Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization
Identifieur interne : 000E44 ( Pascal/Corpus ); précédent : 000E43; suivant : 000E45Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization
Auteurs : Evgueni N. Kirillov ; Elena A. Fedorova ; Alexander A. Trifonov ; Mikhail N. BochkarevSource :
- Applied organometallic chemistry [ 0268-2605 ] ; 2001.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
Organolanthanoids of several classes were examined as potential styrene and propene polymerization catalysts. They are: molecular hydrides of divalent lanthanoids (samarium, europium, ytterbium); naphthalene and stilbene complexes of neodymium(III), samarium(II), europium(II), ytterbium(II), lutetium(III); amides and alkoxides (including heterobifunctional derivatives) of praseodymium(III), neodymium(III), samarium(II), europium(II), thulium(III), ytterbium(II, III); thiolate of samarium(III); phenyl and phenylethinyl derivatives of europium(II), thulium(III), ytterbium(II); methylytterbium cluster Yb8 (μ-CH3)14(μ-CH2)(THF)6; heterobimetallic samarium(II), ytterbium(II, III) complexes; diazabutadiene ytterbium(III) derivatives; metallic praseodymium and ytterbium, activated by iodine. The highest activity in styrene polymerization revealed hydrides, naphthalene and stilbene complexes of samarium(II), europium(II) and ytterbium(II). In the propene polymerization only [(η5-C5H4)CH2CH (CH2OBu)(η1-O)]YbMe(THF) displayed noticeable activity.
Notice en format standard (ISO 2709)
Pour connaître la documentation sur le format Inist Standard.
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Format Inist (serveur)
NO : | PASCAL 01-0171193 INIST |
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ET : | Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization |
AU : | KIRILLOV (Evgueni N.); FEDOROVA (Elena A.); TRIFONOV (Alexander A.); BOCHKAREV (Mikhail N.) |
AF : | G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, ul. Tropinina 49/603600 Nizhny Novgorod/Russie (1 aut., 2 aut., 3 aut., 4 aut.) |
DT : | Publication en série; Niveau analytique |
SO : | Applied organometallic chemistry; ISSN 0268-2605; Coden AOCHEX; Royaume-Uni; Da. 2001; Vol. 15; No. 3; Pp. 151-156; Bibl. 21 ref. |
LA : | Anglais |
EA : | Organolanthanoids of several classes were examined as potential styrene and propene polymerization catalysts. They are: molecular hydrides of divalent lanthanoids (samarium, europium, ytterbium); naphthalene and stilbene complexes of neodymium(III), samarium(II), europium(II), ytterbium(II), lutetium(III); amides and alkoxides (including heterobifunctional derivatives) of praseodymium(III), neodymium(III), samarium(II), europium(II), thulium(III), ytterbium(II, III); thiolate of samarium(III); phenyl and phenylethinyl derivatives of europium(II), thulium(III), ytterbium(II); methylytterbium cluster Yb8 (μ-CH3)14(μ-CH2)(THF)6; heterobimetallic samarium(II), ytterbium(II, III) complexes; diazabutadiene ytterbium(III) derivatives; metallic praseodymium and ytterbium, activated by iodine. The highest activity in styrene polymerization revealed hydrides, naphthalene and stilbene complexes of samarium(II), europium(II) and ytterbium(II). In the propene polymerization only [(η5-C5H4)CH2CH (CH2OBu)(η1-O)]YbMe( THF) displayed noticeable activity. |
CC : | 001D09D02B |
FD : | Catalyseur complexe; Lanthanide Complexe; Coordinat organique; Activité catalytique; Polymérisation catalyseur complexe; Polymérisation masse; Polymérisation solution; Styrène polymère; Propène polymère; Taux conversion; Etude expérimentale |
ED : | Complex catalyst; Lanthanide Complexes; Organic ligand; Catalyst activity; Complex catalyst polymerization; Bulk polymerization; Solution polymerization; Styrene polymer; Propylene polymer; Conversion rate; Experimental study |
SD : | Catalizador complejo; Lantánido Complejo; Ligando orgánico; Actividad catalítica; Polimerización catalizador complejo; Polimerización masa; Polimerización solución; Estireno polímero; Propeno polímero; Factor conversión; Estudio experimental |
LO : | INIST-21323.354000094966060010 |
ID : | 01-0171193 |
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Pascal:01-0171193Le document en format XML
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<term>Catalyst activity</term>
<term>Complex catalyst</term>
<term>Complex catalyst polymerization</term>
<term>Conversion rate</term>
<term>Experimental study</term>
<term>Lanthanide Complexes</term>
<term>Organic ligand</term>
<term>Propylene polymer</term>
<term>Solution polymerization</term>
<term>Styrene polymer</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Catalyseur complexe</term>
<term>Lanthanide Complexe</term>
<term>Coordinat organique</term>
<term>Activité catalytique</term>
<term>Polymérisation catalyseur complexe</term>
<term>Polymérisation masse</term>
<term>Polymérisation solution</term>
<term>Styrène polymère</term>
<term>Propène polymère</term>
<term>Taux conversion</term>
<term>Etude expérimentale</term>
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<front><div type="abstract" xml:lang="en">Organolanthanoids of several classes were examined as potential styrene and propene polymerization catalysts. They are: molecular hydrides of divalent lanthanoids (samarium, europium, ytterbium); naphthalene and stilbene complexes of neodymium(III), samarium(II), europium(II), ytterbium(II), lutetium(III); amides and alkoxides (including heterobifunctional derivatives) of praseodymium(III), neodymium(III), samarium(II), europium(II), thulium(III), ytterbium(II, III); thiolate of samarium(III); phenyl and phenylethinyl derivatives of europium(II), thulium(III), ytterbium(II); methylytterbium cluster Yb<sub>8</sub>
(μ-CH<sub>3</sub>
)<sub>14</sub>
(μ-CH<sub>2</sub>
)(THF)<sub>6</sub>
; heterobimetallic samarium(II), ytterbium(II, III) complexes; diazabutadiene ytterbium(III) derivatives; metallic praseodymium and ytterbium, activated by iodine. The highest activity in styrene polymerization revealed hydrides, naphthalene and stilbene complexes of samarium(II), europium(II) and ytterbium(II). In the propene polymerization only [(η<sup>5</sup>
-C<sub>5</sub>
H<sub>4</sub>
)CH<sub>2</sub>
CH (CH<sub>2</sub>
OBu)(η<sup>1</sup>
-O)]YbMe(THF) displayed noticeable activity.</div>
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<fC01 i1="01" l="ENG"><s0>Organolanthanoids of several classes were examined as potential styrene and propene polymerization catalysts. They are: molecular hydrides of divalent lanthanoids (samarium, europium, ytterbium); naphthalene and stilbene complexes of neodymium(III), samarium(II), europium(II), ytterbium(II), lutetium(III); amides and alkoxides (including heterobifunctional derivatives) of praseodymium(III), neodymium(III), samarium(II), europium(II), thulium(III), ytterbium(II, III); thiolate of samarium(III); phenyl and phenylethinyl derivatives of europium(II), thulium(III), ytterbium(II); methylytterbium cluster Yb<sub>8</sub>
(μ-CH<sub>3</sub>
)<sub>14</sub>
(μ-CH<sub>2</sub>
)(THF)<sub>6</sub>
; heterobimetallic samarium(II), ytterbium(II, III) complexes; diazabutadiene ytterbium(III) derivatives; metallic praseodymium and ytterbium, activated by iodine. The highest activity in styrene polymerization revealed hydrides, naphthalene and stilbene complexes of samarium(II), europium(II) and ytterbium(II). In the propene polymerization only [(η<sup>5</sup>
-C<sub>5</sub>
H<sub>4</sub>
)CH<sub>2</sub>
CH (CH<sub>2</sub>
OBu)(η<sup>1</sup>
-O)]YbMe(THF) displayed noticeable activity.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001D09D02B</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Catalyseur complexe</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Complex catalyst</s0>
<s5>01</s5>
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<s5>01</s5>
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<fC03 i1="02" i2="X" l="FRE"><s0>Lanthanide Complexe</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>02</s5>
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<fC03 i1="02" i2="X" l="ENG"><s0>Lanthanide Complexes</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>02</s5>
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<fC03 i1="02" i2="X" l="SPA"><s0>Lantánido Complejo</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>02</s5>
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<fC03 i1="03" i2="X" l="FRE"><s0>Coordinat organique</s0>
<s5>03</s5>
</fC03>
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<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Ligando orgánico</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Activité catalytique</s0>
<s5>04</s5>
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<s5>04</s5>
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<fC03 i1="04" i2="X" l="SPA"><s0>Actividad catalítica</s0>
<s5>04</s5>
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<fC03 i1="05" i2="X" l="FRE"><s0>Polymérisation catalyseur complexe</s0>
<s5>05</s5>
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<fC03 i1="05" i2="X" l="ENG"><s0>Complex catalyst polymerization</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Polimerización catalizador complejo</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Polymérisation masse</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Bulk polymerization</s0>
<s5>06</s5>
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<s5>06</s5>
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<s5>07</s5>
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<fC03 i1="07" i2="X" l="ENG"><s0>Solution polymerization</s0>
<s5>07</s5>
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<s5>07</s5>
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<s2>NK</s2>
<s5>08</s5>
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<s2>NK</s2>
<s5>08</s5>
</fC03>
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<s2>NK</s2>
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<s2>NK</s2>
<s5>09</s5>
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<s2>NK</s2>
<s5>09</s5>
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<fC03 i1="09" i2="X" l="SPA"><s0>Propeno polímero</s0>
<s2>NK</s2>
<s5>09</s5>
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<s5>10</s5>
</fC03>
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<s5>10</s5>
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<s5>10</s5>
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<server><NO>PASCAL 01-0171193 INIST</NO>
<ET>Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization</ET>
<AU>KIRILLOV (Evgueni N.); FEDOROVA (Elena A.); TRIFONOV (Alexander A.); BOCHKAREV (Mikhail N.)</AU>
<AF>G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, ul. Tropinina 49/603600 Nizhny Novgorod/Russie (1 aut., 2 aut., 3 aut., 4 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Applied organometallic chemistry; ISSN 0268-2605; Coden AOCHEX; Royaume-Uni; Da. 2001; Vol. 15; No. 3; Pp. 151-156; Bibl. 21 ref.</SO>
<LA>Anglais</LA>
<EA>Organolanthanoids of several classes were examined as potential styrene and propene polymerization catalysts. They are: molecular hydrides of divalent lanthanoids (samarium, europium, ytterbium); naphthalene and stilbene complexes of neodymium(III), samarium(II), europium(II), ytterbium(II), lutetium(III); amides and alkoxides (including heterobifunctional derivatives) of praseodymium(III), neodymium(III), samarium(II), europium(II), thulium(III), ytterbium(II, III); thiolate of samarium(III); phenyl and phenylethinyl derivatives of europium(II), thulium(III), ytterbium(II); methylytterbium cluster Yb<sub>8</sub>
(μ-CH<sub>3</sub>
)<sub>14</sub>
(μ-CH<sub>2</sub>
)(THF)<sub>6</sub>
; heterobimetallic samarium(II), ytterbium(II, III) complexes; diazabutadiene ytterbium(III) derivatives; metallic praseodymium and ytterbium, activated by iodine. The highest activity in styrene polymerization revealed hydrides, naphthalene and stilbene complexes of samarium(II), europium(II) and ytterbium(II). In the propene polymerization only [(η<sup>5</sup>
-C<sub>5</sub>
H<sub>4</sub>
)CH<sub>2</sub>
CH (CH<sub>2</sub>
OBu)(η<sup>1</sup>
-O)]YbMe( THF) displayed noticeable activity.</EA>
<CC>001D09D02B</CC>
<FD>Catalyseur complexe; Lanthanide Complexe; Coordinat organique; Activité catalytique; Polymérisation catalyseur complexe; Polymérisation masse; Polymérisation solution; Styrène polymère; Propène polymère; Taux conversion; Etude expérimentale</FD>
<ED>Complex catalyst; Lanthanide Complexes; Organic ligand; Catalyst activity; Complex catalyst polymerization; Bulk polymerization; Solution polymerization; Styrene polymer; Propylene polymer; Conversion rate; Experimental study</ED>
<SD>Catalizador complejo; Lantánido Complejo; Ligando orgánico; Actividad catalítica; Polimerización catalizador complejo; Polimerización masa; Polimerización solución; Estireno polímero; Propeno polímero; Factor conversión; Estudio experimental</SD>
<LO>INIST-21323.354000094966060010</LO>
<ID>01-0171193</ID>
</server>
</inist>
</record>
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