ThuliumV1, Main, Exploration, bibRecordById, Pascal:01-0171193

Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization

Identifieur interne : 002092 ( Main/Exploration ); précédent : 002091; suivant : 002093

Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization

Auteurs : Evgueni N. Kirillov [Russie] ; Elena A. Fedorova [Russie] ; Alexander A. Trifonov [Russie] ; Mikhail N. Bochkarev [Russie]

Source :

Applied Organometallic Chemistry [ 0268-2605 ] ; 2001-03.

RBID : ISTEX:27664CF9DA03A84681335BB13BC7152EC6D625B3

Descripteurs français

Pascal (Inist)
- Activité catalytique, Catalyseur complexe, Coordinat organique, Etude expérimentale, Lanthanide Complexe, Polymérisation catalyseur complexe, Polymérisation masse, Polymérisation solution, Propène polymère, Styrène polymère, Taux conversion.
Wicri :
- topic : Droit d'auteur, Méthanol, Polymère.

English descriptors

KwdEn :
- Acad, Amide, Appl, Bochkarev, Bulk polymerization, Catalyst activity, Catalytic activity, Chem, Complex catalyst, Complex catalyst polymerization, Conversion rate, Copyright, Derivative, Divalent, Europium, Experimental study, Fedorova, Hydride, John wiley sons, Kirillov, Lanthanide Complexes, Lanthanoid, Methanol, Molecular hydrides, Molecular weights, Naphthalene, Nauk, Organic ligand, Organolanthanoid, Organolanthanoid derivatives, Organolanthanoids, Organomet, Organometal, Organometallic, Organometallic chemistry, Organometallics, Polymer, Propene, Propene polymerization, Propylene polymer, Room temperature, Samarium, Schumann, Solution polymerization, Stilbene, Stilbene complexes, Styrene polymer, Styrene polymerization, Toluene, Trifonov, Ytterbium, Zakharov.
Teeft :
- Acad, Amide, Appl, Bochkarev, Catalytic activity, Chem, Copyright, Derivative, Divalent, Europium, Fedorova, Hydride, John wiley sons, Kirillov, Lanthanoid, Methanol, Molecular hydrides, Molecular weights, Naphthalene, Nauk, Organolanthanoid, Organolanthanoid derivatives, Organolanthanoids, Organomet, Organometal, Organometallic, Organometallic chemistry, Organometallics, Polymer, Propene, Propene polymerization, Room temperature, Samarium, Schumann, Stilbene, Stilbene complexes, Styrene polymerization, Toluene, Trifonov, Ytterbium, Zakharov.

Abstract

Organolanthanoids of several classes were examined as potential styrene and propene polymerization catalysts. They are: molecular hydrides of divalent lanthanoids (samarium, europium, ytterbium); naphthalene and stilbene complexes of neodymium(III), samarium(II), europium(II), ytterbium(II), lutetium(III); amides and alkoxides (including heterobifunctional derivatives) of praseodymium(III), neodymium(III), samarium(II), europium(II), thulium(III), ytterbium(II, III); thiolate of samarium(III); phenyl and phenylethinyl derivatives of europium(II), thulium(III), ytterbium(II); methylytterbium cluster Yb8 (μ‐CH3)14(μ‐CH2)(THF)6; heterobimetallic samarium(II), ytterbium(II, III) complexes; diazabutadiene ytterbium(III) derivatives; metallic praseodymium and ytterbium, activated by iodine. The highest activity in styrene polymerization revealed hydrides, naphthalene and stilbene complexes of samarium(II), europium(II) and ytterbium(II). In the propene polymerization only [(η5‐C5H4)CH2CH(CH2OBu)(η1‐O)]YbMe(THF) displayed noticeable activity.Copyright © 2001 John Wiley & Sons, Ltd.

Url:

https://api.istex.fr/document/27664CF9DA03A84681335BB13BC7152EC6D625B3/fulltext/pdf

DOI: 10.1002/aoc.123

Affiliations:

Russie

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<term>Amide</term>
<term>Appl</term>
<term>Bochkarev</term>
<term>Bulk polymerization</term>
<term>Catalyst activity</term>
<term>Catalytic activity</term>
<term>Chem</term>
<term>Complex catalyst</term>
<term>Complex catalyst polymerization</term>
<term>Conversion rate</term>
<term>Copyright</term>
<term>Derivative</term>
<term>Divalent</term>
<term>Europium</term>
<term>Experimental study</term>
<term>Fedorova</term>
<term>Hydride</term>
<term>John wiley sons</term>
<term>Kirillov</term>
<term>Lanthanide Complexes</term>
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<term>Methanol</term>
<term>Molecular hydrides</term>
<term>Molecular weights</term>
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<term>Nauk</term>
<term>Organic ligand</term>
<term>Organolanthanoid</term>
<term>Organolanthanoid derivatives</term>
<term>Organolanthanoids</term>
<term>Organomet</term>
<term>Organometal</term>
<term>Organometallic</term>
<term>Organometallic chemistry</term>
<term>Organometallics</term>
<term>Polymer</term>
<term>Propene</term>
<term>Propene polymerization</term>
<term>Propylene polymer</term>
<term>Room temperature</term>
<term>Samarium</term>
<term>Schumann</term>
<term>Solution polymerization</term>
<term>Stilbene</term>
<term>Stilbene complexes</term>
<term>Styrene polymer</term>
<term>Styrene polymerization</term>
<term>Toluene</term>
<term>Trifonov</term>
<term>Ytterbium</term>
<term>Zakharov</term>
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<term>Lanthanide Complexe</term>
<term>Polymérisation catalyseur complexe</term>
<term>Polymérisation masse</term>
<term>Polymérisation solution</term>
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<term>Catalytic activity</term>
<term>Chem</term>
<term>Copyright</term>
<term>Derivative</term>
<term>Divalent</term>
<term>Europium</term>
<term>Fedorova</term>
<term>Hydride</term>
<term>John wiley sons</term>
<term>Kirillov</term>
<term>Lanthanoid</term>
<term>Methanol</term>
<term>Molecular hydrides</term>
<term>Molecular weights</term>
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<term>Nauk</term>
<term>Organolanthanoid</term>
<term>Organolanthanoid derivatives</term>
<term>Organolanthanoids</term>
<term>Organomet</term>
<term>Organometal</term>
<term>Organometallic</term>
<term>Organometallic chemistry</term>
<term>Organometallics</term>
<term>Polymer</term>
<term>Propene</term>
<term>Propene polymerization</term>
<term>Room temperature</term>
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<term>Trifonov</term>
<term>Ytterbium</term>
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<front><div type="abstract" xml:lang="en">Organolanthanoids of several classes were examined as potential styrene and propene polymerization catalysts. They are: molecular hydrides of divalent lanthanoids (samarium, europium, ytterbium); naphthalene and stilbene complexes of neodymium(III), samarium(II), europium(II), ytterbium(II), lutetium(III); amides and alkoxides (including heterobifunctional derivatives) of praseodymium(III), neodymium(III), samarium(II), europium(II), thulium(III), ytterbium(II, III); thiolate of samarium(III); phenyl and phenylethinyl derivatives of europium(II), thulium(III), ytterbium(II); methylytterbium cluster Yb8 (μ‐CH3)14(μ‐CH2)(THF)6; heterobimetallic samarium(II), ytterbium(II, III) complexes; diazabutadiene ytterbium(III) derivatives; metallic praseodymium and ytterbium, activated by iodine. The highest activity in styrene polymerization revealed hydrides, naphthalene and stilbene complexes of samarium(II), europium(II) and ytterbium(II). In the propene polymerization only [(η5‐C5H4)CH2CH(CH2OBu)(η1‐O)]YbMe(THF) displayed noticeable activity.Copyright © 2001 John Wiley & Sons, Ltd.</div>
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Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization

Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization

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Descripteurs français

English descriptors

Abstract

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