Enhancement of lanthanide evaporation by complexation: dysprosium tri-iodide mixed with indium iodide and thulium tri-iodide mixed with thallium iodide.
Identifieur interne : 000243 ( PubMed/Corpus ); précédent : 000242; suivant : 000244Enhancement of lanthanide evaporation by complexation: dysprosium tri-iodide mixed with indium iodide and thulium tri-iodide mixed with thallium iodide.
Auteurs : J J Curry ; E G Estupi N ; A. Henins ; W P Lapatovich ; S D Shastri ; J E HardisSource :
- The Journal of chemical physics [ 1089-7690 ] ; 2013.
Abstract
The vapors in equilibrium with condensates of DyI3, DyI3/InI, TmI3, and TmI3/TlI were observed over the temperature range from 900 K to 1400 K using x-ray induced fluorescence. The total densities of each element (Dy, Tm, In, Tl, and I) in the vapor, summed over all atomic and molecular species, were determined. Dramatic enhancements in the total vapor densities of Dy and Tm were observed in the vapors over DyI3/InI and TmI3/TlI as compared to the vapors over pure DyI3 and pure TmI3, respectively. An enhancement factor exceeding 10 was observed for Dy at T ≈ 1020 K, decreasing to 0 at T ≈ 1250 K. An enhancement factor exceeding 20 was observed for Tm at T ≈ 1040 K, decreasing to 0 at T ≈ 1300 K. Such enhancements are expected from the formation of the vapor-phase hetero-complexes DyInI4 and TmTlI4. Numerical simulations of the thermo-chemical equilibrium suggest the importance of additional complexes in liquid phases. A description of the measurement technique is given. Improvements in the absolute calibration lead to an approximately 40% correction to previously reported preliminary results [J. J. Curry et al., Chem. Phys. Lett. 507, 52 (2011); Appl. Phys. Lett. 100, 083505 (2012)].
DOI: 10.1063/1.4821828
PubMed: 24089770
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Enhancement of lanthanide evaporation by complexation: dysprosium tri-iodide mixed with indium iodide and thulium tri-iodide mixed with thallium iodide.</title><author><name sortKey="Curry, J J" sort="Curry, J J" uniqKey="Curry J" first="J J" last="Curry">J J Curry</name><affiliation><nlm:affiliation>National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, Maryland 20899, USA.</nlm:affiliation></affiliation></author><author><name sortKey="Estupi N, E G" sort="Estupi N, E G" uniqKey="Estupi N E" first="E G" last="Estupi N">E G Estupi N</name></author><author><name sortKey="Henins, A" sort="Henins, A" uniqKey="Henins A" first="A" last="Henins">A. Henins</name></author><author><name sortKey="Lapatovich, W P" sort="Lapatovich, W P" uniqKey="Lapatovich W" first="W P" last="Lapatovich">W P Lapatovich</name></author><author><name sortKey="Shastri, S D" sort="Shastri, S D" uniqKey="Shastri S" first="S D" last="Shastri">S D Shastri</name></author><author><name sortKey="Hardis, J E" sort="Hardis, J E" uniqKey="Hardis J" first="J E" last="Hardis">J E Hardis</name></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2013">2013</date><idno type="doi">10.1063/1.4821828</idno><idno type="RBID">pubmed:24089770</idno><idno type="pmid">24089770</idno><idno type="wicri:Area/PubMed/Corpus">000243</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000243</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Enhancement of lanthanide evaporation by complexation: dysprosium tri-iodide mixed with indium iodide and thulium tri-iodide mixed with thallium iodide.</title><author><name sortKey="Curry, J J" sort="Curry, J J" uniqKey="Curry J" first="J J" last="Curry">J J Curry</name><affiliation><nlm:affiliation>National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, Maryland 20899, USA.</nlm:affiliation></affiliation></author><author><name sortKey="Estupi N, E G" sort="Estupi N, E G" uniqKey="Estupi N E" first="E G" last="Estupi N">E G Estupi N</name></author><author><name sortKey="Henins, A" sort="Henins, A" uniqKey="Henins A" first="A" last="Henins">A. Henins</name></author><author><name sortKey="Lapatovich, W P" sort="Lapatovich, W P" uniqKey="Lapatovich W" first="W P" last="Lapatovich">W P Lapatovich</name></author><author><name sortKey="Shastri, S D" sort="Shastri, S D" uniqKey="Shastri S" first="S D" last="Shastri">S D Shastri</name></author><author><name sortKey="Hardis, J E" sort="Hardis, J E" uniqKey="Hardis J" first="J E" last="Hardis">J E Hardis</name></author></analytic><series><title level="j">The Journal of chemical physics</title><idno type="eISSN">1089-7690</idno><imprint><date when="2013" type="published">2013</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The vapors in equilibrium with condensates of DyI3, DyI3/InI, TmI3, and TmI3/TlI were observed over the temperature range from 900 K to 1400 K using x-ray induced fluorescence. The total densities of each element (Dy, Tm, In, Tl, and I) in the vapor, summed over all atomic and molecular species, were determined. Dramatic enhancements in the total vapor densities of Dy and Tm were observed in the vapors over DyI3/InI and TmI3/TlI as compared to the vapors over pure DyI3 and pure TmI3, respectively. An enhancement factor exceeding 10 was observed for Dy at T ≈ 1020 K, decreasing to 0 at T ≈ 1250 K. An enhancement factor exceeding 20 was observed for Tm at T ≈ 1040 K, decreasing to 0 at T ≈ 1300 K. Such enhancements are expected from the formation of the vapor-phase hetero-complexes DyInI4 and TmTlI4. Numerical simulations of the thermo-chemical equilibrium suggest the importance of additional complexes in liquid phases. A description of the measurement technique is given. Improvements in the absolute calibration lead to an approximately 40% correction to previously reported preliminary results [J. J. Curry et al., Chem. Phys. Lett. 507, 52 (2011); Appl. Phys. Lett. 100, 083505 (2012)].</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">24089770</PMID><DateCreated><Year>2013</Year><Month>10</Month><Day>04</Day></DateCreated><DateCompleted><Year>2014</Year><Month>04</Month><Day>25</Day></DateCompleted><Article PubModel="Print"><Journal><ISSN IssnType="Electronic">1089-7690</ISSN><JournalIssue CitedMedium="Internet"><Volume>139</Volume><Issue>12</Issue><PubDate><Year>2013</Year><Month>Sep</Month><Day>28</Day></PubDate></JournalIssue><Title>The Journal of chemical physics</Title><ISOAbbreviation>J Chem Phys</ISOAbbreviation></Journal><ArticleTitle>Enhancement of lanthanide evaporation by complexation: dysprosium tri-iodide mixed with indium iodide and thulium tri-iodide mixed with thallium iodide.</ArticleTitle><Pagination><MedlinePgn>124310</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1063/1.4821828</ELocationID><Abstract><AbstractText>The vapors in equilibrium with condensates of DyI3, DyI3/InI, TmI3, and TmI3/TlI were observed over the temperature range from 900 K to 1400 K using x-ray induced fluorescence. The total densities of each element (Dy, Tm, In, Tl, and I) in the vapor, summed over all atomic and molecular species, were determined. Dramatic enhancements in the total vapor densities of Dy and Tm were observed in the vapors over DyI3/InI and TmI3/TlI as compared to the vapors over pure DyI3 and pure TmI3, respectively. An enhancement factor exceeding 10 was observed for Dy at T ≈ 1020 K, decreasing to 0 at T ≈ 1250 K. An enhancement factor exceeding 20 was observed for Tm at T ≈ 1040 K, decreasing to 0 at T ≈ 1300 K. Such enhancements are expected from the formation of the vapor-phase hetero-complexes DyInI4 and TmTlI4. Numerical simulations of the thermo-chemical equilibrium suggest the importance of additional complexes in liquid phases. A description of the measurement technique is given. Improvements in the absolute calibration lead to an approximately 40% correction to previously reported preliminary results [J. J. Curry et al., Chem. Phys. Lett. 507, 52 (2011); Appl. Phys. Lett. 100, 083505 (2012)].</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Curry</LastName><ForeName>J J</ForeName><Initials>JJ</Initials><AffiliationInfo><Affiliation>National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, Maryland 20899, USA.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Estupiñán</LastName><ForeName>E G</ForeName><Initials>EG</Initials></Author><Author ValidYN="Y"><LastName>Henins</LastName><ForeName>A</ForeName><Initials>A</Initials></Author><Author ValidYN="Y"><LastName>Lapatovich</LastName><ForeName>W P</ForeName><Initials>WP</Initials></Author><Author ValidYN="Y"><LastName>Shastri</LastName><ForeName>S D</ForeName><Initials>SD</Initials></Author><Author ValidYN="Y"><LastName>Hardis</LastName><ForeName>J E</ForeName><Initials>JE</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>J Chem Phys</MedlineTA><NlmUniqueID>0375360</NlmUniqueID><ISSNLinking>0021-9606</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="entrez"><Year>2013</Year><Month>10</Month><Day>5</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2013</Year><Month>10</Month><Day>5</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2013</Year><Month>10</Month><Day>5</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1063/1.4821828</ArticleId><ArticleId IdType="pubmed">24089770</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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