Standard enthalpies of formation of some thulium alloys, Tm+Me (Me = Ni, Rh, Pd, Pt), by high temperature direct synthesis calorimetry
Identifieur interne : 001E41 ( Istex/Curation ); précédent : 001E40; suivant : 001E42Standard enthalpies of formation of some thulium alloys, Tm+Me (Me = Ni, Rh, Pd, Pt), by high temperature direct synthesis calorimetry
Auteurs : Qiti Guo [États-Unis, République populaire de Chine] ; Ole Jakob Kleppa [États-Unis]Source :
- Journal of Alloys and Compounds [ 0925-8388 ] ; 1997.
Descripteurs français
- Wicri :
- topic : Alliage.
English descriptors
- KwdEn :
- Alloy, Alloy samples, Binary alloys, Calorimetry, Characteristic valency, Diameter pellets, Direct synthesis calorimetry, Enthalpy, Exothermic character, Experimental results, Formation data, Gdni, Group viii, Kkppa, Kleppa, Late transition metals, Liquid alloys, Mesh sieve, Platinum powder, Present work, Second phases, Selhaoui, Standard enthalpies, Standard enthalpy, Thulium alloys, Tmni, Tmpd, Tmpt, Tmrh.
- Teeft :
- Alloy, Alloy samples, Binary alloys, Calorimetry, Characteristic valency, Diameter pellets, Direct synthesis calorimetry, Enthalpy, Exothermic character, Experimental results, Formation data, Gdni, Group viii, Kkppa, Kleppa, Late transition metals, Liquid alloys, Mesh sieve, Platinum powder, Present work, Second phases, Selhaoui, Standard enthalpies, Standard enthalpy, Thulium alloys, Tmni, Tmpd, Tmpt, Tmrh.
Abstract
Abstract: The standard enthalpies of formation of nine thulium alloys with late transition metals have been determined by direct synthesis calorimetry at 1400±2 K. The following values of ΔH1 (kJ (mol atom)−1) are reported: TmNi5, −29.1±0.7; TmRh, −88.9±2.0; TmRh2, −73.0±2.0; TmPd, −92.6±2.0; Tm3Pd4, −93.0±1.7; TmPd3, −86.8±1.6; TmPt, −121.0±2.0; TmPt2, −112.4±3.1; TmPt3, −91.1±2.1. The results are compared with predicted values from the Miedema model and with available literature data for tmPd and TmPt.
Url:
DOI: 10.1016/S0925-8388(96)02401-2
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<front><div type="abstract" xml:lang="en">Abstract: The standard enthalpies of formation of nine thulium alloys with late transition metals have been determined by direct synthesis calorimetry at 1400±2 K. The following values of ΔH1 (kJ (mol atom)−1) are reported: TmNi5, −29.1±0.7; TmRh, −88.9±2.0; TmRh2, −73.0±2.0; TmPd, −92.6±2.0; Tm3Pd4, −93.0±1.7; TmPd3, −86.8±1.6; TmPt, −121.0±2.0; TmPt2, −112.4±3.1; TmPt3, −91.1±2.1. The results are compared with predicted values from the Miedema model and with available literature data for tmPd and TmPt.</div>
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