Standard enthalpies of formation of some thulium alloys, Tm+Me (Me = Ni, Rh, Pd, Pt), by high temperature direct synthesis calorimetry
Identifieur interne : 002943 ( Main/Exploration ); précédent : 002942; suivant : 002944Standard enthalpies of formation of some thulium alloys, Tm+Me (Me = Ni, Rh, Pd, Pt), by high temperature direct synthesis calorimetry
Auteurs : Qiti Guo [États-Unis, République populaire de Chine] ; Ole Jakob Kleppa [États-Unis]Source :
- Journal of Alloys and Compounds [ 0925-8388 ] ; 1997.
Descripteurs français
- Pascal (Inist)
- 6550, Alliage Ni63Tm37, Alliage Rh55Tm45, Alliage Tm61Pd39, Alliage Tm62Rh38, Alliage base nickel, Alliage base thulium, Alliage binaire, Calorimétrie, Chaleur formation, Composé intermétallique, Enthalpie, Etude expérimentale, Ni Tm, Nickel alliage, Palladium alliage, Pd Tm, Platine alliage, Propriété thermique, Propriété thermodynamique, Rh Tm, Rhodium alliage, Synthèse, Thulium alliage.
- Wicri :
- topic : Alliage.
English descriptors
- KwdEn :
- Alloy, Alloy samples, Binary alloys, Calorimetry, Characteristic valency, Diameter pellets, Direct synthesis calorimetry, Enthalpy, Exothermic character, Experimental results, Experimental study, Formation data, Formation heat, Gdni, Group viii, Intermetallic compounds, Kkppa, Kleppa, Late transition metals, Liquid alloys, Mesh sieve, Nickel alloys, Nickel base alloys, Palladium alloys, Platinum alloys, Platinum powder, Present work, Rhodium alloys, Second phases, Selhaoui, Standard enthalpies, Standard enthalpy, Synthesis, Thermal properties, Thermodynamic properties, Thulium alloys, Thulium base alloys, Tmni, Tmpd, Tmpt, Tmrh.
- Teeft :
- Alloy, Alloy samples, Binary alloys, Calorimetry, Characteristic valency, Diameter pellets, Direct synthesis calorimetry, Enthalpy, Exothermic character, Experimental results, Formation data, Gdni, Group viii, Kkppa, Kleppa, Late transition metals, Liquid alloys, Mesh sieve, Platinum powder, Present work, Second phases, Selhaoui, Standard enthalpies, Standard enthalpy, Thulium alloys, Tmni, Tmpd, Tmpt, Tmrh.
Abstract
Abstract: The standard enthalpies of formation of nine thulium alloys with late transition metals have been determined by direct synthesis calorimetry at 1400±2 K. The following values of ΔH1 (kJ (mol atom)−1) are reported: TmNi5, −29.1±0.7; TmRh, −88.9±2.0; TmRh2, −73.0±2.0; TmPd, −92.6±2.0; Tm3Pd4, −93.0±1.7; TmPd3, −86.8±1.6; TmPt, −121.0±2.0; TmPt2, −112.4±3.1; TmPt3, −91.1±2.1. The results are compared with predicted values from the Miedema model and with available literature data for tmPd and TmPt.
Url:
DOI: 10.1016/S0925-8388(96)02401-2
Affiliations:
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Le document en format XML
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<term>Characteristic valency</term>
<term>Diameter pellets</term>
<term>Direct synthesis calorimetry</term>
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<term>Exothermic character</term>
<term>Experimental results</term>
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<term>Platine alliage</term>
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<term>Propriété thermodynamique</term>
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<term>Group viii</term>
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<front><div type="abstract" xml:lang="en">Abstract: The standard enthalpies of formation of nine thulium alloys with late transition metals have been determined by direct synthesis calorimetry at 1400±2 K. The following values of ΔH1 (kJ (mol atom)−1) are reported: TmNi5, −29.1±0.7; TmRh, −88.9±2.0; TmRh2, −73.0±2.0; TmPd, −92.6±2.0; Tm3Pd4, −93.0±1.7; TmPd3, −86.8±1.6; TmPt, −121.0±2.0; TmPt2, −112.4±3.1; TmPt3, −91.1±2.1. The results are compared with predicted values from the Miedema model and with available literature data for tmPd and TmPt.</div>
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