ThuliumV1, Pascal, Corpus, bibRecord, 000F53

Magnetic order and crystal fields in the Pnma phases of Tm2BaTO5 (T=Co and Ni)

Identifieur interne : 000F53 ( Pascal/Corpus ); précédent : 000F52; suivant : 000F54

Magnetic order and crystal fields in the Pnma phases of Tm2BaTO5 (T=Co and Ni)

Auteurs : S. J. Harker ; G. A. Stewart ; P. C. M. Gubbens

Source :

Journal of alloys and compounds [ 0925-8388 ] ; 2000.

RBID : Pascal:00-0371646

Descripteurs français

Pascal (Inist)
- Ordre magnétique, Champ cristallin, Interaction champ cristallin, Spectrométrie Mössbauer, Interaction hyperfine, Dépendance température, Sous réseau, Décomposition quadripolaire, Interaction échange, Site cristallographique, Réseau orthorhombique, Baryum oxyde, Thulium oxyde, Cobalt oxyde, Nickel oxyde, Etude expérimentale, Composé quaternaire, 7525, 7680, Tm2BaCoO5, Ba Co O Tm, Tm2BaNiO5, Ba Ni O Tm.

English descriptors

KwdEn :
- Barium oxides, Cobalt oxides, Crystal field, Crystal field interactions, Crystallographic site, Exchange interactions, Experimental study, Hyperfine interactions, Magnetic ordering, Moessbauer spectroscopy, Nickel oxides, Orthorhombic lattices, Quadrupolar splitting, Quaternary compounds, Sublattices, Temperature dependence, Thulium oxides.

Abstract

The magnetic ordering and crystal field interactions of the Pnma phases of both Tm₂BaCoO₅ and Tm₂BaNiO₅ are investigated by ¹⁶⁹Tm Mössbauer spectroscopy and the temperature-dependent hyperfine interactions are compared with those obtained elsewhere for Tm₂BaCuO₅. The Pnma phases are shown to order magnetically at temperatures of 3.5(2) K (Tm₂BaCoO₅) and 4.85(5) K (Tm₂BaNiO₅), the order being induced by the transition metal. For Tm₂BaNiO₅ an additional first-order transition observed at T≤1.4 K is identified with the independent magnetic order of the thulium sub-lattice.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 0925-8388`
A03		`1`		`@0 J. alloys compd.`
A05				`@2 307`
A06				`@2 1-2`
A08	`01`	`1`	`ENG`	`@1 Magnetic order and crystal fields in the Pnma phases of Tm₂BaTO₅ (T=Co and Ni)`
A11	`01`	`1`		`@1 HARKER (S. J.)`
A11	`02`	`1`		`@1 STEWART (G. A.)`
A11	`03`	`1`		`@1 GUBBENS (P. C. M.)`
A14	`01`			`@1 Interfacultair Reactor Instituut, Delft University of Technology, Mekelweg 15 @2 2629 JB Delft @3 NLD @Z 1 aut. @Z 2 aut.`
A14	`02`			`@1 School of Physics, University College. The University of New South Wales, Australian Defence Force Academy @2 Canberra, ACT 2600 @3 AUS @Z 3 aut.`
A20				`@1 70-76`
A21				`@1 2000`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 1151 @5 354000090758630110`
A44				`@0 0000 @1 © 2000 INIST-CNRS. All rights reserved.`
A45				`@0 20 ref.`
A47	`01`	`1`		`@0 00-0371646`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Journal of alloys and compounds`
A66	`01`			`@0 CHE`
C01	`01`		`ENG`	@0 The magnetic ordering and crystal field interactions of the Pnma phases of both Tm₂BaCoO₅ and Tm₂BaNiO₅ are investigated by ¹⁶⁹Tm Mössbauer spectroscopy and the temperature-dependent hyperfine interactions are compared with those obtained elsewhere for Tm₂BaCuO₅. The Pnma phases are shown to order magnetically at temperatures of 3.5(2) K (Tm₂BaCoO₅) and 4.85(5) K (Tm₂BaNiO₅), the order being induced by the transition metal. For Tm₂BaNiO₅ an additional first-order transition observed at T≤1.4 K is identified with the independent magnetic order of the thulium sub-lattice.
C02	`01`	`3`		`@0 001B70E25`
C02	`02`	`3`		`@0 001B70F80`
C03	`01`	`3`	`FRE`	`@0 Ordre magnétique @5 01`
C03	`01`	`3`	`ENG`	`@0 Magnetic ordering @5 01`
C03	`02`	`3`	`FRE`	`@0 Champ cristallin @5 02`
C03	`02`	`3`	`ENG`	`@0 Crystal field @5 02`
C03	`03`	`3`	`FRE`	`@0 Interaction champ cristallin @5 03`
C03	`03`	`3`	`ENG`	`@0 Crystal field interactions @5 03`
C03	`04`	`3`	`FRE`	`@0 Spectrométrie Mössbauer @5 04`
C03	`04`	`3`	`ENG`	`@0 Moessbauer spectroscopy @5 04`
C03	`05`	`3`	`FRE`	`@0 Interaction hyperfine @5 05`
C03	`05`	`3`	`ENG`	`@0 Hyperfine interactions @5 05`
C03	`06`	`3`	`FRE`	`@0 Dépendance température @5 06`
C03	`06`	`3`	`ENG`	`@0 Temperature dependence @5 06`
C03	`07`	`3`	`FRE`	`@0 Sous réseau @5 07`
C03	`07`	`3`	`ENG`	`@0 Sublattices @5 07`
C03	`08`	`X`	`FRE`	`@0 Décomposition quadripolaire @5 08`
C03	`08`	`X`	`ENG`	`@0 Quadrupolar splitting @5 08`
C03	`08`	`X`	`SPA`	`@0 Descomposición cuadripolar @5 08`
C03	`09`	`3`	`FRE`	`@0 Interaction échange @5 09`
C03	`09`	`3`	`ENG`	`@0 Exchange interactions @5 09`
C03	`10`	`X`	`FRE`	`@0 Site cristallographique @5 10`
C03	`10`	`X`	`ENG`	`@0 Crystallographic site @5 10`
C03	`10`	`X`	`SPA`	`@0 Sitio cristalográfico @5 10`
C03	`11`	`3`	`FRE`	`@0 Réseau orthorhombique @5 11`
C03	`11`	`3`	`ENG`	`@0 Orthorhombic lattices @5 11`
C03	`12`	`3`	`FRE`	`@0 Baryum oxyde @2 NK @5 12`
C03	`12`	`3`	`ENG`	`@0 Barium oxides @2 NK @5 12`
C03	`13`	`3`	`FRE`	`@0 Thulium oxyde @2 NK @5 13`
C03	`13`	`3`	`ENG`	`@0 Thulium oxides @2 NK @5 13`
C03	`14`	`3`	`FRE`	`@0 Cobalt oxyde @2 NK @5 14`
C03	`14`	`3`	`ENG`	`@0 Cobalt oxides @2 NK @5 14`
C03	`15`	`3`	`FRE`	`@0 Nickel oxyde @2 NK @5 15`
C03	`15`	`3`	`ENG`	`@0 Nickel oxides @2 NK @5 15`
C03	`16`	`3`	`FRE`	`@0 Etude expérimentale @5 16`
C03	`16`	`3`	`ENG`	`@0 Experimental study @5 16`
C03	`17`	`3`	`FRE`	`@0 Composé quaternaire @5 18`
C03	`17`	`3`	`ENG`	`@0 Quaternary compounds @5 18`
C03	`18`	`3`	`FRE`	`@0 7525 @2 PAC @4 INC @5 56`
C03	`19`	`3`	`FRE`	`@0 7680 @2 PAC @4 INC @5 57`
C03	`20`	`3`	`FRE`	`@0 Tm2BaCoO5 @4 INC @5 92`
C03	`21`	`3`	`FRE`	`@0 Ba Co O Tm @4 INC @5 93`
C03	`22`	`3`	`FRE`	`@0 Tm2BaNiO5 @4 INC @5 94`
C03	`23`	`3`	`FRE`	`@0 Ba Ni O Tm @4 INC @5 95`
C07	`01`	`3`	`FRE`	`@0 Composé minéral @5 17`
C07	`01`	`3`	`ENG`	`@0 Inorganic compounds @5 17`
C07	`02`	`3`	`FRE`	`@0 Métal transition composé @5 81`
C07	`02`	`3`	`ENG`	`@0 Transition element compounds @5 81`
C07	`03`	`3`	`FRE`	`@0 Lanthanide composé @5 82`
C07	`03`	`3`	`ENG`	`@0 Rare earth compounds @5 82`
N21				`@1 255`

Format Inist (serveur)

NO :	PASCAL 00-0371646 INIST
ET :	Magnetic order and crystal fields in the Pnma phases of Tm₂BaTO₅ (T=Co and Ni)
AU :	HARKER (S. J.); STEWART (G. A.); GUBBENS (P. C. M.)
AF :	Interfacultair Reactor Instituut, Delft University of Technology, Mekelweg 15/2629 JB Delft/Pays-Bas (1 aut., 2 aut.); School of Physics, University College. The University of New South Wales, Australian Defence Force Academy/Canberra, ACT 2600/Australie (3 aut.)
DT :	Publication en série; Niveau analytique
SO :	Journal of alloys and compounds; ISSN 0925-8388; Suisse; Da. 2000; Vol. 307; No. 1-2; Pp. 70-76; Bibl. 20 ref.
LA :	Anglais
EA :	The magnetic ordering and crystal field interactions of the Pnma phases of both Tm₂BaCoO₅ and Tm₂BaNiO₅ are investigated by ¹⁶⁹Tm Mössbauer spectroscopy and the temperature-dependent hyperfine interactions are compared with those obtained elsewhere for Tm₂BaCuO₅. The Pnma phases are shown to order magnetically at temperatures of 3.5(2) K (Tm₂BaCoO₅) and 4.85(5) K (Tm₂BaNiO₅), the order being induced by the transition metal. For Tm₂BaNiO₅ an additional first-order transition observed at T≤1.4 K is identified with the independent magnetic order of the thulium sub-lattice.
CC :	001B70E25; 001B70F80
FD :	Ordre magnétique; Champ cristallin; Interaction champ cristallin; Spectrométrie Mössbauer; Interaction hyperfine; Dépendance température; Sous réseau; Décomposition quadripolaire; Interaction échange; Site cristallographique; Réseau orthorhombique; Baryum oxyde; Thulium oxyde; Cobalt oxyde; Nickel oxyde; Etude expérimentale; Composé quaternaire; 7525; 7680; Tm2BaCoO5; Ba Co O Tm; Tm2BaNiO5; Ba Ni O Tm
FG :	Composé minéral; Métal transition composé; Lanthanide composé
ED :	Magnetic ordering; Crystal field; Crystal field interactions; Moessbauer spectroscopy; Hyperfine interactions; Temperature dependence; Sublattices; Quadrupolar splitting; Exchange interactions; Crystallographic site; Orthorhombic lattices; Barium oxides; Thulium oxides; Cobalt oxides; Nickel oxides; Experimental study; Quaternary compounds
EG :	Inorganic compounds; Transition element compounds; Rare earth compounds
SD :	Descomposición cuadripolar; Sitio cristalográfico
LO :	INIST-1151.354000090758630110
ID :	00-0371646

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Pascal:00-0371646

Le document en format XML

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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Magnetic order and crystal fields in the Pnma phases of Tm<sub>2</sub>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Barium oxides</term>
<term>Cobalt oxides</term>
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<term>Crystal field interactions</term>
<term>Crystallographic site</term>
<term>Exchange interactions</term>
<term>Experimental study</term>
<term>Hyperfine interactions</term>
<term>Magnetic ordering</term>
<term>Moessbauer spectroscopy</term>
<term>Nickel oxides</term>
<term>Orthorhombic lattices</term>
<term>Quadrupolar splitting</term>
<term>Quaternary compounds</term>
<term>Sublattices</term>
<term>Temperature dependence</term>
<term>Thulium oxides</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Ordre magnétique</term>
<term>Champ cristallin</term>
<term>Interaction champ cristallin</term>
<term>Spectrométrie Mössbauer</term>
<term>Interaction hyperfine</term>
<term>Dépendance température</term>
<term>Sous réseau</term>
<term>Décomposition quadripolaire</term>
<term>Interaction échange</term>
<term>Site cristallographique</term>
<term>Réseau orthorhombique</term>
<term>Baryum oxyde</term>
<term>Thulium oxyde</term>
<term>Cobalt oxyde</term>
<term>Nickel oxyde</term>
<term>Etude expérimentale</term>
<term>Composé quaternaire</term>
<term>7525</term>
<term>7680</term>
<term>Tm2BaCoO5</term>
<term>Ba Co O Tm</term>
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<term>Ba Ni O Tm</term>
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<front><div type="abstract" xml:lang="en">The magnetic ordering and crystal field interactions of the Pnma phases of both Tm<sub>2</sub>
BaCoO<sub>5</sub>
 and Tm<sub>2</sub>
BaNiO<sub>5</sub>
 are investigated by <sup>169</sup>
Tm Mössbauer spectroscopy and the temperature-dependent hyperfine interactions are compared with those obtained elsewhere for Tm<sub>2</sub>
BaCuO<sub>5</sub>
. The Pnma phases are shown to order magnetically at temperatures of 3.5(2) K (Tm<sub>2</sub>
BaCoO<sub>5</sub>
) and 4.85(5) K (Tm<sub>2</sub>
BaNiO<sub>5</sub>
), the order being induced by the transition metal. For Tm<sub>2</sub>
BaNiO<sub>5</sub>
 an additional first-order transition observed at T≤1.4 K is identified with the independent magnetic order of the thulium sub-lattice.</div>
</front>
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<fA14 i1="02"><s1>School of Physics, University College. The University of New South Wales, Australian Defence Force Academy</s1>
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<fA66 i1="01"><s0>CHE</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>The magnetic ordering and crystal field interactions of the Pnma phases of both Tm<sub>2</sub>
BaCoO<sub>5</sub>
 and Tm<sub>2</sub>
BaNiO<sub>5</sub>
 are investigated by <sup>169</sup>
Tm Mössbauer spectroscopy and the temperature-dependent hyperfine interactions are compared with those obtained elsewhere for Tm<sub>2</sub>
BaCuO<sub>5</sub>
. The Pnma phases are shown to order magnetically at temperatures of 3.5(2) K (Tm<sub>2</sub>
BaCoO<sub>5</sub>
) and 4.85(5) K (Tm<sub>2</sub>
BaNiO<sub>5</sub>
), the order being induced by the transition metal. For Tm<sub>2</sub>
BaNiO<sub>5</sub>
 an additional first-order transition observed at T≤1.4 K is identified with the independent magnetic order of the thulium sub-lattice.</s0>
</fC01>
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<fC03 i1="01" i2="3" l="FRE"><s0>Ordre magnétique</s0>
<s5>01</s5>
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<fC03 i1="01" i2="3" l="ENG"><s0>Magnetic ordering</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Champ cristallin</s0>
<s5>02</s5>
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<s5>03</s5>
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<s5>04</s5>
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<s5>04</s5>
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<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Hyperfine interactions</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Dépendance température</s0>
<s5>06</s5>
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<fC03 i1="06" i2="3" l="ENG"><s0>Temperature dependence</s0>
<s5>06</s5>
</fC03>
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<s5>07</s5>
</fC03>
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<s5>07</s5>
</fC03>
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<s5>08</s5>
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<s5>08</s5>
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<s5>09</s5>
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<fC03 i1="09" i2="3" l="ENG"><s0>Exchange interactions</s0>
<s5>09</s5>
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<fC03 i1="10" i2="X" l="FRE"><s0>Site cristallographique</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Crystallographic site</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Sitio cristalográfico</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Réseau orthorhombique</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG"><s0>Orthorhombic lattices</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>Baryum oxyde</s0>
<s2>NK</s2>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG"><s0>Barium oxides</s0>
<s2>NK</s2>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Thulium oxyde</s0>
<s2>NK</s2>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG"><s0>Thulium oxides</s0>
<s2>NK</s2>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Cobalt oxyde</s0>
<s2>NK</s2>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG"><s0>Cobalt oxides</s0>
<s2>NK</s2>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>Nickel oxyde</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG"><s0>Nickel oxides</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE"><s0>Composé quaternaire</s0>
<s5>18</s5>
</fC03>
<fC03 i1="17" i2="3" l="ENG"><s0>Quaternary compounds</s0>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE"><s0>7525</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE"><s0>7680</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE"><s0>Tm2BaCoO5</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="21" i2="3" l="FRE"><s0>Ba Co O Tm</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC03 i1="22" i2="3" l="FRE"><s0>Tm2BaNiO5</s0>
<s4>INC</s4>
<s5>94</s5>
</fC03>
<fC03 i1="23" i2="3" l="FRE"><s0>Ba Ni O Tm</s0>
<s4>INC</s4>
<s5>95</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>17</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>17</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>81</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>81</s5>
</fC07>
<fC07 i1="03" i2="3" l="FRE"><s0>Lanthanide composé</s0>
<s5>82</s5>
</fC07>
<fC07 i1="03" i2="3" l="ENG"><s0>Rare earth compounds</s0>
<s5>82</s5>
</fC07>
<fN21><s1>255</s1>
</fN21>
</pA>
</standard>
<server><NO>PASCAL 00-0371646 INIST</NO>
<ET>Magnetic order and crystal fields in the Pnma phases of Tm<sub>2</sub>
BaTO<sub>5</sub>
 (T=Co and Ni)</ET>
<AU>HARKER (S. J.); STEWART (G. A.); GUBBENS (P. C. M.)</AU>
<AF>Interfacultair Reactor Instituut, Delft University of Technology, Mekelweg 15/2629 JB Delft/Pays-Bas (1 aut., 2 aut.); School of Physics, University College. The University of New South Wales, Australian Defence Force Academy/Canberra, ACT 2600/Australie (3 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Journal of alloys and compounds; ISSN 0925-8388; Suisse; Da. 2000; Vol. 307; No. 1-2; Pp. 70-76; Bibl. 20 ref.</SO>
<LA>Anglais</LA>
<EA>The magnetic ordering and crystal field interactions of the Pnma phases of both Tm<sub>2</sub>
BaCoO<sub>5</sub>
 and Tm<sub>2</sub>
BaNiO<sub>5</sub>
 are investigated by <sup>169</sup>
Tm Mössbauer spectroscopy and the temperature-dependent hyperfine interactions are compared with those obtained elsewhere for Tm<sub>2</sub>
BaCuO<sub>5</sub>
. The Pnma phases are shown to order magnetically at temperatures of 3.5(2) K (Tm<sub>2</sub>
BaCoO<sub>5</sub>
) and 4.85(5) K (Tm<sub>2</sub>
BaNiO<sub>5</sub>
), the order being induced by the transition metal. For Tm<sub>2</sub>
BaNiO<sub>5</sub>
 an additional first-order transition observed at T≤1.4 K is identified with the independent magnetic order of the thulium sub-lattice.</EA>
<CC>001B70E25; 001B70F80</CC>
<FD>Ordre magnétique; Champ cristallin; Interaction champ cristallin; Spectrométrie Mössbauer; Interaction hyperfine; Dépendance température; Sous réseau; Décomposition quadripolaire; Interaction échange; Site cristallographique; Réseau orthorhombique; Baryum oxyde; Thulium oxyde; Cobalt oxyde; Nickel oxyde; Etude expérimentale; Composé quaternaire; 7525; 7680; Tm2BaCoO5; Ba Co O Tm; Tm2BaNiO5; Ba Ni O Tm</FD>
<FG>Composé minéral; Métal transition composé; Lanthanide composé</FG>
<ED>Magnetic ordering; Crystal field; Crystal field interactions; Moessbauer spectroscopy; Hyperfine interactions; Temperature dependence; Sublattices; Quadrupolar splitting; Exchange interactions; Crystallographic site; Orthorhombic lattices; Barium oxides; Thulium oxides; Cobalt oxides; Nickel oxides; Experimental study; Quaternary compounds</ED>
<EG>Inorganic compounds; Transition element compounds; Rare earth compounds</EG>
<SD>Descomposición cuadripolar; Sitio cristalográfico</SD>
<LO>INIST-1151.354000090758630110</LO>
<ID>00-0371646</ID>
</server>
</inist>
</record>

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Magnetic order and crystal fields in the Pnma phases of Tm2BaTO5 (T=Co and Ni)

Magnetic order and crystal fields in the Pnma phases of Tm2BaTO5 (T=Co and Ni)

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