Magnetic order and crystal fields in the Pnma phases of Tm2BaTO5 (T=Co and Ni)
Identifieur interne : 002539 ( Main/Merge ); précédent : 002538; suivant : 002540Magnetic order and crystal fields in the Pnma phases of Tm2BaTO5 (T=Co and Ni)
Auteurs : S. J. Harker [Pays-Bas] ; G. A. Stewart [Pays-Bas] ; P. C. M. Gubbens [Australie]Source :
- Journal of alloys and compounds [ 0925-8388 ] ; 2000.
Descripteurs français
- Pascal (Inist)
- Ordre magnétique, Champ cristallin, Interaction champ cristallin, Spectrométrie Mössbauer, Interaction hyperfine, Dépendance température, Sous réseau, Décomposition quadripolaire, Interaction échange, Site cristallographique, Réseau orthorhombique, Baryum oxyde, Thulium oxyde, Cobalt oxyde, Nickel oxyde, Etude expérimentale, Composé quaternaire, 7525, 7680, Tm2BaCoO5, Ba Co O Tm, Tm2BaNiO5, Ba Ni O Tm.
English descriptors
- KwdEn :
- Barium oxides, Cobalt oxides, Crystal field, Crystal field interactions, Crystallographic site, Exchange interactions, Experimental study, Hyperfine interactions, Magnetic ordering, Moessbauer spectroscopy, Nickel oxides, Orthorhombic lattices, Quadrupolar splitting, Quaternary compounds, Sublattices, Temperature dependence, Thulium oxides.
Abstract
The magnetic ordering and crystal field interactions of the Pnma phases of both Tm2BaCoO5 and Tm2BaNiO5 are investigated by 169Tm Mössbauer spectroscopy and the temperature-dependent hyperfine interactions are compared with those obtained elsewhere for Tm2BaCuO5. The Pnma phases are shown to order magnetically at temperatures of 3.5(2) K (Tm2BaCoO5) and 4.85(5) K (Tm2BaNiO5), the order being induced by the transition metal. For Tm2BaNiO5 an additional first-order transition observed at T≤1.4 K is identified with the independent magnetic order of the thulium sub-lattice.
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Pascal:00-0371646Le document en format XML
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BaTO<sub>5</sub>
(T=Co and Ni)</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Magnetic order and crystal fields in the Pnma phases of Tm<sub>2</sub>
BaTO<sub>5</sub>
(T=Co and Ni)</title>
<author><name sortKey="Harker, S J" sort="Harker, S J" uniqKey="Harker S" first="S. J." last="Harker">S. J. Harker</name>
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<series><title level="j" type="main">Journal of alloys and compounds</title>
<title level="j" type="abbreviated">J. alloys compd.</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Barium oxides</term>
<term>Cobalt oxides</term>
<term>Crystal field</term>
<term>Crystal field interactions</term>
<term>Crystallographic site</term>
<term>Exchange interactions</term>
<term>Experimental study</term>
<term>Hyperfine interactions</term>
<term>Magnetic ordering</term>
<term>Moessbauer spectroscopy</term>
<term>Nickel oxides</term>
<term>Orthorhombic lattices</term>
<term>Quadrupolar splitting</term>
<term>Quaternary compounds</term>
<term>Sublattices</term>
<term>Temperature dependence</term>
<term>Thulium oxides</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Ordre magnétique</term>
<term>Champ cristallin</term>
<term>Interaction champ cristallin</term>
<term>Spectrométrie Mössbauer</term>
<term>Interaction hyperfine</term>
<term>Dépendance température</term>
<term>Sous réseau</term>
<term>Décomposition quadripolaire</term>
<term>Interaction échange</term>
<term>Site cristallographique</term>
<term>Réseau orthorhombique</term>
<term>Baryum oxyde</term>
<term>Thulium oxyde</term>
<term>Cobalt oxyde</term>
<term>Nickel oxyde</term>
<term>Etude expérimentale</term>
<term>Composé quaternaire</term>
<term>7525</term>
<term>7680</term>
<term>Tm2BaCoO5</term>
<term>Ba Co O Tm</term>
<term>Tm2BaNiO5</term>
<term>Ba Ni O Tm</term>
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<front><div type="abstract" xml:lang="en">The magnetic ordering and crystal field interactions of the Pnma phases of both Tm<sub>2</sub>
BaCoO<sub>5</sub>
and Tm<sub>2</sub>
BaNiO<sub>5</sub>
are investigated by <sup>169</sup>
Tm Mössbauer spectroscopy and the temperature-dependent hyperfine interactions are compared with those obtained elsewhere for Tm<sub>2</sub>
BaCuO<sub>5</sub>
. The Pnma phases are shown to order magnetically at temperatures of 3.5(2) K (Tm<sub>2</sub>
BaCoO<sub>5</sub>
) and 4.85(5) K (Tm<sub>2</sub>
BaNiO<sub>5</sub>
), the order being induced by the transition metal. For Tm<sub>2</sub>
BaNiO<sub>5</sub>
an additional first-order transition observed at T≤1.4 K is identified with the independent magnetic order of the thulium sub-lattice.</div>
</front>
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<country name="Australie"><noRegion><name sortKey="Gubbens, P C M" sort="Gubbens, P C M" uniqKey="Gubbens P" first="P. C. M." last="Gubbens">P. C. M. Gubbens</name>
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