ThuliumV1, Pascal, Corpus, bibRecord, 000E44

Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization

Identifieur interne : 000E44 ( Pascal/Corpus ); précédent : 000E43; suivant : 000E45

Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization

Auteurs : Evgueni N. Kirillov ; Elena A. Fedorova ; Alexander A. Trifonov ; Mikhail N. Bochkarev

Source :

Applied organometallic chemistry [ 0268-2605 ] ; 2001.

RBID : Pascal:01-0171193

Descripteurs français

Pascal (Inist)
- Catalyseur complexe, Lanthanide Complexe, Coordinat organique, Activité catalytique, Polymérisation catalyseur complexe, Polymérisation masse, Polymérisation solution, Styrène polymère, Propène polymère, Taux conversion, Etude expérimentale.

English descriptors

KwdEn :
- Bulk polymerization, Catalyst activity, Complex catalyst, Complex catalyst polymerization, Conversion rate, Experimental study, Lanthanide Complexes, Organic ligand, Propylene polymer, Solution polymerization, Styrene polymer.

Abstract

Organolanthanoids of several classes were examined as potential styrene and propene polymerization catalysts. They are: molecular hydrides of divalent lanthanoids (samarium, europium, ytterbium); naphthalene and stilbene complexes of neodymium(III), samarium(II), europium(II), ytterbium(II), lutetium(III); amides and alkoxides (including heterobifunctional derivatives) of praseodymium(III), neodymium(III), samarium(II), europium(II), thulium(III), ytterbium(II, III); thiolate of samarium(III); phenyl and phenylethinyl derivatives of europium(II), thulium(III), ytterbium(II); methylytterbium cluster Yb₈ (μ-CH₃)₁₄(μ-CH₂)(THF)₆; heterobimetallic samarium(II), ytterbium(II, III) complexes; diazabutadiene ytterbium(III) derivatives; metallic praseodymium and ytterbium, activated by iodine. The highest activity in styrene polymerization revealed hydrides, naphthalene and stilbene complexes of samarium(II), europium(II) and ytterbium(II). In the propene polymerization only [(η⁵-C₅H₄)CH₂CH (CH₂OBu)(η¹-O)]YbMe(THF) displayed noticeable activity.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 0268-2605`
A02	`01`			`@0 AOCHEX`
A03		`1`		`@0 Appl. organomet. chem.`
A05				`@2 15`
A06				`@2 3`
A08	`01`	`1`	`ENG`	`@1 Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization`
A11	`01`	`1`		`@1 KIRILLOV (Evgueni N.)`
A11	`02`	`1`		`@1 FEDOROVA (Elena A.)`
A11	`03`	`1`		`@1 TRIFONOV (Alexander A.)`
A11	`04`	`1`		`@1 BOCHKAREV (Mikhail N.)`
A14	`01`			`@1 G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, ul. Tropinina 49 @2 603600 Nizhny Novgorod @3 RUS @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 4 aut.`
A20				`@1 151-156`
A21				`@1 2001`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 21323 @5 354000094966060010`
A44				`@0 0000 @1 © 2001 INIST-CNRS. All rights reserved.`
A45				`@0 21 ref.`
A47	`01`	`1`		`@0 01-0171193`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Applied organometallic chemistry`
A66	`01`			`@0 GBR`
C01	`01`		`ENG`	@0 Organolanthanoids of several classes were examined as potential styrene and propene polymerization catalysts. They are: molecular hydrides of divalent lanthanoids (samarium, europium, ytterbium); naphthalene and stilbene complexes of neodymium(III), samarium(II), europium(II), ytterbium(II), lutetium(III); amides and alkoxides (including heterobifunctional derivatives) of praseodymium(III), neodymium(III), samarium(II), europium(II), thulium(III), ytterbium(II, III); thiolate of samarium(III); phenyl and phenylethinyl derivatives of europium(II), thulium(III), ytterbium(II); methylytterbium cluster Yb₈ (μ-CH₃)₁₄(μ-CH₂)(THF)₆; heterobimetallic samarium(II), ytterbium(II, III) complexes; diazabutadiene ytterbium(III) derivatives; metallic praseodymium and ytterbium, activated by iodine. The highest activity in styrene polymerization revealed hydrides, naphthalene and stilbene complexes of samarium(II), europium(II) and ytterbium(II). In the propene polymerization only [(η⁵-C₅H₄)CH₂CH (CH₂OBu)(η¹-O)]YbMe(THF) displayed noticeable activity.
C02	`01`	`X`		`@0 001D09D02B`
C03	`01`	`X`	`FRE`	`@0 Catalyseur complexe @5 01`
C03	`01`	`X`	`ENG`	`@0 Complex catalyst @5 01`
C03	`01`	`X`	`SPA`	`@0 Catalizador complejo @5 01`
C03	`02`	`X`	`FRE`	`@0 Lanthanide Complexe @1 ACT @2 NC @2 NA @5 02`
C03	`02`	`X`	`ENG`	`@0 Lanthanide Complexes @1 ACT @2 NC @2 NA @5 02`
C03	`02`	`X`	`SPA`	`@0 Lantánido Complejo @1 ACT @2 NC @2 NA @5 02`
C03	`03`	`X`	`FRE`	`@0 Coordinat organique @5 03`
C03	`03`	`X`	`ENG`	`@0 Organic ligand @5 03`
C03	`03`	`X`	`SPA`	`@0 Ligando orgánico @5 03`
C03	`04`	`X`	`FRE`	`@0 Activité catalytique @5 04`
C03	`04`	`X`	`ENG`	`@0 Catalyst activity @5 04`
C03	`04`	`X`	`SPA`	`@0 Actividad catalítica @5 04`
C03	`05`	`X`	`FRE`	`@0 Polymérisation catalyseur complexe @5 05`
C03	`05`	`X`	`ENG`	`@0 Complex catalyst polymerization @5 05`
C03	`05`	`X`	`SPA`	`@0 Polimerización catalizador complejo @5 05`
C03	`06`	`X`	`FRE`	`@0 Polymérisation masse @5 06`
C03	`06`	`X`	`ENG`	`@0 Bulk polymerization @5 06`
C03	`06`	`X`	`SPA`	`@0 Polimerización masa @5 06`
C03	`07`	`X`	`FRE`	`@0 Polymérisation solution @5 07`
C03	`07`	`X`	`ENG`	`@0 Solution polymerization @5 07`
C03	`07`	`X`	`SPA`	`@0 Polimerización solución @5 07`
C03	`08`	`X`	`FRE`	`@0 Styrène polymère @2 NK @5 08`
C03	`08`	`X`	`ENG`	`@0 Styrene polymer @2 NK @5 08`
C03	`08`	`X`	`SPA`	`@0 Estireno polímero @2 NK @5 08`
C03	`09`	`X`	`FRE`	`@0 Propène polymère @2 NK @5 09`
C03	`09`	`X`	`ENG`	`@0 Propylene polymer @2 NK @5 09`
C03	`09`	`X`	`SPA`	`@0 Propeno polímero @2 NK @5 09`
C03	`10`	`X`	`FRE`	`@0 Taux conversion @5 10`
C03	`10`	`X`	`ENG`	`@0 Conversion rate @5 10`
C03	`10`	`X`	`SPA`	`@0 Factor conversión @5 10`
C03	`11`	`X`	`FRE`	`@0 Etude expérimentale @5 11`
C03	`11`	`X`	`ENG`	`@0 Experimental study @5 11`
C03	`11`	`X`	`SPA`	`@0 Estudio experimental @5 11`
N21				`@1 113`

Format Inist (serveur)

NO :	PASCAL 01-0171193 INIST
ET :	Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization
AU :	KIRILLOV (Evgueni N.); FEDOROVA (Elena A.); TRIFONOV (Alexander A.); BOCHKAREV (Mikhail N.)
AF :	G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, ul. Tropinina 49/603600 Nizhny Novgorod/Russie (1 aut., 2 aut., 3 aut., 4 aut.)
DT :	Publication en série; Niveau analytique
SO :	Applied organometallic chemistry; ISSN 0268-2605; Coden AOCHEX; Royaume-Uni; Da. 2001; Vol. 15; No. 3; Pp. 151-156; Bibl. 21 ref.
LA :	Anglais
EA :	Organolanthanoids of several classes were examined as potential styrene and propene polymerization catalysts. They are: molecular hydrides of divalent lanthanoids (samarium, europium, ytterbium); naphthalene and stilbene complexes of neodymium(III), samarium(II), europium(II), ytterbium(II), lutetium(III); amides and alkoxides (including heterobifunctional derivatives) of praseodymium(III), neodymium(III), samarium(II), europium(II), thulium(III), ytterbium(II, III); thiolate of samarium(III); phenyl and phenylethinyl derivatives of europium(II), thulium(III), ytterbium(II); methylytterbium cluster Yb₈ (μ-CH₃)₁₄(μ-CH₂)(THF)₆; heterobimetallic samarium(II), ytterbium(II, III) complexes; diazabutadiene ytterbium(III) derivatives; metallic praseodymium and ytterbium, activated by iodine. The highest activity in styrene polymerization revealed hydrides, naphthalene and stilbene complexes of samarium(II), europium(II) and ytterbium(II). In the propene polymerization only [(η⁵-C₅H₄)CH₂CH (CH₂OBu)(η¹-O)]YbMe( THF) displayed noticeable activity.
CC :	001D09D02B
FD :	Catalyseur complexe; Lanthanide Complexe; Coordinat organique; Activité catalytique; Polymérisation catalyseur complexe; Polymérisation masse; Polymérisation solution; Styrène polymère; Propène polymère; Taux conversion; Etude expérimentale
ED :	Complex catalyst; Lanthanide Complexes; Organic ligand; Catalyst activity; Complex catalyst polymerization; Bulk polymerization; Solution polymerization; Styrene polymer; Propylene polymer; Conversion rate; Experimental study
SD :	Catalizador complejo; Lantánido Complejo; Ligando orgánico; Actividad catalítica; Polimerización catalizador complejo; Polimerización masa; Polimerización solución; Estireno polímero; Propeno polímero; Factor conversión; Estudio experimental
LO :	INIST-21323.354000094966060010
ID :	01-0171193

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Pascal:01-0171193

Le document en format XML

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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bulk polymerization</term>
<term>Catalyst activity</term>
<term>Complex catalyst</term>
<term>Complex catalyst polymerization</term>
<term>Conversion rate</term>
<term>Experimental study</term>
<term>Lanthanide Complexes</term>
<term>Organic ligand</term>
<term>Propylene polymer</term>
<term>Solution polymerization</term>
<term>Styrene polymer</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Catalyseur complexe</term>
<term>Lanthanide Complexe</term>
<term>Coordinat organique</term>
<term>Activité catalytique</term>
<term>Polymérisation catalyseur complexe</term>
<term>Polymérisation masse</term>
<term>Polymérisation solution</term>
<term>Styrène polymère</term>
<term>Propène polymère</term>
<term>Taux conversion</term>
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<front><div type="abstract" xml:lang="en">Organolanthanoids of several classes were examined as potential styrene and propene polymerization catalysts. They are: molecular hydrides of divalent lanthanoids (samarium, europium, ytterbium); naphthalene and stilbene complexes of neodymium(III), samarium(II), europium(II), ytterbium(II), lutetium(III); amides and alkoxides (including heterobifunctional derivatives) of praseodymium(III), neodymium(III), samarium(II), europium(II), thulium(III), ytterbium(II, III); thiolate of samarium(III); phenyl and phenylethinyl derivatives of europium(II), thulium(III), ytterbium(II); methylytterbium cluster Yb<sub>8</sub>
 (μ-CH<sub>3</sub>
)<sub>14</sub>
(μ-CH<sub>2</sub>
)(THF)<sub>6</sub>
; heterobimetallic samarium(II), ytterbium(II, III) complexes; diazabutadiene ytterbium(III) derivatives; metallic praseodymium and ytterbium, activated by iodine. The highest activity in styrene polymerization revealed hydrides, naphthalene and stilbene complexes of samarium(II), europium(II) and ytterbium(II). In the propene polymerization only [(η<sup>5</sup>
-C<sub>5</sub>
H<sub>4</sub>
)CH<sub>2</sub>
CH (CH<sub>2</sub>
OBu)(η<sup>1</sup>
-O)]YbMe(THF) displayed noticeable activity.</div>
</front>
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<fA11 i1="01" i2="1"><s1>KIRILLOV (Evgueni N.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>FEDOROVA (Elena A.)</s1>
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<fA11 i1="03" i2="1"><s1>TRIFONOV (Alexander A.)</s1>
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<fA11 i1="04" i2="1"><s1>BOCHKAREV (Mikhail N.)</s1>
</fA11>
<fA14 i1="01"><s1>G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, ul. Tropinina 49</s1>
<s2>603600 Nizhny Novgorod</s2>
<s3>RUS</s3>
<sZ>1 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>Organolanthanoids of several classes were examined as potential styrene and propene polymerization catalysts. They are: molecular hydrides of divalent lanthanoids (samarium, europium, ytterbium); naphthalene and stilbene complexes of neodymium(III), samarium(II), europium(II), ytterbium(II), lutetium(III); amides and alkoxides (including heterobifunctional derivatives) of praseodymium(III), neodymium(III), samarium(II), europium(II), thulium(III), ytterbium(II, III); thiolate of samarium(III); phenyl and phenylethinyl derivatives of europium(II), thulium(III), ytterbium(II); methylytterbium cluster Yb<sub>8</sub>
 (μ-CH<sub>3</sub>
)<sub>14</sub>
(μ-CH<sub>2</sub>
)(THF)<sub>6</sub>
; heterobimetallic samarium(II), ytterbium(II, III) complexes; diazabutadiene ytterbium(III) derivatives; metallic praseodymium and ytterbium, activated by iodine. The highest activity in styrene polymerization revealed hydrides, naphthalene and stilbene complexes of samarium(II), europium(II) and ytterbium(II). In the propene polymerization only [(η<sup>5</sup>
-C<sub>5</sub>
H<sub>4</sub>
)CH<sub>2</sub>
CH (CH<sub>2</sub>
OBu)(η<sup>1</sup>
-O)]YbMe(THF) displayed noticeable activity.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001D09D02B</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Catalyseur complexe</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Complex catalyst</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Catalizador complejo</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Lanthanide Complexe</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Lanthanide Complexes</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Lantánido Complejo</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Coordinat organique</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Organic ligand</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Ligando orgánico</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Activité catalytique</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Catalyst activity</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Actividad catalítica</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Polymérisation catalyseur complexe</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Complex catalyst polymerization</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Polimerización catalizador complejo</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Polymérisation masse</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Bulk polymerization</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Polimerización masa</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Polymérisation solution</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Solution polymerization</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Polimerización solución</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Styrène polymère</s0>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Styrene polymer</s0>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Estireno polímero</s0>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Propène polymère</s0>
<s2>NK</s2>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Propylene polymer</s0>
<s2>NK</s2>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Propeno polímero</s0>
<s2>NK</s2>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Taux conversion</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Conversion rate</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Factor conversión</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Etude expérimentale</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Experimental study</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Estudio experimental</s0>
<s5>11</s5>
</fC03>
<fN21><s1>113</s1>
</fN21>
</pA>
</standard>
<server><NO>PASCAL 01-0171193 INIST</NO>
<ET>Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization</ET>
<AU>KIRILLOV (Evgueni N.); FEDOROVA (Elena A.); TRIFONOV (Alexander A.); BOCHKAREV (Mikhail N.)</AU>
<AF>G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, ul. Tropinina 49/603600 Nizhny Novgorod/Russie (1 aut., 2 aut., 3 aut., 4 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Applied organometallic chemistry; ISSN 0268-2605; Coden AOCHEX; Royaume-Uni; Da. 2001; Vol. 15; No. 3; Pp. 151-156; Bibl. 21 ref.</SO>
<LA>Anglais</LA>
<EA>Organolanthanoids of several classes were examined as potential styrene and propene polymerization catalysts. They are: molecular hydrides of divalent lanthanoids (samarium, europium, ytterbium); naphthalene and stilbene complexes of neodymium(III), samarium(II), europium(II), ytterbium(II), lutetium(III); amides and alkoxides (including heterobifunctional derivatives) of praseodymium(III), neodymium(III), samarium(II), europium(II), thulium(III), ytterbium(II, III); thiolate of samarium(III); phenyl and phenylethinyl derivatives of europium(II), thulium(III), ytterbium(II); methylytterbium cluster Yb<sub>8</sub>
 (μ-CH<sub>3</sub>
)<sub>14</sub>
(μ-CH<sub>2</sub>
)(THF)<sub>6</sub>
; heterobimetallic samarium(II), ytterbium(II, III) complexes; diazabutadiene ytterbium(III) derivatives; metallic praseodymium and ytterbium, activated by iodine. The highest activity in styrene polymerization revealed hydrides, naphthalene and stilbene complexes of samarium(II), europium(II) and ytterbium(II). In the propene polymerization only [(η<sup>5</sup>
-C<sub>5</sub>
H<sub>4</sub>
)CH<sub>2</sub>
CH (CH<sub>2</sub>
OBu)(η<sup>1</sup>
-O)]YbMe( THF) displayed noticeable activity.</EA>
<CC>001D09D02B</CC>
<FD>Catalyseur complexe; Lanthanide Complexe; Coordinat organique; Activité catalytique; Polymérisation catalyseur complexe; Polymérisation masse; Polymérisation solution; Styrène polymère; Propène polymère; Taux conversion; Etude expérimentale</FD>
<ED>Complex catalyst; Lanthanide Complexes; Organic ligand; Catalyst activity; Complex catalyst polymerization; Bulk polymerization; Solution polymerization; Styrene polymer; Propylene polymer; Conversion rate; Experimental study</ED>
<SD>Catalizador complejo; Lantánido Complejo; Ligando orgánico; Actividad catalítica; Polimerización catalizador complejo; Polimerización masa; Polimerización solución; Estireno polímero; Propeno polímero; Factor conversión; Estudio experimental</SD>
<LO>INIST-21323.354000094966060010</LO>
<ID>01-0171193</ID>
</server>
</inist>
</record>

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Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization

Catalytic activity of some organolanthanoid derivatives in styrene and propene polymerization

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