The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds
Identifieur interne : 000F23 ( Istex/Curation ); précédent : 000F22; suivant : 000F24The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds
Auteurs : Mercouri G. Kanatzidis [États-Unis] ; Rainer Pöttgen [Allemagne] ; Wolfgang Jeitschko [Allemagne]Source :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2005-11-04.
Descripteurs français
English descriptors
- KwdEn :
- Acetic acid, Acta, Acta chem, Acta crystallogr, Albering, Allg, Alloy, Alloys compd, Alumina, Aluminides, Ampoule, Angew, Angewandte, Angewandte chemie synthesis, Annealing, Anorg, Appl, Atomic ratio, Bilc, Binary, Binary compounds, Binary phosphides, Boride, Borides, Braun, Brazis, Canfield, Chem, Chemie, Compd, Compound, Cosn, Crucible, Crucible material, Cryst, Crystal growth, Crystal structures, Crystallogr, Cubic phase, Direct reaction, Disalvo, Elemental components, Eutectic, Gmbh, Higashi, High content, High pressure, High temperatures, Hydrochloric, Hydrochloric acid, Indium, Indium flux, Inorg, Intermetallic, Intermetallic compounds, Intermetallic phases, Intermetallics, Isotypic, Jeitschko, Kanatzidis, Kannewurf, Kgaa, Kristallogr, Kudou, Lanthanoid, Large crystals, Large number, Liquid aluminum, Liquid gallium, Liquid metals, Lithium, Lower temperatures, Mahanti, Mater, Matrix, Metal flux, Metallic flux, Metallic fluxes, Molten, Molten aluminum, Molten metals, Naturforsch, Niemann, Nitride, Okada, Peritectic, Peritectic reactions, Phase diagram, Phosphides, Phosphorus, Phys, Physical properties, Polyphosphides, Quaternary, Quaternary compounds, Rare earths, Reactant, Reaction product, Reactive, Reactive flux, Recent examples, Reehuis, Room temperature, Scanning electron micrograph, Shishido, Silica tubes, Silicide, Silicon, Single crystal, Single crystals, Slow cooling, Small amounts, Solid state chem, Stannides, Structure type, Such reactions, Ternary, Ternary compounds, Ternary phosphides, Thiede, Transition metal, Transition metals, Unpublished results, Verlag, Verlag gmbh, Weinheim, Weinheim angew, Yamane, Zhuravleva.
- Teeft :
- Acetic acid, Acta, Acta chem, Acta crystallogr, Albering, Allg, Alloy, Alloys compd, Alumina, Aluminides, Ampoule, Angew, Angewandte, Angewandte chemie synthesis, Annealing, Anorg, Appl, Atomic ratio, Bilc, Binary, Binary compounds, Binary phosphides, Boride, Borides, Braun, Brazis, Canfield, Chem, Chemie, Compd, Compound, Cosn, Crucible, Crucible material, Cryst, Crystal growth, Crystal structures, Crystallogr, Cubic phase, Direct reaction, Disalvo, Elemental components, Eutectic, Gmbh, Higashi, High content, High pressure, High temperatures, Hydrochloric, Hydrochloric acid, Indium, Indium flux, Inorg, Intermetallic, Intermetallic compounds, Intermetallic phases, Intermetallics, Isotypic, Jeitschko, Kanatzidis, Kannewurf, Kgaa, Kristallogr, Kudou, Lanthanoid, Large crystals, Large number, Liquid aluminum, Liquid gallium, Liquid metals, Lithium, Lower temperatures, Mahanti, Mater, Matrix, Metal flux, Metallic flux, Metallic fluxes, Molten, Molten aluminum, Molten metals, Naturforsch, Niemann, Nitride, Okada, Peritectic, Peritectic reactions, Phase diagram, Phosphides, Phosphorus, Phys, Physical properties, Polyphosphides, Quaternary, Quaternary compounds, Rare earths, Reactant, Reaction product, Reactive, Reactive flux, Recent examples, Reehuis, Room temperature, Scanning electron micrograph, Shishido, Silica tubes, Silicide, Silicon, Single crystal, Single crystals, Slow cooling, Small amounts, Solid state chem, Stannides, Structure type, Such reactions, Ternary, Ternary compounds, Ternary phosphides, Thiede, Transition metal, Transition metals, Unpublished results, Verlag, Verlag gmbh, Weinheim, Weinheim angew, Yamane, Zhuravleva.
Abstract
This review highlights the use and great potential of liquid metals as exotic and powerful solvents (i.e. fluxes) for the synthesis of intermetallic phases. The results presented demonstrate that considerable advances in the discovery of novel and complex phases are achievable utilizing molten metals as solvents. A wide cross‐section of examples of flux‐grown intermetallic phases and related solids are discussed and a brief history of the origins of flux chemistry is given. The most commonly used metal fluxes are surveyed and where possible, the underlying principal reasons that make the flux reaction work are discussed.
Url:
DOI: 10.1002/anie.200462170
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<term>Acta</term>
<term>Acta chem</term>
<term>Acta crystallogr</term>
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<term>Allg</term>
<term>Alloy</term>
<term>Alloys compd</term>
<term>Alumina</term>
<term>Aluminides</term>
<term>Ampoule</term>
<term>Angew</term>
<term>Angewandte</term>
<term>Angewandte chemie synthesis</term>
<term>Annealing</term>
<term>Anorg</term>
<term>Appl</term>
<term>Atomic ratio</term>
<term>Bilc</term>
<term>Binary</term>
<term>Binary compounds</term>
<term>Binary phosphides</term>
<term>Boride</term>
<term>Borides</term>
<term>Braun</term>
<term>Brazis</term>
<term>Canfield</term>
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<term>Chemie</term>
<term>Compd</term>
<term>Compound</term>
<term>Cosn</term>
<term>Crucible</term>
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<term>Cryst</term>
<term>Crystal growth</term>
<term>Crystal structures</term>
<term>Crystallogr</term>
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<term>Direct reaction</term>
<term>Disalvo</term>
<term>Elemental components</term>
<term>Eutectic</term>
<term>Gmbh</term>
<term>Higashi</term>
<term>High content</term>
<term>High pressure</term>
<term>High temperatures</term>
<term>Hydrochloric</term>
<term>Hydrochloric acid</term>
<term>Indium</term>
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<term>Inorg</term>
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<term>Intermetallic compounds</term>
<term>Intermetallic phases</term>
<term>Intermetallics</term>
<term>Isotypic</term>
<term>Jeitschko</term>
<term>Kanatzidis</term>
<term>Kannewurf</term>
<term>Kgaa</term>
<term>Kristallogr</term>
<term>Kudou</term>
<term>Lanthanoid</term>
<term>Large crystals</term>
<term>Large number</term>
<term>Liquid aluminum</term>
<term>Liquid gallium</term>
<term>Liquid metals</term>
<term>Lithium</term>
<term>Lower temperatures</term>
<term>Mahanti</term>
<term>Mater</term>
<term>Matrix</term>
<term>Metal flux</term>
<term>Metallic flux</term>
<term>Metallic fluxes</term>
<term>Molten</term>
<term>Molten aluminum</term>
<term>Molten metals</term>
<term>Naturforsch</term>
<term>Niemann</term>
<term>Nitride</term>
<term>Okada</term>
<term>Peritectic</term>
<term>Peritectic reactions</term>
<term>Phase diagram</term>
<term>Phosphides</term>
<term>Phosphorus</term>
<term>Phys</term>
<term>Physical properties</term>
<term>Polyphosphides</term>
<term>Quaternary</term>
<term>Quaternary compounds</term>
<term>Rare earths</term>
<term>Reactant</term>
<term>Reaction product</term>
<term>Reactive</term>
<term>Reactive flux</term>
<term>Recent examples</term>
<term>Reehuis</term>
<term>Room temperature</term>
<term>Scanning electron micrograph</term>
<term>Shishido</term>
<term>Silica tubes</term>
<term>Silicide</term>
<term>Silicon</term>
<term>Single crystal</term>
<term>Single crystals</term>
<term>Slow cooling</term>
<term>Small amounts</term>
<term>Solid state chem</term>
<term>Stannides</term>
<term>Structure type</term>
<term>Such reactions</term>
<term>Ternary</term>
<term>Ternary compounds</term>
<term>Ternary phosphides</term>
<term>Thiede</term>
<term>Transition metal</term>
<term>Transition metals</term>
<term>Unpublished results</term>
<term>Verlag</term>
<term>Verlag gmbh</term>
<term>Weinheim</term>
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<front><div type="abstract" xml:lang="en">This review highlights the use and great potential of liquid metals as exotic and powerful solvents (i.e. fluxes) for the synthesis of intermetallic phases. The results presented demonstrate that considerable advances in the discovery of novel and complex phases are achievable utilizing molten metals as solvents. A wide cross‐section of examples of flux‐grown intermetallic phases and related solids are discussed and a brief history of the origins of flux chemistry is given. The most commonly used metal fluxes are surveyed and where possible, the underlying principal reasons that make the flux reaction work are discussed.</div>
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