaxation croisée</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Cross relaxation</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Relajación cruzada</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE">
<s0>Addition thulium</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG">
<s0>Thulium additions</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE">
<s0>Fluorescence</s0>
<s5>10</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG">
<s0>Fluorescence</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE">
<s0>Rendement quantique</s0>
<s5>11</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG">
<s0>Quantum yield</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE">
<s0>Verre phosphate</s0>
<s5>16</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG">
<s0>Phosphate glass</s0>
<s5>16</s5>
</fC03>
<fN21>
<s1>182</s1>
</fN21>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>International Conference on Dynamical processes in Excited States of Solids, DPC 07</s1>
<s2>16</s2>
<s3>Segovia ESP</s3>
<s4>2007-06-17</s4>
</fA30>
</pR>
</standard>
<server>
<NO>PASCAL 08-0285205 INIST</NO>
<ET>Spectroscopic investigations of OH
<sup>-</sup>
influence on near-infrared fluorescence quenching of Yb
<sup>3+</sup>
/Tm
<sup>3+</sup>
co-doped sodium-metaphosphate glasses</ET>
<AU>TERRA (I. A. A.); DE CAMARGO (A. S. S.); TERRILE (M. C.); NUNES (L. A. O.); GARCIA-SOLE (José); DE ANDRES (Alicia); BAUSA (Luisa)</AU>
<AF>Instituto de Fisica de São Carlos, Universidade de São Paulo, Av. Trabalhador Sãocarlense 400/CEP 13566-590, USP-São Carlos, SP/Brésil (1 aut., 2 aut., 3 aut., 4 aut.); Departamento de Física de Materiales, Universidad Autónoma de Madrid/28049 Madrid/Espagne (1 aut., 2 aut.); Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Cientificas/28049 Madrid/Espagne (3 aut.)</AF>
<DT>Publication en série; Congrès; Niveau analytique</DT>
<SO>Journal of luminescence; ISSN 0022-2313; Coden JLUMA8; Pays-Bas; Da. 2008; Vol. 128; No. 5-6; Pp. 891-893; Bibl. 6 ref.</SO>
<LA>Anglais</LA>
<EA>Energy transfer processes were studied in two sets of Yb
<sup>3+</sup>
and Tm
<sup>3+</sup>
co-doped sodium-metaphosphate glasses, prepared in air and nitrogen atmospheres. Using Förster, Dexter, and Miyakawa theoretical models, the energy transfer parameters were calculated. The main ion-ion energy transfer processes analyzed were energy migration among Yb
<sup>3+</sup>
ions, cross-relaxations between Yb
<sup>3+</sup>
and Tm
<sup>3+</sup>
ions, and interactions with OH
<sup>-</sup>
radicals. The results indicated that Yb→Tm energy transfer favors 1.8 μm emissions, and there is no evidence of concentration quenching up to 2% Tm
<sub>2</sub>
O
<sub>3</sub>
doping. As expected, samples prepared in nitrogen atmosphere present higher fluorescence quantum efficiency than those prepared in air, and this feature is specially noted in the near-infrared region, where the interaction with the OH
<sup>-</sup>
radicals is more pronounced.</EA>
<CC>001B70H55Q</CC>
<FD>Rayonnement IR proche; Extinction luminescence; Codopage; Transfert énergie; Addition ytterbium; Relaxation croisée; Addition thulium; Fluorescence; Rendement quantique; Verre phosphate</FD>
<ED>Near infrared radiation; Luminescence quenching; Codoping; Energy transfer; Ytterbium additions; Cross relaxation; Thulium additions; Fluorescence; Quantum yield; Phosphate glass</ED>
<SD>Extinción luminiscencia; Codrogado; Relajación cruzada</SD>
<LO>INIST-14666.354000172659770580</LO>
<ID>08-0285205</ID>
</server>
</inist>
</record>

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