Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation.
Identifieur interne : 000953 ( Main/Curation ); précédent : 000952; suivant : 000954Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation.
Auteurs : Aurélien Momin [France] ; Fanny Bonnet ; Marc Visseaux ; Laurent Maron ; Josef Takats ; Michael J. Ferguson ; Xavier-Frédéric Le Goff ; François NiefSource :
- Chemical communications (Cambridge, England) [ 1364-548X ] ; 2011.
Abstract
The new divalent thulium compound [Tm(BH(4))(2)(DME)(2)] could be prepared by reduction of [Tm(BH(4))(3)(THF)(3)] or from TmI(2) and KBH(4). It was used as a precursor to the divalent [(Tp(tBu,Me))Tm(BH(4))(THF)] by reaction with potassium tris(2-tBu-4-Me)pyrazolylborate (KTp(tBu,Me)). Both Tm(II) compounds were found active as ε-caprolactone polymerisation catalysts.
DOI: 10.1039/c1cc15294g
PubMed: 21987051
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