Enhancement of lanthanide evaporation by complexation: dysprosium tri-iodide mixed with indium iodide and thulium tri-iodide mixed with thallium iodide.
Identifieur interne : 000744 ( Ncbi/Curation ); précédent : 000743; suivant : 000745Enhancement of lanthanide evaporation by complexation: dysprosium tri-iodide mixed with indium iodide and thulium tri-iodide mixed with thallium iodide.
Auteurs : J J Curry [États-Unis] ; E G Estupi N ; A. Henins ; W P Lapatovich ; S D Shastri ; J E HardisSource :
- The Journal of chemical physics [ 1089-7690 ] ; 2013.
Abstract
The vapors in equilibrium with condensates of DyI3, DyI3/InI, TmI3, and TmI3/TlI were observed over the temperature range from 900 K to 1400 K using x-ray induced fluorescence. The total densities of each element (Dy, Tm, In, Tl, and I) in the vapor, summed over all atomic and molecular species, were determined. Dramatic enhancements in the total vapor densities of Dy and Tm were observed in the vapors over DyI3/InI and TmI3/TlI as compared to the vapors over pure DyI3 and pure TmI3, respectively. An enhancement factor exceeding 10 was observed for Dy at T ≈ 1020 K, decreasing to 0 at T ≈ 1250 K. An enhancement factor exceeding 20 was observed for Tm at T ≈ 1040 K, decreasing to 0 at T ≈ 1300 K. Such enhancements are expected from the formation of the vapor-phase hetero-complexes DyInI4 and TmTlI4. Numerical simulations of the thermo-chemical equilibrium suggest the importance of additional complexes in liquid phases. A description of the measurement technique is given. Improvements in the absolute calibration lead to an approximately 40% correction to previously reported preliminary results [J. J. Curry et al., Chem. Phys. Lett. 507, 52 (2011); Appl. Phys. Lett. 100, 083505 (2012)].
DOI: 10.1063/1.4821828
PubMed: 24089770
Links toward previous steps (curation, corpus...)
- to stream PubMed, to step Corpus: Pour aller vers cette notice dans l'étape Curation :000243
- to stream PubMed, to step Curation: Pour aller vers cette notice dans l'étape Curation :000243
- to stream PubMed, to step Checkpoint: Pour aller vers cette notice dans l'étape Curation :000243
- to stream Ncbi, to step Merge: Pour aller vers cette notice dans l'étape Curation :000744
Links to Exploration step
pubmed:24089770Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Enhancement of lanthanide evaporation by complexation: dysprosium tri-iodide mixed with indium iodide and thulium tri-iodide mixed with thallium iodide.</title><author><name sortKey="Curry, J J" sort="Curry, J J" uniqKey="Curry J" first="J J" last="Curry">J J Curry</name><affiliation wicri:level="1"><nlm:affiliation>National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, Maryland 20899, USA.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, Maryland 20899</wicri:regionArea><wicri:noRegion>Maryland 20899</wicri:noRegion></affiliation></author><author><name sortKey="Estupi N, E G" sort="Estupi N, E G" uniqKey="Estupi N E" first="E G" last="Estupi N">E G Estupi N</name></author><author><name sortKey="Henins, A" sort="Henins, A" uniqKey="Henins A" first="A" last="Henins">A. Henins</name></author><author><name sortKey="Lapatovich, W P" sort="Lapatovich, W P" uniqKey="Lapatovich W" first="W P" last="Lapatovich">W P Lapatovich</name></author><author><name sortKey="Shastri, S D" sort="Shastri, S D" uniqKey="Shastri S" first="S D" last="Shastri">S D Shastri</name></author><author><name sortKey="Hardis, J E" sort="Hardis, J E" uniqKey="Hardis J" first="J E" last="Hardis">J E Hardis</name></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2013">2013</date><idno type="doi">10.1063/1.4821828</idno><idno type="RBID">pubmed:24089770</idno><idno type="pmid">24089770</idno><idno type="wicri:Area/PubMed/Corpus">000243</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000243</idno><idno type="wicri:Area/PubMed/Curation">000243</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000243</idno><idno type="wicri:Area/PubMed/Checkpoint">000243</idno><idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">000243</idno><idno type="wicri:Area/Ncbi/Merge">000744</idno><idno type="wicri:Area/Ncbi/Curation">000744</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Enhancement of lanthanide evaporation by complexation: dysprosium tri-iodide mixed with indium iodide and thulium tri-iodide mixed with thallium iodide.</title><author><name sortKey="Curry, J J" sort="Curry, J J" uniqKey="Curry J" first="J J" last="Curry">J J Curry</name><affiliation wicri:level="1"><nlm:affiliation>National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, Maryland 20899, USA.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, Maryland 20899</wicri:regionArea><wicri:noRegion>Maryland 20899</wicri:noRegion></affiliation></author><author><name sortKey="Estupi N, E G" sort="Estupi N, E G" uniqKey="Estupi N E" first="E G" last="Estupi N">E G Estupi N</name></author><author><name sortKey="Henins, A" sort="Henins, A" uniqKey="Henins A" first="A" last="Henins">A. Henins</name></author><author><name sortKey="Lapatovich, W P" sort="Lapatovich, W P" uniqKey="Lapatovich W" first="W P" last="Lapatovich">W P Lapatovich</name></author><author><name sortKey="Shastri, S D" sort="Shastri, S D" uniqKey="Shastri S" first="S D" last="Shastri">S D Shastri</name></author><author><name sortKey="Hardis, J E" sort="Hardis, J E" uniqKey="Hardis J" first="J E" last="Hardis">J E Hardis</name></author></analytic><series><title level="j">The Journal of chemical physics</title><idno type="eISSN">1089-7690</idno><imprint><date when="2013" type="published">2013</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The vapors in equilibrium with condensates of DyI3, DyI3/InI, TmI3, and TmI3/TlI were observed over the temperature range from 900 K to 1400 K using x-ray induced fluorescence. The total densities of each element (Dy, Tm, In, Tl, and I) in the vapor, summed over all atomic and molecular species, were determined. Dramatic enhancements in the total vapor densities of Dy and Tm were observed in the vapors over DyI3/InI and TmI3/TlI as compared to the vapors over pure DyI3 and pure TmI3, respectively. An enhancement factor exceeding 10 was observed for Dy at T ≈ 1020 K, decreasing to 0 at T ≈ 1250 K. An enhancement factor exceeding 20 was observed for Tm at T ≈ 1040 K, decreasing to 0 at T ≈ 1300 K. Such enhancements are expected from the formation of the vapor-phase hetero-complexes DyInI4 and TmTlI4. Numerical simulations of the thermo-chemical equilibrium suggest the importance of additional complexes in liquid phases. A description of the measurement technique is given. Improvements in the absolute calibration lead to an approximately 40% correction to previously reported preliminary results [J. J. Curry et al., Chem. Phys. Lett. 507, 52 (2011); Appl. Phys. Lett. 100, 083505 (2012)].</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/ThuliumV1/Data/Ncbi/Curation
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000744 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Ncbi/Curation/biblio.hfd -nk 000744 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Terre
|area= ThuliumV1
|flux= Ncbi
|étape= Curation
|type= RBID
|clé= pubmed:24089770
|texte= Enhancement of lanthanide evaporation by complexation: dysprosium tri-iodide mixed with indium iodide and thulium tri-iodide mixed with thallium iodide.
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Ncbi/Curation/RBID.i -Sk "pubmed:24089770" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Ncbi/Curation/biblio.hfd \
| NlmPubMed2Wicri -a ThuliumV1
| This area was generated with Dilib version V0.6.21. |  |