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Enhancing upconversion emissions of NaTm0.02YbxY0.98-xF4 nanocrystals through increasing Yb3+ doping

Identifieur interne : 000238 ( Pascal/Corpus ); précédent : 000237; suivant : 000239

Enhancing upconversion emissions of NaTm0.02YbxY0.98-xF4 nanocrystals through increasing Yb3+ doping

Auteurs : H. J. Liang ; Y. D. Zheng ; L. Wu ; L. X. Liu ; Z. G. Zhang ; W. W. Cao

Source :

RBID : Pascal:11-0318723

Descripteurs français

English descriptors

Abstract

By increasing the content of Yb3+ ions from 20% to 98% in NaTm0.02YbxY0.98-xF4 (x=0.2-0.98) nanocrystals with size about 10 nm, the intensities of near infrared (800 nm) and blue (470 nm) upconversion (UC) luminescence can be enhanced by orders of 45 and 49 times, respectively, under 970 nm diode laser excitation. Pump power dependence illustrated that the 800 and 470 nm radiations are still two- and three-photon processes, respectively. TEM imaging showed that the enhancement is not from the change of the crystal size. Steady-state equation and the measured lifetimes indicated that the enhanced 800 nm radiations can induce the enhancement of the 470 nm emissions, which is in good agreement with the experimental data.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0022-2313
A02 01      @0 JLUMA8
A03   1    @0 J. lumin.
A05       @2 131
A06       @2 8
A08 01  1  ENG  @1 Enhancing upconversion emissions of NaTm0.02YbxY0.98-xF4 nanocrystals through increasing Yb3+ doping
A11 01  1    @1 LIANG (H. J.)
A11 02  1    @1 ZHENG (Y. D.)
A11 03  1    @1 WU (L.)
A11 04  1    @1 LIU (L. X)
A11 05  1    @1 ZHANG (Z. G.)
A11 06  1    @1 CAO (W. W.)
A14 01      @1 Department of Physics, Harbin Institute of Technology @2 150001 Harbin @3 CHN @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 4 aut. @Z 5 aut.
A14 02      @1 Laboratory of Sono- and photo- theranostic Technology, Harbin Institute of Technology @2 150001 Harbin @3 CHN @Z 1 aut. @Z 2 aut. @Z 4 aut. @Z 5 aut. @Z 6 aut.
A14 03      @1 Materials Research Institute, The Pennsylvania State University @2 University Park, 16802 Pennsylvania @3 USA @Z 6 aut.
A20       @1 1802-1806
A21       @1 2011
A23 01      @0 ENG
A43 01      @1 INIST @2 14666 @5 354000190345120450
A44       @0 0000 @1 © 2011 INIST-CNRS. All rights reserved.
A45       @0 20 ref.
A47 01  1    @0 11-0318723
A60       @1 P
A61       @0 A
A64 01  1    @0 Journal of luminescence
A66 01      @0 NLD
C01 01    ENG  @0 By increasing the content of Yb3+ ions from 20% to 98% in NaTm0.02YbxY0.98-xF4 (x=0.2-0.98) nanocrystals with size about 10 nm, the intensities of near infrared (800 nm) and blue (470 nm) upconversion (UC) luminescence can be enhanced by orders of 45 and 49 times, respectively, under 970 nm diode laser excitation. Pump power dependence illustrated that the 800 and 470 nm radiations are still two- and three-photon processes, respectively. TEM imaging showed that the enhancement is not from the change of the crystal size. Steady-state equation and the measured lifetimes indicated that the enhanced 800 nm radiations can induce the enhancement of the 470 nm emissions, which is in good agreement with the experimental data.
C02 01  3    @0 001B70H67B
C03 01  3  FRE  @0 Photoluminescence @5 02
C03 01  3  ENG  @0 Photoluminescence @5 02
C03 02  X  FRE  @0 Dopage @5 03
C03 02  X  ENG  @0 Doping @5 03
C03 02  X  SPA  @0 Doping @5 03
C03 03  3  FRE  @0 Processus n photons @5 04
C03 03  3  ENG  @0 Multi-photon processes @5 04
C03 04  X  FRE  @0 Spectre excitation @5 05
C03 04  X  ENG  @0 Excitation spectrum @5 05
C03 04  X  SPA  @0 Espectro excitación @5 05
C03 05  3  FRE  @0 Composition chimique @5 06
C03 05  3  ENG  @0 Chemical composition @5 06
C03 06  3  FRE  @0 Microscopie électronique transmission @5 07
C03 06  3  ENG  @0 Transmission electron microscopy @5 07
C03 07  3  FRE  @0 Niveau énergie @5 08
C03 07  3  ENG  @0 Energy levels @5 08
C03 08  X  FRE  @0 Déclin luminescence @5 09
C03 08  X  ENG  @0 Luminescence decay @5 09
C03 08  X  SPA  @0 Decadencia luminiscencia @5 09
C03 09  X  FRE  @0 Conversion fréquence @5 10
C03 09  X  ENG  @0 Frequency conversion @5 10
C03 09  X  SPA  @0 Conversión frecuencia @5 10
C03 10  X  FRE  @0 Sodium Ytterbium Yttrium Fluorure Mixte @2 NC @2 NA @5 11
C03 10  X  ENG  @0 Sodium Ytterbium Yttrium Fluorides Mixed @2 NC @2 NA @5 11
C03 10  X  SPA  @0 Mixto @2 NC @2 NA @5 11
C03 11  3  FRE  @0 Addition thulium @5 12
C03 11  3  ENG  @0 Thulium additions @5 12
C03 12  3  FRE  @0 Spectre résolution temporelle @5 13
C03 12  3  ENG  @0 Time resolved spectra @5 13
C03 13  3  FRE  @0 Dimension particule @5 14
C03 13  3  ENG  @0 Particle size @5 14
C03 14  X  FRE  @0 Nanocristal @5 15
C03 14  X  ENG  @0 Nanocrystal @5 15
C03 14  X  SPA  @0 Nanocristal @5 15
N21       @1 220

Format Inist (serveur)

NO : PASCAL 11-0318723 INIST
ET : Enhancing upconversion emissions of NaTm0.02YbxY0.98-xF4 nanocrystals through increasing Yb3+ doping
AU : LIANG (H. J.); ZHENG (Y. D.); WU (L.); LIU (L. X); ZHANG (Z. G.); CAO (W. W.)
AF : Department of Physics, Harbin Institute of Technology/150001 Harbin/Chine (1 aut., 2 aut., 3 aut., 4 aut., 5 aut.); Laboratory of Sono- and photo- theranostic Technology, Harbin Institute of Technology/150001 Harbin/Chine (1 aut., 2 aut., 4 aut., 5 aut., 6 aut.); Materials Research Institute, The Pennsylvania State University/University Park, 16802 Pennsylvania/Etats-Unis (6 aut.)
DT : Publication en série; Niveau analytique
SO : Journal of luminescence; ISSN 0022-2313; Coden JLUMA8; Pays-Bas; Da. 2011; Vol. 131; No. 8; Pp. 1802-1806; Bibl. 20 ref.
LA : Anglais
EA : By increasing the content of Yb3+ ions from 20% to 98% in NaTm0.02YbxY0.98-xF4 (x=0.2-0.98) nanocrystals with size about 10 nm, the intensities of near infrared (800 nm) and blue (470 nm) upconversion (UC) luminescence can be enhanced by orders of 45 and 49 times, respectively, under 970 nm diode laser excitation. Pump power dependence illustrated that the 800 and 470 nm radiations are still two- and three-photon processes, respectively. TEM imaging showed that the enhancement is not from the change of the crystal size. Steady-state equation and the measured lifetimes indicated that the enhanced 800 nm radiations can induce the enhancement of the 470 nm emissions, which is in good agreement with the experimental data.
CC : 001B70H67B
FD : Photoluminescence; Dopage; Processus n photons; Spectre excitation; Composition chimique; Microscopie électronique transmission; Niveau énergie; Déclin luminescence; Conversion fréquence; Sodium Ytterbium Yttrium Fluorure Mixte; Addition thulium; Spectre résolution temporelle; Dimension particule; Nanocristal
ED : Photoluminescence; Doping; Multi-photon processes; Excitation spectrum; Chemical composition; Transmission electron microscopy; Energy levels; Luminescence decay; Frequency conversion; Sodium Ytterbium Yttrium Fluorides Mixed; Thulium additions; Time resolved spectra; Particle size; Nanocrystal
SD : Doping; Espectro excitación; Decadencia luminiscencia; Conversión frecuencia; Mixto; Nanocristal
LO : INIST-14666.354000190345120450
ID : 11-0318723

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Pascal:11-0318723

Le document en format XML

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<title xml:lang="en" level="a">Enhancing upconversion emissions of NaTm
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Yb
<sub>x</sub>
Y
<sub>0.98-x</sub>
F
<sub>4</sub>
nanocrystals through increasing Yb
<sup>3+</sup>
doping</title>
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<term>Chemical composition</term>
<term>Doping</term>
<term>Energy levels</term>
<term>Excitation spectrum</term>
<term>Frequency conversion</term>
<term>Luminescence decay</term>
<term>Multi-photon processes</term>
<term>Nanocrystal</term>
<term>Particle size</term>
<term>Photoluminescence</term>
<term>Sodium Ytterbium Yttrium Fluorides Mixed</term>
<term>Thulium additions</term>
<term>Time resolved spectra</term>
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<term>Photoluminescence</term>
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<term>Spectre excitation</term>
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<term>Microscopie électronique transmission</term>
<term>Niveau énergie</term>
<term>Déclin luminescence</term>
<term>Conversion fréquence</term>
<term>Sodium Ytterbium Yttrium Fluorure Mixte</term>
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<front>
<div type="abstract" xml:lang="en">By increasing the content of Yb
<sup>3+</sup>
ions from 20% to 98% in NaTm
<sub>0.02</sub>
Yb
<sub>x</sub>
Y
<sub>0.98-x</sub>
F
<sub>4</sub>
(x=0.2-0.98) nanocrystals with size about 10 nm, the intensities of near infrared (800 nm) and blue (470 nm) upconversion (UC) luminescence can be enhanced by orders of 45 and 49 times, respectively, under 970 nm diode laser excitation. Pump power dependence illustrated that the 800 and 470 nm radiations are still two- and three-photon processes, respectively. TEM imaging showed that the enhancement is not from the change of the crystal size. Steady-state equation and the measured lifetimes indicated that the enhanced 800 nm radiations can induce the enhancement of the 470 nm emissions, which is in good agreement with the experimental data.</div>
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<sub>x</sub>
Y
<sub>0.98-x</sub>
F
<sub>4</sub>
nanocrystals through increasing Yb
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<s1>WU (L.)</s1>
</fA11>
<fA11 i1="04" i2="1">
<s1>LIU (L. X)</s1>
</fA11>
<fA11 i1="05" i2="1">
<s1>ZHANG (Z. G.)</s1>
</fA11>
<fA11 i1="06" i2="1">
<s1>CAO (W. W.)</s1>
</fA11>
<fA14 i1="01">
<s1>Department of Physics, Harbin Institute of Technology</s1>
<s2>150001 Harbin</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
</fA14>
<fA14 i1="02">
<s1>Laboratory of Sono- and photo- theranostic Technology, Harbin Institute of Technology</s1>
<s2>150001 Harbin</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</fA14>
<fA14 i1="03">
<s1>Materials Research Institute, The Pennsylvania State University</s1>
<s2>University Park, 16802 Pennsylvania</s2>
<s3>USA</s3>
<sZ>6 aut.</sZ>
</fA14>
<fA20>
<s1>1802-1806</s1>
</fA20>
<fA21>
<s1>2011</s1>
</fA21>
<fA23 i1="01">
<s0>ENG</s0>
</fA23>
<fA43 i1="01">
<s1>INIST</s1>
<s2>14666</s2>
<s5>354000190345120450</s5>
</fA43>
<fA44>
<s0>0000</s0>
<s1>© 2011 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45>
<s0>20 ref.</s0>
</fA45>
<fA47 i1="01" i2="1">
<s0>11-0318723</s0>
</fA47>
<fA60>
<s1>P</s1>
</fA60>
<fA61>
<s0>A</s0>
</fA61>
<fA64 i1="01" i2="1">
<s0>Journal of luminescence</s0>
</fA64>
<fA66 i1="01">
<s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG">
<s0>By increasing the content of Yb
<sup>3+</sup>
ions from 20% to 98% in NaTm
<sub>0.02</sub>
Yb
<sub>x</sub>
Y
<sub>0.98-x</sub>
F
<sub>4</sub>
(x=0.2-0.98) nanocrystals with size about 10 nm, the intensities of near infrared (800 nm) and blue (470 nm) upconversion (UC) luminescence can be enhanced by orders of 45 and 49 times, respectively, under 970 nm diode laser excitation. Pump power dependence illustrated that the 800 and 470 nm radiations are still two- and three-photon processes, respectively. TEM imaging showed that the enhancement is not from the change of the crystal size. Steady-state equation and the measured lifetimes indicated that the enhanced 800 nm radiations can induce the enhancement of the 470 nm emissions, which is in good agreement with the experimental data.</s0>
</fC01>
<fC02 i1="01" i2="3">
<s0>001B70H67B</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE">
<s0>Photoluminescence</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG">
<s0>Photoluminescence</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE">
<s0>Dopage</s0>
<s5>03</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG">
<s0>Doping</s0>
<s5>03</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA">
<s0>Doping</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE">
<s0>Processus n photons</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG">
<s0>Multi-photon processes</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE">
<s0>Spectre excitation</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG">
<s0>Excitation spectrum</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA">
<s0>Espectro excitación</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE">
<s0>Composition chimique</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG">
<s0>Chemical composition</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE">
<s0>Microscopie électronique transmission</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG">
<s0>Transmission electron microscopy</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE">
<s0>Niveau énergie</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG">
<s0>Energy levels</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Déclin luminescence</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Luminescence decay</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Decadencia luminiscencia</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Conversion fréquence</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>Frequency conversion</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Conversión frecuencia</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Sodium Ytterbium Yttrium Fluorure Mixte</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Sodium Ytterbium Yttrium Fluorides Mixed</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Mixto</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>Addition thulium</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG">
<s0>Thulium additions</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE">
<s0>Spectre résolution temporelle</s0>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG">
<s0>Time resolved spectra</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>Dimension particule</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG">
<s0>Particle size</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Nanocristal</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG">
<s0>Nanocrystal</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA">
<s0>Nanocristal</s0>
<s5>15</s5>
</fC03>
<fN21>
<s1>220</s1>
</fN21>
</pA>
</standard>
<server>
<NO>PASCAL 11-0318723 INIST</NO>
<ET>Enhancing upconversion emissions of NaTm
<sub>0.02</sub>
Yb
<sub>x</sub>
Y
<sub>0.98-x</sub>
F
<sub>4</sub>
nanocrystals through increasing Yb
<sup>3+</sup>
doping</ET>
<AU>LIANG (H. J.); ZHENG (Y. D.); WU (L.); LIU (L. X); ZHANG (Z. G.); CAO (W. W.)</AU>
<AF>Department of Physics, Harbin Institute of Technology/150001 Harbin/Chine (1 aut., 2 aut., 3 aut., 4 aut., 5 aut.); Laboratory of Sono- and photo- theranostic Technology, Harbin Institute of Technology/150001 Harbin/Chine (1 aut., 2 aut., 4 aut., 5 aut., 6 aut.); Materials Research Institute, The Pennsylvania State University/University Park, 16802 Pennsylvania/Etats-Unis (6 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Journal of luminescence; ISSN 0022-2313; Coden JLUMA8; Pays-Bas; Da. 2011; Vol. 131; No. 8; Pp. 1802-1806; Bibl. 20 ref.</SO>
<LA>Anglais</LA>
<EA>By increasing the content of Yb
<sup>3+</sup>
ions from 20% to 98% in NaTm
<sub>0.02</sub>
Yb
<sub>x</sub>
Y
<sub>0.98-x</sub>
F
<sub>4</sub>
(x=0.2-0.98) nanocrystals with size about 10 nm, the intensities of near infrared (800 nm) and blue (470 nm) upconversion (UC) luminescence can be enhanced by orders of 45 and 49 times, respectively, under 970 nm diode laser excitation. Pump power dependence illustrated that the 800 and 470 nm radiations are still two- and three-photon processes, respectively. TEM imaging showed that the enhancement is not from the change of the crystal size. Steady-state equation and the measured lifetimes indicated that the enhanced 800 nm radiations can induce the enhancement of the 470 nm emissions, which is in good agreement with the experimental data.</EA>
<CC>001B70H67B</CC>
<FD>Photoluminescence; Dopage; Processus n photons; Spectre excitation; Composition chimique; Microscopie électronique transmission; Niveau énergie; Déclin luminescence; Conversion fréquence; Sodium Ytterbium Yttrium Fluorure Mixte; Addition thulium; Spectre résolution temporelle; Dimension particule; Nanocristal</FD>
<ED>Photoluminescence; Doping; Multi-photon processes; Excitation spectrum; Chemical composition; Transmission electron microscopy; Energy levels; Luminescence decay; Frequency conversion; Sodium Ytterbium Yttrium Fluorides Mixed; Thulium additions; Time resolved spectra; Particle size; Nanocrystal</ED>
<SD>Doping; Espectro excitación; Decadencia luminiscencia; Conversión frecuencia; Mixto; Nanocristal</SD>
<LO>INIST-14666.354000190345120450</LO>
<ID>11-0318723</ID>
</server>
</inist>
</record>

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