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Magnetic order and crystal fields in the Pnma phases of Tm2BaTO5 (T=Co and Ni)

Identifieur interne : 002539 ( Main/Merge ); précédent : 002538; suivant : 002540

Magnetic order and crystal fields in the Pnma phases of Tm2BaTO5 (T=Co and Ni)

Auteurs : S. J. Harker [Pays-Bas] ; G. A. Stewart [Pays-Bas] ; P. C. M. Gubbens [Australie]

Source :

RBID : Pascal:00-0371646

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Abstract

The magnetic ordering and crystal field interactions of the Pnma phases of both Tm2BaCoO5 and Tm2BaNiO5 are investigated by 169Tm Mössbauer spectroscopy and the temperature-dependent hyperfine interactions are compared with those obtained elsewhere for Tm2BaCuO5. The Pnma phases are shown to order magnetically at temperatures of 3.5(2) K (Tm2BaCoO5) and 4.85(5) K (Tm2BaNiO5), the order being induced by the transition metal. For Tm2BaNiO5 an additional first-order transition observed at T≤1.4 K is identified with the independent magnetic order of the thulium sub-lattice.

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Pascal:00-0371646

Le document en format XML

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<title level="j" type="main">Journal of alloys and compounds</title>
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<term>Barium oxides</term>
<term>Cobalt oxides</term>
<term>Crystal field</term>
<term>Crystal field interactions</term>
<term>Crystallographic site</term>
<term>Exchange interactions</term>
<term>Experimental study</term>
<term>Hyperfine interactions</term>
<term>Magnetic ordering</term>
<term>Moessbauer spectroscopy</term>
<term>Nickel oxides</term>
<term>Orthorhombic lattices</term>
<term>Quadrupolar splitting</term>
<term>Quaternary compounds</term>
<term>Sublattices</term>
<term>Temperature dependence</term>
<term>Thulium oxides</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Ordre magnétique</term>
<term>Champ cristallin</term>
<term>Interaction champ cristallin</term>
<term>Spectrométrie Mössbauer</term>
<term>Interaction hyperfine</term>
<term>Dépendance température</term>
<term>Sous réseau</term>
<term>Décomposition quadripolaire</term>
<term>Interaction échange</term>
<term>Site cristallographique</term>
<term>Réseau orthorhombique</term>
<term>Baryum oxyde</term>
<term>Thulium oxyde</term>
<term>Cobalt oxyde</term>
<term>Nickel oxyde</term>
<term>Etude expérimentale</term>
<term>Composé quaternaire</term>
<term>7525</term>
<term>7680</term>
<term>Tm2BaCoO5</term>
<term>Ba Co O Tm</term>
<term>Tm2BaNiO5</term>
<term>Ba Ni O Tm</term>
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<div type="abstract" xml:lang="en">The magnetic ordering and crystal field interactions of the Pnma phases of both Tm
<sub>2</sub>
BaCoO
<sub>5</sub>
and Tm
<sub>2</sub>
BaNiO
<sub>5</sub>
are investigated by
<sup>169</sup>
Tm Mössbauer spectroscopy and the temperature-dependent hyperfine interactions are compared with those obtained elsewhere for Tm
<sub>2</sub>
BaCuO
<sub>5</sub>
. The Pnma phases are shown to order magnetically at temperatures of 3.5(2) K (Tm
<sub>2</sub>
BaCoO
<sub>5</sub>
) and 4.85(5) K (Tm
<sub>2</sub>
BaNiO
<sub>5</sub>
), the order being induced by the transition metal. For Tm
<sub>2</sub>
BaNiO
<sub>5</sub>
an additional first-order transition observed at T≤1.4 K is identified with the independent magnetic order of the thulium sub-lattice.</div>
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