Importance of hydrogen‐bonding sites in the chiral recognition mechanism between racemic D3 terbium(III) complexes and amino acids

Importance of hydrogen‐bonding sites in the chiral recognition mechanism between racemic D3 terbium(III) complexes and amino acids

Source :

• Chirality [ 0899-0042 ] ; 2009-05.

Descripteurs français

• Wicri :
  • topic : Acide.

English descriptors

• KwdEn :
  • Absolute stereochemistry, Acid, Active sites, Amino, Amino acid, Amino acids, Amino group, Analog compound, Aqueous solution, Aqueous solutions, Aromatic rings, Brittain, Carbon atoms, Carboxylate function, Carboxylic acids, Chelidamic acid, Chem, Chemical shifts, Chiral, Chiral agents, Chiral lanthanide complexes, Chiral molecules, Chiral probe, Chiral probes, Chiral recognition, Chirality, Circular dichroism, Circularly, Complex salts, Contract grant number, Coord chem, Coulombic forces, Dalton trans, Diastereomeric association, Drug discovery, Emission monochromator, Emission spectra, Equilibrium shift, Excitation, Excitation spectra, Excitation wavelengths, Experimental conditions, Form hydrogen bonds, Free unassociated, Gilles muller, Glum, Glum values, Guanidino group, High degree, Hydrophobic effects, Hydroxyl, Hydroxyl group, Inorg, Inorg chem, Jose state university, Lanthanide, Lanthanide complexes, Ligand, Ligand interface, Ligand ratio, Local structure, Luminescence, Luminescence dissymmetry factor, Luminescence dissymmetry ratio values, Luminescence spectroscopy, Luminescence studies, Opposite signs, Optical activity, Optical rotation values, Other hand, Perturbation, Pfeiffer, Pfeiffer effect, Positive charge, Practical guide, Preferential formation, Pyridine ring, Pyrrolidone rings, Racemic, Racemic complexes, Racemic equilibrium, Racemic mixtures, Racemic solution, Racemic solutions, Recognition mechanism, Side chain, Spectral range, Spectroscopic studies, Standard deviation, Various acids, Washington square, Zwitterionic form.
• Teeft :
  • Absolute stereochemistry, Acid, Active sites, Amino, Amino acid, Amino acids, Amino group, Analog compound, Aqueous solution, Aqueous solutions, Aromatic rings, Brittain, Carbon atoms, Carboxylate function, Carboxylic acids, Chelidamic acid, Chem, Chemical shifts, Chiral, Chiral agents, Chiral lanthanide complexes, Chiral molecules, Chiral probe, Chiral probes, Chiral recognition, Chirality, Circular dichroism, Circularly, Complex salts, Contract grant number, Coord chem, Coulombic forces, Dalton trans, Diastereomeric association, Drug discovery, Emission monochromator, Emission spectra, Equilibrium shift, Excitation, Excitation spectra, Excitation wavelengths, Experimental conditions, Form hydrogen bonds, Free unassociated, Gilles muller, Glum, Glum values, Guanidino group, High degree, Hydrophobic effects, Hydroxyl, Hydroxyl group, Inorg, Inorg chem, Jose state university, Lanthanide, Lanthanide complexes, Ligand, Ligand interface, Ligand ratio, Local structure, Luminescence, Luminescence dissymmetry factor, Luminescence dissymmetry ratio values, Luminescence spectroscopy, Luminescence studies, Opposite signs, Optical activity, Optical rotation values, Other hand, Perturbation, Pfeiffer, Pfeiffer effect, Positive charge, Practical guide, Preferential formation, Pyridine ring, Pyrrolidone rings, Racemic, Racemic complexes, Racemic equilibrium, Racemic mixtures, Racemic solution, Racemic solutions, Recognition mechanism, Side chain, Spectral range, Spectroscopic studies, Standard deviation, Various acids, Washington square, Zwitterionic form.

Abstract

• https://api.istex.fr/document/0E84689966BCA756674BA0BDCF53826BC9F114B0/fulltext/pdf
• http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2668746

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